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Hydrogen generation from catalytic hydrolysis of sodium borohydride using bimetallic Ni–Co nanoparticles on reduced graphene oxide as catalysts

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  • Chou, Chang-Chen
  • Hsieh, Ching-Hsuan
  • Chen, Bing-Hung

Abstract

Preparation and characterization of bimetallic Ni–Co nanoparticle catalysts loaded on the reduced graphene oxide, denoted as Ni–Co/r-GO, for hydrogen generation from catalytic hydrolysis of sodium borohydride were studied. The reduced graphene oxide nanosheets were prepared from natural graphite. The Ni and Co metals were electrolessly deposited on the light-weighted reduced graphene oxide (r-GO) nanosheets. Process parameters affecting the hydrolysis reaction of NaBH4 in the presence of Ni–Co/r-GO catalysts, such as NaOH and NaBH4 concentrations, as well as catalyst loadings and reaction temperature, were investigated. A hydrogen production rate as high as ca. 1280 mL min−1 (g cat.)−1 could be obtained using the prepared Ni–Co/r-GO catalysts. The activation energy of the catalytic hydrolysis reaction of sodium borohydride was found at 55.12 kJ mol−1 from the system consisting of 10 wt% NaBH4 and 5 wt% NaOH as well as a catalyst loading at 0.1 g catalyst per g NaBH4.

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  • Chou, Chang-Chen & Hsieh, Ching-Hsuan & Chen, Bing-Hung, 2015. "Hydrogen generation from catalytic hydrolysis of sodium borohydride using bimetallic Ni–Co nanoparticles on reduced graphene oxide as catalysts," Energy, Elsevier, vol. 90(P2), pages 1973-1982.
    • Handle: RePEc:eee:energy:v:90:y:2015:i:p2:p:1973-1982
    DOI: 10.1016/j.energy.2015.07.023
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    1. Helder X. Nunes & Diogo L. Silva & Carmen M. Rangel & Alexandra M. F. R. Pinto, 2021. "Rehydrogenation of Sodium Borates to Close the NaBH 4 -H 2 Cycle: A Review," Energies, MDPI, vol. 14(12), pages 1-28, June.
    2. Zhang, Hongming & Xu, Guochang & Zhang, Lu & Wang, Wenfeng & Miao, Wenkang & Chen, Kangli & Cheng, Lina & Li, Yuan & Han, Shumin, 2020. "Ultrafine cobalt nanoparticles supported on carbon nanospheres for hydrolysis of sodium borohydride," Renewable Energy, Elsevier, vol. 162(C), pages 345-354.
    3. Luo, Chunlin & Liu, Shuai & Yang, Gang & Jiang, Peng & Luo, Xiang & Chen, Yipei & Xu, Mengxia & Lester, Edward & Wu, Tao, 2023. "Microwave-accelerated hydrolysis for hydrogen production over a cobalt-loaded multi-walled carbon nanotube-magnetite composite catalyst," Applied Energy, Elsevier, vol. 333(C).
    4. Bozkurt, Gamze & Özer, Abdulkadir & Yurtcan, Ayşe Bayrakçeken, 2019. "Development of effective catalysts for hydrogen generation from sodium borohydride: Ru, Pt, Pd nanoparticles supported on Co3O4," Energy, Elsevier, vol. 180(C), pages 702-713.
    5. Ensafi, Ali A. & Jafari-Asl, Mehdi & Nabiyan, Afshin & Rezaei, B., 2016. "Ni3S2/ball-milled silicon flour as a bi-functional electrocatalyst for hydrogen and oxygen evolution reactions," Energy, Elsevier, vol. 116(P1), pages 392-401.
    6. Tomboc, Gracita Raquel M. & Tamboli, Ashif H. & Kim, Hern, 2017. "Synthesis of Co3O4 macrocubes catalyst using novel chitosan/urea template for hydrogen generation from sodium borohydride," Energy, Elsevier, vol. 121(C), pages 238-245.
    7. Cai, Haokun & Liu, Liping & Chen, Qiang & Lu, Ping & Dong, Jian, 2016. "Ni-polymer nanogel hybrid particles: A new strategy for hydrogen production from the hydrolysis of dimethylamine-borane and sodium borohydride," Energy, Elsevier, vol. 99(C), pages 129-135.

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