IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v130y2019icp633-640.html
   My bibliography  Save this article

Production of biodiesel from crude palm oil by a sequential hydrolysis/esterification process using subcritical water

Author

Listed:
  • dos Santos, Letícia Karen
  • Hatanaka, Rafael Rodrigues
  • de Oliveira, José Eduardo
  • Flumignan, Danilo Luiz

Abstract

This paper investigates the biodiesel production by subcritical/chemical hydroesterification from crude palm oil. Hydroesterification is the innovation of biodiesel production in two-step: consists of hydrolysis of oil into free fatty acids (FFAs) in subcritical water and subsequent chemical esterification of FFAs into FAMEs (biodiesel). The purpose was to apply the experimental factorial design to evaluate the influence of reaction variables on the effectiveness of hydrolysis and determine the relationship of FFAs and FAMEs yields. Experiments were conducted in a batch reactor under various conditions and the optimal conditions (250 °C, 120 min, 100:1 water:oil molar ratio and 700 rpm) for hydrolysis was determined. The analyses indicated high FFAs yields (86 wt%). Esterification results revealed a conversion of the FFAs in 99.1 wt% of FAMEs in biodiesel production. This study shows that hydroesterification process produces biodiesel with excellent quality as well as traditional alkaline transesterification.

Suggested Citation

  • dos Santos, Letícia Karen & Hatanaka, Rafael Rodrigues & de Oliveira, José Eduardo & Flumignan, Danilo Luiz, 2019. "Production of biodiesel from crude palm oil by a sequential hydrolysis/esterification process using subcritical water," Renewable Energy, Elsevier, vol. 130(C), pages 633-640.
  • Handle: RePEc:eee:renene:v:130:y:2019:i:c:p:633-640
    DOI: 10.1016/j.renene.2018.06.102
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148118307547
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2018.06.102?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Giakoumis, Evangelos G. & Rakopoulos, Constantine D. & Dimaratos, Athanasios M. & Rakopoulos, Dimitrios C., 2013. "Exhaust emissions with ethanol or n-butanol diesel fuel blends during transient operation: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 17(C), pages 170-190.
    2. Ong, H.C. & Mahlia, T.M.I. & Masjuki, H.H. & Norhasyima, R.S., 2011. "Comparison of palm oil, Jatropha curcas and Calophyllum inophyllum for biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3501-3515.
    3. dos Santos, Letícia Karen & Hatanaka, Rafael Rodrigues & de Oliveira, José Eduardo & Flumignan, Danilo Luiz, 2017. "Experimental factorial design on hydroesterification of waste cooking oil by subcritical conditions for biodiesel production," Renewable Energy, Elsevier, vol. 114(PB), pages 574-580.
    4. Nongbe, Medy C. & Ekou, Tchirioua & Ekou, Lynda & Yao, Kouassi Benjamin & Le Grognec, Erwan & Felpin, François-Xavier, 2017. "Biodiesel production from palm oil using sulfonated graphene catalyst," Renewable Energy, Elsevier, vol. 106(C), pages 135-141.
    5. Kuss, Vivian Vicentini & Kuss, Anelise Vicentini & Rosa, Rosana Gomes da & Aranda, Donato A.G. & Cruz, Yordanka Reyes, 2015. "Potential of biodiesel production from palm oil at Brazilian Amazon," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1013-1020.
    6. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zamani, Ali Salehi & Saidi, Majid & Najafabadi, Ali Taheri, 2023. "Selective production of diesel-like alkanes via Neem seed oil hydrodeoxygenation over Ni/MgSiO3 catalyst," Renewable Energy, Elsevier, vol. 209(C), pages 462-470.
    2. Saidi, Majid & Faraji, Mehdi, 2024. "Thermochemical conversion of neem seed biomass to sustainable hydrogen and biofuels: Experimental and theoretical evaluation," Renewable Energy, Elsevier, vol. 221(C).
    3. Gourich, Wail & Chan, Eng-Seng & Ng, Wei Zhe & Obon, Aaron Anthony & Maran, Kireshwen & Ong, Yi Hui & Lee, Chin Loong & Tan, Jully & Song, Cher Pin, 2022. "Life cycle benefits of enzymatic biodiesel co-produced in palm oil mills from sludge palm oil as renewable fuel for rural electrification," Applied Energy, Elsevier, vol. 325(C).
    4. Zulqarnain & Muhammad Ayoub & Mohd Hizami Mohd Yusoff & Muhammad Hamza Nazir & Imtisal Zahid & Mariam Ameen & Farooq Sher & Dita Floresyona & Eduardus Budi Nursanto, 2021. "A Comprehensive Review on Oil Extraction and Biodiesel Production Technologies," Sustainability, MDPI, vol. 13(2), pages 1-28, January.
    5. Muanruksa, Papasanee & Kaewkannetra, Pakawadee, 2020. "Combination of fatty acids extraction and enzymatic esterification for biodiesel production using sludge palm oil as a low-cost substrate," Renewable Energy, Elsevier, vol. 146(C), pages 901-906.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Blanco-Marigorta, A.M. & Suárez-Medina, J. & Vera-Castellano, A., 2013. "Exergetic analysis of a biodiesel production process from Jatropha curcas," Applied Energy, Elsevier, vol. 101(C), pages 218-225.
    2. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    3. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel—Part: 1 selection of feedstocks, oil extraction techniques and conversion technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1109-1128.
    4. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Hazrat, M.A., 2015. "Prospect of biofuels as an alternative transport fuel in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 331-351.
    5. Teuku Meurah Indra Riayatsyah & Hwai Chyuan Ong & Wen Tong Chong & Lisa Aditya & Heri Hermansyah & Teuku Meurah Indra Mahlia, 2017. "Life Cycle Cost and Sensitivity Analysis of Reutealis trisperma as Non-Edible Feedstock for Future Biodiesel Production," Energies, MDPI, vol. 10(7), pages 1-21, June.
    6. Kanjaikaew, Utaiwan & Tongurai, Chakrit & Chongkhong, Sininart & Prasertsit, Kulchanat, 2018. "Two-step esterification of palm fatty acid distillate in ethyl ester production: Optimization and sensitivity analysis," Renewable Energy, Elsevier, vol. 119(C), pages 336-344.
    7. Khairul Azly Zahan & Manabu Kano, 2018. "Biodiesel Production from Palm Oil, Its By-Products, and Mill Effluent: A Review," Energies, MDPI, vol. 11(8), pages 1-25, August.
    8. Silitonga, A.S. & Masjuki, H.H. & Mahlia, T.M.I. & Ong, H.C. & Atabani, A.E. & Chong, W.T., 2013. "A global comparative review of biodiesel production from jatropha curcas using different homogeneous acid and alkaline catalysts: Study of physical and chemical properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 514-533.
    9. Yesilyurt, Murat Kadir & Cesur, Cüneyt & Aslan, Volkan & Yilbasi, Zeki, 2020. "The production of biodiesel from safflower (Carthamus tinctorius L.) oil as a potential feedstock and its usage in compression ignition engine: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    10. Motasemi, F. & Ani, F.N., 2012. "A review on microwave-assisted production of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4719-4733.
    11. Suhaiza Zailani & Mohammad Iranmanesh & Sunghyup Sean Hyun & Mohd Helmi Ali, 2019. "Barriers of Biodiesel Adoption by Transportation Companies: A Case of Malaysian Transportation Industry," Sustainability, MDPI, vol. 11(3), pages 1-15, February.
    12. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.
    13. Sivabalan Kaniapan & Suhaimi Hassan & Hamdan Ya & Kartikeyan Patma Nesan & Mohammad Azeem, 2021. "The Utilisation of Palm Oil and Oil Palm Residues and the Related Challenges as a Sustainable Alternative in Biofuel, Bioenergy, and Transportation Sector: A Review," Sustainability, MDPI, vol. 13(6), pages 1-25, March.
    14. D'Souza, Reena & Vats, Tripti & Chattree, Amit & Siril, Prem Felix, 2018. "Graphene supported magnetically separable solid acid catalyst for the single step conversion of waste cooking oil to biodiesel," Renewable Energy, Elsevier, vol. 126(C), pages 1064-1073.
    15. Bergthorson, Jeffrey M. & Thomson, Murray J., 2015. "A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1393-1417.
    16. Ruxandra-Cristina Stanescu & Cristian-Ioan Leahu & Adrian Soica, 2023. "Aspects Regarding the Modelling and Optimization of the Transesterification Process through Temperature Control of the Chemical Reactor," Energies, MDPI, vol. 16(6), pages 1-17, March.
    17. Iraklis Zahos-Siagos & Vlasios Karathanassis & Dimitrios Karonis, 2018. "Exhaust Emissions and Physicochemical Properties of n -Butanol/Diesel Blends with 2-Ethylhexyl Nitrate (EHN) or Hydrotreated Used Cooking Oil (HUCO) as Cetane Improvers," Energies, MDPI, vol. 11(12), pages 1-20, December.
    18. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    19. Şahin, Zehra & Aksu, Orhan N., 2015. "Experimental investigation of the effects of using low ratio n-butanol/diesel fuel blends on engine performance and exhaust emissions in a turbocharged DI diesel engine," Renewable Energy, Elsevier, vol. 77(C), pages 279-290.
    20. Zhang, X.L. & Yan, S. & Tyagi, R.D. & Surampalli, R.Y., 2013. "Biodiesel production from heterotrophic microalgae through transesterification and nanotechnology application in the production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 216-223.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:130:y:2019:i:c:p:633-640. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.