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Biodiesel production using unrefined methanol as transesterification agent and the research of individual effect of impurities

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  • Ma, Yingqun
  • Wang, Qunhui
  • Zheng, Lu
  • Gao, Zhen
  • Yang, Yajuan
  • Wang, Nan
  • Ma, Hongzhi

Abstract

In this study, we produced biodiesel by utilising waste cooking oil as a raw material, unrefined methanol produced by a chemical plant as a transesterification agent and sodium hydroxide as a catalyst. The yield and heating value of the biodiesel produced with unrefined methanol were respectively 1.09% and 0.23 MJ/kg higher than those of the biodiesel prepared with pure methanol. The biodiesel characteristics met the standard of the ASTM (American Society for Testing and Materials). We investigated the effects of four impurity types in the unrefined methanol on biodiesel preparation. Alcohol impurities acting as co-solvents and transesterification agents can increase the yield and heating value. Organic solvent impurities can only act as co-solvents; thus, they can only improve the yield. Ester impurities (methyl formate) exhibited no effects on the yield and heating value because they evaporated in the ester exchange reaction. Water impurities significantly reduced the yield by affecting the miscibility of waste cooking oil and pure methanol. However, the negative effects of these impurities were alleviated when water was mixed with the organic solvent impurities. This study has a great significance for the resource and energy of unrefined methanol.

Suggested Citation

  • Ma, Yingqun & Wang, Qunhui & Zheng, Lu & Gao, Zhen & Yang, Yajuan & Wang, Nan & Ma, Hongzhi, 2015. "Biodiesel production using unrefined methanol as transesterification agent and the research of individual effect of impurities," Energy, Elsevier, vol. 82(C), pages 361-369.
    • Handle: RePEc:eee:energy:v:82:y:2015:i:c:p:361-369
    DOI: 10.1016/j.energy.2015.01.046
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    References listed on IDEAS

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    1. Lim, Steven & Lee, Keat Teong, 2014. "Investigation of impurity tolerance and thermal stability for biodiesel production from Jatropha curcas L. seeds using supercritical reactive extraction," Energy, Elsevier, vol. 68(C), pages 71-79.
    2. Rakopoulos, Dimitrios C. & Rakopoulos, Constantine D. & Giakoumis, Evangelos G. & Papagiannakis, Roussos G. & Kyritsis, Dimitrios C., 2014. "Influence of properties of various common bio-fuels on the combustion and emission characteristics of high-speed DI (direct injection) diesel engine: Vegetable oil, bio-diesel, ethanol, n-butanol, die," Energy, Elsevier, vol. 73(C), pages 354-366.
    3. Macor, A. & Pavanello, P., 2009. "Performance and emissions of biodiesel in a boiler for residential heating," Energy, Elsevier, vol. 34(12), pages 2025-2032.
    4. Endalew, Abebe K. & Kiros, Yohannes & Zanzi, Rolando, 2011. "Heterogeneous catalysis for biodiesel production from Jatropha curcas oil (JCO)," Energy, Elsevier, vol. 36(5), pages 2693-2700.
    5. Lee, H.V. & Taufiq-Yap, Y.H. & Hussein, M.Z. & Yunus, R., 2013. "Transesterification of jatropha oil with methanol over Mg–Zn mixed metal oxide catalysts," Energy, Elsevier, vol. 49(C), pages 12-18.
    6. Xue, Bao-jin & Luo, Jia & Zhang, Fan & Fang, Zhen, 2014. "Biodiesel production from soybean and Jatropha oils by magnetic CaFe2O4–Ca2Fe2O5-based catalyst," Energy, Elsevier, vol. 68(C), pages 584-591.
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    4. Li, Yangyang & Jin, Yiying & Li, Jinhui, 2016. "Influence of thermal hydrolysis on composition characteristics of fatty acids in kitchen waste," Energy, Elsevier, vol. 102(C), pages 139-147.
    5. Gülüm, Mert & Bilgin, Atilla, 2018. "A comprehensive study on measurement and prediction of viscosity of biodiesel-diesel-alcohol ternary blends," Energy, Elsevier, vol. 148(C), pages 341-361.
    6. Zhang, Xiaolei & Yan, Song & Tyagi, Rajeshwar Dayal & Drogui, Patrick & Surampalli, Rao Y., 2016. "Ultrasonication aided biodiesel production from one-step and two-step transesterification of sludge derived lipid," Energy, Elsevier, vol. 94(C), pages 401-408.
    7. Sina Faizollahzadeh Ardabili & Bahman Najafi & Meysam Alizamir & Amir Mosavi & Shahaboddin Shamshirband & Timon Rabczuk, 2018. "Using SVM-RSM and ELM-RSM Approaches for Optimizing the Production Process of Methyl and Ethyl Esters," Energies, MDPI, vol. 11(11), pages 1-19, October.
    8. Ma, Yingqun & Wang, Qunhui & Sun, Xiaohong & Wu, Chuanfu & Gao, Zhen, 2017. "Kinetics studies of biodiesel production from waste cooking oil using FeCl3-modified resin as heterogeneous catalyst," Renewable Energy, Elsevier, vol. 107(C), pages 522-530.

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