IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v78y2014icp950-956.html
   My bibliography  Save this article

Preparation and properties of palmitic-stearic acid eutectic mixture/expanded graphite composite as phase change material for energy storage

Author

Listed:
  • Zhang, Nan
  • Yuan, Yanping
  • Du, Yanxia
  • Cao, Xiaoling
  • Yuan, Yaguang

Abstract

A novel composite PCM (phase change material) with PA-SA (palmitic-stearic acid) eutectic mixture as PCM and EG (expanded graphite) as supporting material was prepared. The optimum absorption ratio of PA-SA/EG (Palmitic-stearic acid/expanded graphite) composite PCM was determined as PA-SA:EG = 13:1 (by mass). Scanning electron microscope and Fourier transformation infrared spectroscopy results show that PA-SA was uniformly distributed in the porous network structure of EG due to the physical action. Thermal property and thermal stability of the PA-SA/EG composite PCM were characterized by DSC (differential scanning calorimetry) and TGA (thermogravimetric analysis). DSC results indicated that the melting and freezing temperatures and latent heats of PA-SA/EG were measured as 53.89 °C and 54.37 °C, and 166.27 J/g and 166.13 J/g. TGA test results revealed that PA-SA/EG had a good thermal stability in working temperature range. Thermal cycling test results showed PA-SA/EG had a good thermal reliability after 720 thermal cycles. Thermal conductivity of the composite PCM was measured as 2.51 W/m K, much higher than that of PA-SA. The thermal energy storage and release rates of PA-SA/EG were also increased due to the high thermal conductivity of EG. In conclusion, the prepared PA-SA/EG composite PCM can be acted as a potential material for thermal energy storage due to the acceptable thermal properties, good thermal reliability and stability, high thermal conductivity.

Suggested Citation

  • Zhang, Nan & Yuan, Yanping & Du, Yanxia & Cao, Xiaoling & Yuan, Yaguang, 2014. "Preparation and properties of palmitic-stearic acid eutectic mixture/expanded graphite composite as phase change material for energy storage," Energy, Elsevier, vol. 78(C), pages 950-956.
    • Handle: RePEc:eee:energy:v:78:y:2014:i:c:p:950-956
    DOI: 10.1016/j.energy.2014.10.092
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214012523
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2014.10.092?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhao, Jianguo & Guo, Yong & Feng, Feng & Tong, Qinghua & Qv, Wenshan & Wang, Haiqing, 2011. "Microstructure and thermal properties of a paraffin/expanded graphite phase-change composite for thermal storage," Renewable Energy, Elsevier, vol. 36(5), pages 1339-1342.
    2. Tyagi, Vineet Veer & Buddhi, D., 2007. "PCM thermal storage in buildings: A state of art," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(6), pages 1146-1166, August.
    3. Yuan, Yanping & Zhang, Nan & Tao, Wenquan & Cao, Xiaoling & He, Yaling, 2014. "Fatty acids as phase change materials: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 482-498.
    4. Tumirah, K. & Hussein, M.Z. & Zulkarnain, Z. & Rafeadah, R., 2014. "Nano-encapsulated organic phase change material based on copolymer nanocomposites for thermal energy storage," Energy, Elsevier, vol. 66(C), pages 881-890.
    5. Li, Wei & Zhang, Xing-xiang & Wang, Xue-chen & Tang, Guo-yi & Shi, Hai-feng, 2012. "Fabrication and morphological characterization of microencapsulated phase change materials (MicroPCMs) and macrocapsules containing MicroPCMs for thermal energy storage," Energy, Elsevier, vol. 38(1), pages 249-254.
    6. Li, TingXian & Lee, Ju-Hyuk & Wang, RuZhu & Kang, Yong Tae, 2013. "Enhancement of heat transfer for thermal energy storage application using stearic acid nanocomposite with multi-walled carbon nanotubes," Energy, Elsevier, vol. 55(C), pages 752-761.
    7. Koca, Ahmet & Oztop, Hakan F. & Koyun, Tansel & Varol, Yasin, 2008. "Energy and exergy analysis of a latent heat storage system with phase change material for a solar collector," Renewable Energy, Elsevier, vol. 33(4), pages 567-574.
    8. Fang, Guiyin & Li, Hui & Chen, Zhi & Liu, Xu, 2010. "Preparation and characterization of stearic acid/expanded graphite composites as thermal energy storage materials," Energy, Elsevier, vol. 35(12), pages 4622-4626.
    9. Tunçbilek, Kadir & Sari, Ahmet & Tarhan, Sefa & Ergüneş, Gazanfer & Kaygusuz, Kamil, 2005. "Lauric and palmitic acids eutectic mixture as latent heat storage material for low temperature heating applications," Energy, Elsevier, vol. 30(5), pages 677-692.
    10. Fan, Liwu & Khodadadi, J.M., 2011. "Thermal conductivity enhancement of phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 24-46, January.
    11. Karaipekli, Ali & Sarı, Ahmet & Kaygusuz, Kamil, 2007. "Thermal conductivity improvement of stearic acid using expanded graphite and carbon fiber for energy storage applications," Renewable Energy, Elsevier, vol. 32(13), pages 2201-2210.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Abdulhamed, Ali Jaber & Adam, Nor Mariah & Ab-Kadir, Mohd Zainal Abidin & Hairuddin, Abdul Aziz, 2018. "Review of solar parabolic-trough collector geometrical and thermal analyses, performance, and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 822-831.
    2. Wu, Minqiang & Li, Tingxian & He, Qifan & Du, Ruxue & Wang, Ruzhu, 2022. "Thermally conductive and form-stable phase change composite for building thermal management," Energy, Elsevier, vol. 239(PA).
    3. Ait Ousaleh, Hanane & Sair, Said & Zaki, Abdelali & Younes, Abboud & Faik, Abdessamad & El Bouari, Abdeslam, 2020. "Advanced experimental investigation of double hydrated salts and their composite for improved cycling stability and metal compatibility for long-term heat storage technologies," Renewable Energy, Elsevier, vol. 162(C), pages 447-457.
    4. Zhang, Suling & Wu, Wei & Wang, Shuangfeng, 2017. "Integration highly concentrated photovoltaic module exhaust heat recovery system with adsorption air-conditioning module via phase change materials," Energy, Elsevier, vol. 118(C), pages 1187-1197.
    5. Cui, Wenlong & Yuan, Yanping & Sun, Liangliang & Cao, Xiaoling & Yang, Xiaojiao, 2016. "Experimental studies on the supercooling and melting/freezing characteristics of nano-copper/sodium acetate trihydrate composite phase change materials," Renewable Energy, Elsevier, vol. 99(C), pages 1029-1037.
    6. Yuan, Yanping & Zhang, Nan & Li, Tianyu & Cao, Xiaoling & Long, Weiyue, 2016. "Thermal performance enhancement of palmitic-stearic acid by adding graphene nanoplatelets and expanded graphite for thermal energy storage: A comparative study," Energy, Elsevier, vol. 97(C), pages 488-497.
    7. Li, Min & Mu, Boyuan, 2019. "Effect of different dimensional carbon materials on the properties and application of phase change materials: A review," Applied Energy, Elsevier, vol. 242(C), pages 695-715.
    8. Zhang, P. & Xiao, X. & Ma, Z.W., 2016. "A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement," Applied Energy, Elsevier, vol. 165(C), pages 472-510.
    9. Jinghua Yu & Kangxin Leng & Feifei Wang & Hong Ye & Yongqiang Luo, 2020. "Simulation Study on Dynamic Thermal Performance of a New Ventilated Roof with Form-Stable PCM in Southern China," Sustainability, MDPI, vol. 12(22), pages 1-21, November.
    10. Liu, Yushi & Yang, Yingzi, 2018. "Form-stable phase change material based on Na2CO3·10H2O-Na2HPO4·12H2O eutectic hydrated salt/expanded graphite oxide composite: The influence of chemical structures of expanded graphite oxide," Renewable Energy, Elsevier, vol. 115(C), pages 734-740.
    11. Zhang, Xiangguo & Li, Yuqing & Luo, Chunhuan & Pan, Chongchao, 2021. "Fabrication and properties of novel tubular carbon fiber-ionic liquids/stearic acid composite PCMs," Renewable Energy, Elsevier, vol. 177(C), pages 411-421.
    12. Song, Yanlin & Zhang, Nan & Jing, Yaoge & Cao, Xiaoling & Yuan, Yanping & Haghighat, Fariborz, 2019. "Experimental and numerical investigation on dodecane/expanded graphite shape-stabilized phase change material for cold energy storage," Energy, Elsevier, vol. 189(C).
    13. Saeed, Rami M. & Schlegel, J.P. & Sawafta, R., 2019. "Characterization of high-temperature PCMs for enhancing passive safety and heat removal capabilities in nuclear reactor systems," Energy, Elsevier, vol. 189(C).
    14. Zhang, Suling & Wu, Wei & Wang, Shuangfeng, 2017. "Preparation, thermal properties and thermal reliability of a novel mid-temperature composite phase change material for energy conservation," Energy, Elsevier, vol. 130(C), pages 228-235.
    15. Gunasekara, Saman Nimali & Martin, Viktoria & Chiu, Justin Ningwei, 2017. "Phase equilibrium in the design of phase change materials for thermal energy storage: State-of-the-art," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 558-581.
    16. Chenxiao Zheng & Shijun You & Huan Zhang & Zeqin Liu & Wandong Zheng & Zhenjing Wu & Man Fan, 2020. "Defrosting Performance Improvement of Air-Source Heat Pump Combined Refrigerant Direct-Condensation Radiant Floor Heating System with Phase Change Material," Energies, MDPI, vol. 13(18), pages 1-17, September.
    17. Yu, Jinghua & Leng, Kangxin & Ye, Hong & Xu, Xinhua & Luo, Yongqiang & Wang, Jinbo & Yang, Xie & Yang, Qingchen & Gang, Wenjie, 2020. "Study on thermal insulation characteristics and optimized design of pipe-embedded ventilation roof with outer-layer shape-stabilized PCM in different climate zones," Renewable Energy, Elsevier, vol. 147(P1), pages 1609-1622.
    18. Xia, Mingzhu & Yuan, Yanping & Zhao, Xudong & Cao, Xiaoling & Tang, Zhonghua, 2016. "Cold storage condensation heat recovery system with a novel composite phase change material," Applied Energy, Elsevier, vol. 175(C), pages 259-268.
    19. Huang, Xuelin & Guo, Jing & Gong, Yumei & Li, Shenglin & Mu, Siyang & Zhang, Sen, 2017. "In-situ preparation of a shape stable phase change material," Renewable Energy, Elsevier, vol. 108(C), pages 244-249.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, P. & Xiao, X. & Ma, Z.W., 2016. "A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement," Applied Energy, Elsevier, vol. 165(C), pages 472-510.
    2. Han, Pengju & Lu, Lixin & Qiu, Xiaolin & Tang, Yali & Wang, Jun, 2015. "Preparation and characterization of macrocapsules containing microencapsulated PCMs (phase change materials) for thermal energy storage," Energy, Elsevier, vol. 91(C), pages 531-539.
    3. Sarı, Ahmet & Alkan, Cemil & Bilgin, Cahit, 2014. "Micro/nano encapsulation of some paraffin eutectic mixtures with poly(methyl methacrylate) shell: Preparation, characterization and latent heat thermal energy storage properties," Applied Energy, Elsevier, vol. 136(C), pages 217-227.
    4. Yuan, Yanping & Zhang, Nan & Tao, Wenquan & Cao, Xiaoling & He, Yaling, 2014. "Fatty acids as phase change materials: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 482-498.
    5. Huang, Xiang & Alva, Guruprasad & Jia, Yuting & Fang, Guiyin, 2017. "Morphological characterization and applications of phase change materials in thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 128-145.
    6. Zhang, Xialan & Lin, Qilang & Luo, Huijun & Luo, Shiyuan, 2020. "Three-dimensional graphitic hierarchical porous carbon/stearic acid composite as shape-stabilized phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 260(C).
    7. Xia, Mingzhu & Yuan, Yanping & Zhao, Xudong & Cao, Xiaoling & Tang, Zhonghua, 2016. "Cold storage condensation heat recovery system with a novel composite phase change material," Applied Energy, Elsevier, vol. 175(C), pages 259-268.
    8. Tao, Y.B. & He, Ya-Ling, 2018. "A review of phase change material and performance enhancement method for latent heat storage system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 93(C), pages 245-259.
    9. Yuan, Yanping & Zhang, Nan & Li, Tianyu & Cao, Xiaoling & Long, Weiyue, 2016. "Thermal performance enhancement of palmitic-stearic acid by adding graphene nanoplatelets and expanded graphite for thermal energy storage: A comparative study," Energy, Elsevier, vol. 97(C), pages 488-497.
    10. Wang, Xianglei & Guo, Quangui & Zhong, Yajuan & Wei, Xinghai & Liu, Lang, 2013. "Heat transfer enhancement of neopentyl glycol using compressed expanded natural graphite for thermal energy storage," Renewable Energy, Elsevier, vol. 51(C), pages 241-246.
    11. Amaral, C. & Vicente, R. & Marques, P.A.A.P. & Barros-Timmons, A., 2017. "Phase change materials and carbon nanostructures for thermal energy storage: A literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1212-1228.
    12. Wei, Haiting & Xie, Xiuzhen & Li, Xiangqi & Lin, Xingshui, 2016. "Preparation and characterization of capric-myristic-stearic acid eutectic mixture/modified expanded vermiculite composite as a form-stable phase change material," Applied Energy, Elsevier, vol. 178(C), pages 616-623.
    13. Li, Min & Wu, Zhishen & Tan, Jinmiao, 2012. "Properties of form-stable paraffin/silicon dioxide/expanded graphite phase change composites prepared by sol–gel method," Applied Energy, Elsevier, vol. 92(C), pages 456-461.
    14. Alizadeh, M. & Sadrameli, S.M., 2016. "Development of free cooling based ventilation technology for buildings: Thermal energy storage (TES) unit, performance enhancement techniques and design considerations – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 619-645.
    15. Soares, N. & Bastos, J. & Pereira, L. Dias & Soares, A. & Amaral, A.R. & Asadi, E. & Rodrigues, E. & Lamas, F.B. & Monteiro, H. & Lopes, M.A.R. & Gaspar, A.R., 2017. "A review on current advances in the energy and environmental performance of buildings towards a more sustainable built environment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 845-860.
    16. Johra, Hicham & Heiselberg, Per, 2017. "Influence of internal thermal mass on the indoor thermal dynamics and integration of phase change materials in furniture for building energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 19-32.
    17. Huang, Zhaowen & Gao, Xuenong & Xu, Tao & Fang, Yutang & Zhang, Zhengguo, 2014. "Thermal property measurement and heat storage analysis of LiNO3/KCl – expanded graphite composite phase change material," Applied Energy, Elsevier, vol. 115(C), pages 265-271.
    18. Ge, Haoshan & Li, Haiyan & Mei, Shengfu & Liu, Jing, 2013. "Low melting point liquid metal as a new class of phase change material: An emerging frontier in energy area," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 331-346.
    19. Dongyi Zhou & Jiawei Yuan & Yuhong Zhou & Yicai Liu, 2020. "Preparation and Properties of Capric–Myristic Acid/Expanded Graphite Composite Phase Change Materials for Latent Heat Thermal Energy Storage," Energies, MDPI, vol. 13(10), pages 1-12, May.
    20. Mishra, Amit Kumar & Lahiri, B.B. & Philip, John, 2020. "Carbon black nano particle loaded lauric acid-based form-stable phase change material with enhanced thermal conductivity and photo-thermal conversion for thermal energy storage," Energy, Elsevier, vol. 191(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:78:y:2014:i:c:p:950-956. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.