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Concentration of renewable products of crude bio-oil from thermal cracking of the methyl esters in castor oil

Author

Listed:
  • Menshhein, Guilherme
  • Costa, Vanderlei
  • Chiarello, Luana M.
  • Scharf, Dilamara R.
  • Simionato, Edesio L.
  • Botton, Vanderleia
  • Meier, Henry F.
  • Wiggers, Vinicyus R.
  • Ender, Laércio

Abstract

Castor oil has been widely used as raw material to obtain compounds such as paints, solvents, rubbers, polyurethane polymers and chemical inputs. Then, one highlighted route is thermal cracking of castor oil to produce bio-oil, mainly composed of heptaldehyde and methyl undecenoate, which are used as precursors of lactones in the food and beverage industry. The main aim of this study was to evaluate the separation heptaldehyde and methyl undecenoate by distillation of bio-oil from thermal cracking of the methyl esters in castor oil (MECO). Distilled fractions were analyzed by gas chromatography (GC). Thus, it was possible to concentrate the fractions of heptaldehyde and methyl undecenoate in a section with a distillation system at atmospheric pressure with a distillation rate of 5.0 mL min-1 at 270 °C, which motivates new researches for up-scaling of the process.

Suggested Citation

  • Menshhein, Guilherme & Costa, Vanderlei & Chiarello, Luana M. & Scharf, Dilamara R. & Simionato, Edesio L. & Botton, Vanderleia & Meier, Henry F. & Wiggers, Vinicyus R. & Ender, Laércio, 2019. "Concentration of renewable products of crude bio-oil from thermal cracking of the methyl esters in castor oil," Renewable Energy, Elsevier, vol. 142(C), pages 561-568.
    • Handle: RePEc:eee:renene:v:142:y:2019:i:c:p:561-568
    DOI: 10.1016/j.renene.2019.04.136
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    References listed on IDEAS

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    1. Dias, J.M. & Araújo, J.M. & Costa, J.F. & Alvim-Ferraz, M.C.M. & Almeida, M.F., 2013. "Biodiesel production from raw castor oil," Energy, Elsevier, vol. 53(C), pages 58-66.
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    Cited by:

    1. Zheng, Yunwu & Wang, Jida & Liu, Can & Lu, Yi & Lin, Xu & Li, Wenbin & Zheng, Zhifeng, 2020. "Efficient and stable Ni-Cu catalysts for ex situ catalytic pyrolysis vapor upgrading of oleic acid into hydrocarbon: Effect of catalyst support, process parameters and Ni-to-Cu mixed ratio," Renewable Energy, Elsevier, vol. 154(C), pages 797-812.
    2. Fang, Jun & Liu, Zhuangzhuang & Luan, Hui & Liu, Fen & Yuan, Xingzhong & Long, Shundong & Wang, Andong & Ma, Yong & Xiao, Zhihua, 2021. "Thermochemical liquefaction of cattle manure using ethanol as solvent: Effects of temperature on bio-oil yields and chemical compositions," Renewable Energy, Elsevier, vol. 167(C), pages 32-41.

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