IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v185y2022icp8-16.html

SrCo0.4Fe0.4Zr0.1Y0.1O3-δ, A new CO2 tolerant cathode for proton-conducting solid oxide fuel cells

Author

Listed:
  • Lv, Xiuqing
  • Chen, Huili
  • Zhou, Wei
  • Li, Si-Dian
  • Cheng, Fangqin
  • Shao, Zongping

Abstract

CO2 poisoning is not a negligible issue for SrCoO3-δ based materials, which limits their application as cathodes for solid oxide fuel cells (SOFCs). In this paper, iron, zirconium, and yttrium were co-doped into SrCoO3-δ to form a structurally stable cubic perovskite material, SrCo0.4Fe0.4Zr0.1Y0.1O3-δ (SCFZY). The CO2 adsorption-desorption on SCFZY was studied via X-ray diffraction and CO2 temperature-programmed desorption. The polarization resistance of the symmetric cell SCFZY|BaZr0.1Ce0.7Y0.1Yb0.1O3-δ (BZCYYb)|SCFZY was tested in air containing 10 vol% CO2 to evaluate the SCFZY's CO2-tolerance as a SOFCs cathode. When applied as a SOFCs cathode in a cell with a proton-conducting electrolyte BZCYYb, SCFZY showed significant CO2-tolerance. The single-cell NiO-BZCYYb|BZCYYb|BZCYYb-SCFZY showed an output with a maximum power density of 679 mW cm−2 at 700 °C and good durability of 500 h. The SCFZY cathode also displayed better CO2-tolerance than the Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) cathode for IT- SOFCs.

Suggested Citation

  • Lv, Xiuqing & Chen, Huili & Zhou, Wei & Li, Si-Dian & Cheng, Fangqin & Shao, Zongping, 2022. "SrCo0.4Fe0.4Zr0.1Y0.1O3-δ, A new CO2 tolerant cathode for proton-conducting solid oxide fuel cells," Renewable Energy, Elsevier, vol. 185(C), pages 8-16.
    • Handle: RePEc:eee:renene:v:185:y:2022:i:c:p:8-16
    DOI: 10.1016/j.renene.2021.12.030
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S096014812101750X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.12.030?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to

    for a different version of it.

    References listed on IDEAS

    as
    1. Zongping Shao & Sossina M. Haile, 2004. "A high-performance cathode for the next generation of solid-oxide fuel cells," Nature, Nature, vol. 431(7005), pages 170-173, September.
    2. Cascos, V. & Fernández-Díaz, M.T. & Alonso, J.A., 2019. "Structural and electrical characterization of the novel SrCo1-xTixO3–δ (x = 0.05, 0.1 and 0.15) perovskites: Evaluation as cathode materials in solid oxide fuel cells," Renewable Energy, Elsevier, vol. 133(C), pages 205-215.
    3. Sharaf, Omar Z. & Orhan, Mehmet F., 2014. "An overview of fuel cell technology: Fundamentals and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 810-853.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhao, Chen & Li, Baozhu & Zhang, Lu & Han, Yaru & Wu, Xiaoyu, 2023. "Novel optimal structure design and testing of air-cooled open-cathode proton exchange membrane fuel cell," Renewable Energy, Elsevier, vol. 215(C).
    2. Farahmand Habibi, Maryam & Arvand, Majid & Sohrabnezhad, Shabnam, 2021. "Boosting bioelectricity generation in microbial fuel cells using metal@metal oxides/nitrogen-doped carbon quantum dots," Energy, Elsevier, vol. 223(C).
    3. Das, Himadry Shekhar & Tan, Chee Wei & Yatim, A.H.M., 2017. "Fuel cell hybrid electric vehicles: A review on power conditioning units and topologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 268-291.
    4. Peng, Fei & Zhao, Yuanzhe & Li, Xiaopeng & Liu, Zhixiang & Chen, Weirong & Liu, Yang & Zhou, Donghua, 2017. "Development of master-slave energy management strategy based on fuzzy logic hysteresis state machine and differential power processing compensation for a PEMFC-LIB-SC hybrid tramway," Applied Energy, Elsevier, vol. 206(C), pages 346-363.
    5. Jae Yun Jeong & Inje Kang & Ki Seok Choi & Byeong-Hee Lee, 2018. "Network Analysis on Green Technology in National Research and Development Projects in Korea," Sustainability, MDPI, vol. 10(4), pages 1-12, April.
    6. Liao, Shuxin & Qiu, Diankai & Yi, Peiyun & Peng, Linfa & Lai, Xinmin, 2022. "Modeling of a novel cathode flow field design with optimized sub-channels to improve drainage for proton exchange membrane fuel cells," Energy, Elsevier, vol. 261(PB).
    7. Yang, Bo & Li, Danyang & Zeng, Chunyuan & Chen, Yijun & Guo, Zhengxun & Wang, Jingbo & Shu, Hongchun & Yu, Tao & Zhu, Jiawei, 2021. "Parameter extraction of PEMFC via Bayesian regularization neural network based meta-heuristic algorithms," Energy, Elsevier, vol. 228(C).
    8. Anastassios Stamatis & Christina Vinni & Diamantis Bakalis & Fotini Tzorbatzoglou & Panagiotis Tsiakaras, 2012. "Exergy Analysis of an Intermediate Temperature Solid Oxide Fuel Cell-Gas Turbine Hybrid System Fed with Ethanol," Energies, MDPI, vol. 5(11), pages 1-20, October.
    9. Aruna, S.T. & Balaji, L.S. & Kumar, S. Senthil & Prakash, B. Shri, 2017. "Electrospinning in solid oxide fuel cells – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 673-682.
    10. Saadat, Nazmus & Dhakal, Hom N. & Tjong, Jimi & Jaffer, Shaffiq & Yang, Weimin & Sain, Mohini, 2021. "Recent advances and future perspectives of carbon materials for fuel cell," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    11. Zapata-Ramírez, Víctor & Rosendo-Santos, Paula & Amador, Ulises & Ritter, Clemens & Mather, Glenn C. & Pérez-Coll, Domingo, 2022. "Optimisation of high-performance, cobalt-free SrFe1-xMoxO3-δ cathodes for solid oxide fuel cells prepared by spray pyrolysis," Renewable Energy, Elsevier, vol. 185(C), pages 1167-1176.
    12. Duan, Liqiang & Sun, Siyu & Yue, Long & Qu, Wanjun & Yang, Yongping, 2015. "Study on a new IGCC (Integrated Gasification Combined Cycle) system with CO2 capture by integrating MCFC (Molten Carbonate Fuel Cell)," Energy, Elsevier, vol. 87(C), pages 490-503.
    13. Wang, Qing-Hui & Yang, Song & Zhou, Wei & Li, Jing-Rong & Xu, Zhi-Jia & Ke, Yu-Zhi & Yu, Wei & Hu, Guang-Hua, 2018. "Optimizing the porosity configuration of porous copper fiber sintered felt for methanol steam reforming micro-reactor based on flow distribution," Applied Energy, Elsevier, vol. 216(C), pages 243-261.
    14. A.M. Shakorfow & A.H. Mohamed, 2024. "Cogeneration Via Solid Oxide Fuel Cells," Acta Chemica Malaysia (ACMY), Zibeline International Publishing, vol. 8(2), pages 97-106, August.
    15. Martin Kügemann & Heracles Polatidis, 2019. "Multi-Criteria Decision Analysis of Road Transportation Fuels and Vehicles: A Systematic Review and Classification of the Literature," Energies, MDPI, vol. 13(1), pages 1-21, December.
    16. Palomba, Valeria & Ferraro, Marco & Frazzica, Andrea & Vasta, Salvatore & Sergi, Francesco & Antonucci, Vincenzo, 2018. "Experimental and numerical analysis of a SOFC-CHP system with adsorption and hybrid chillers for telecommunication applications," Applied Energy, Elsevier, vol. 216(C), pages 620-633.
    17. Gómez, Sergio Yesid & Hotza, Dachamir, 2016. "Current developments in reversible solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 155-174.
    18. Kinnon, Michael Mac & Razeghi, Ghazal & Samuelsen, Scott, 2021. "The role of fuel cells in port microgrids to support sustainable goods movement," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    19. Mehrpooya, Mehdi & Ansarinasab, Hojat & Mousavi, Seyed Ali, 2021. "Life cycle assessment and exergoeconomic analysis of the multi-generation system based on fuel cell for methanol, power, and heat production," Renewable Energy, Elsevier, vol. 172(C), pages 1314-1332.
    20. Zhiyu You & Liwei Wang & Ying Han & Firuz Zare, 2018. "System Design and Energy Management for a Fuel Cell/Battery Hybrid Forklift," Energies, MDPI, vol. 11(12), pages 1-24, December.

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;

    JEL classification:

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:185:y:2022:i:c:p:8-16. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.