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Metasilicate-based catalyst prepared from natural diatomaceous earth for biodiesel production

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  • Chen, Ying-Chen
  • Lin, Dai-Ying
  • Chen, Bing-Hung

Abstract

In this study, natural diatomaceous earth was utilized for the preparation of efficient lithium metasilicate (Li2SiO3) catalyst for biodiesel production via the transesterification of soybean oil and waste cooking oil. Lithium metasilicate was successfully synthesized from the hydrothermal reaction of natural diatomite in LiOH solutions at 150 °C for 24 h and, subsequently, by calcination at 500 °C for 6 h. Both fresh and spent Li2SiO3 catalysts were characterized by using XRD, 29Si NMR, BET, ICP-OES and acid-base titration. The acidity of the soybean oil and waste cooking oil used in this study was 0.54 mg KOH/g oil and 1.67 mg KOH/g oil, respectively. The yields of biodiesel from soybean oil reached ca. 80.3% in 1 h, respectively, in presence of catalyst at 3 wt% of oil used. Generally, more catalyst present would lead to a higher yield of biodiesel. With the mass loading of catalyst-to-oil at 0.05, the activation energy of the catalyzed transesterification using Li2SiO3 catalyst was 61.65 kJ/mol. The durability test of the Li2SiO3 catalysts was conducted in the same system. A high catalytic activity after being reused for 19 times was observed with a yield of biodiesel near ca. 85% after 4 h of the transesterification reaction at 60 °C. The deactivation mechanism of the Li2SiO3 catalyst was mainly attributed to the loss of surface base sites coincident with more Q4 and less Q2 Si atoms in catalyst after reaction, as found by 29Si NMR.

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  • Chen, Ying-Chen & Lin, Dai-Ying & Chen, Bing-Hung, 2019. "Metasilicate-based catalyst prepared from natural diatomaceous earth for biodiesel production," Renewable Energy, Elsevier, vol. 138(C), pages 1042-1050.
  • Handle: RePEc:eee:renene:v:138:y:2019:i:c:p:1042-1050
    DOI: 10.1016/j.renene.2019.02.054
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    References listed on IDEAS

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    1. Kaur, Mandeep & Malhotra, Rashi & Ali, Amjad, 2018. "Tungsten supported Ti/SiO2 nanoflowers as reusable heterogeneous catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 116(PA), pages 109-119.
    2. Malhotra, Rashi & Ali, Amjad, 2018. "Lithium-doped ceria supported SBA−15 as mesoporous solid reusable and heterogeneous catalyst for biodiesel production via simultaneous esterification and transesterification of waste cottonseed oil," Renewable Energy, Elsevier, vol. 119(C), pages 32-44.
    3. Roschat, Wuttichai & Siritanon, Theeranun & Yoosuk, Boonyawan & Sudyoadsuk, Taweesak & Promarak, Vinich, 2017. "Rubber seed oil as potential non-edible feedstock for biodiesel production using heterogeneous catalyst in Thailand," Renewable Energy, Elsevier, vol. 101(C), pages 937-944.
    4. Gaurav, N. & Sivasankari, S. & Kiran, GS & Ninawe, A. & Selvin, J., 2017. "Utilization of bioresources for sustainable biofuels: A Review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 205-214.
    5. Veljković, Vlada B. & Banković-Ilić, Ivana B. & Stamenković, Olivera S., 2015. "Purification of crude biodiesel obtained by heterogeneously-catalyzed transesterification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 49(C), pages 500-516.
    6. Ma, Yingqun & Wang, Qunhui & Sun, Xiaohong & Wu, Chuanfu & Gao, Zhen, 2017. "Kinetics studies of biodiesel production from waste cooking oil using FeCl3-modified resin as heterogeneous catalyst," Renewable Energy, Elsevier, vol. 107(C), pages 522-530.
    7. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    8. Hoseini, S.S. & Najafi, G. & Ghobadian, B. & Mamat, Rizalman & Sidik, Nor Azwadi Che & Azmi, W.H., 2017. "The effect of combustion management on diesel engine emissions fueled with biodiesel-diesel blends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 307-331.
    9. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
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    2. Đặng, Tấn-Hiệp & Nguyễn, Xuân-Hoàn & Chou, Chi-Lin & Chen, Bing-Hung, 2021. "Preparation of cancrinite-type zeolite from diatomaceous earth as transesterification catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 174(C), pages 347-358.

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