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Preparation and characterization of capric-myristic-stearic acid eutectic mixture/modified expanded vermiculite composite as a form-stable phase change material

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  • Wei, Haiting
  • Xie, Xiuzhen
  • Li, Xiangqi
  • Lin, Xingshui

Abstract

A novel capric-myristic-stearic acid (CA-MA-SA)/modified expanded vermiculite composite phase change material (PCM) with simultaneously enhanced thermal conductivity and latent heat was prepared in this study. The expanded vermiculite/carbon composite (EVC), obtained by in-situ carbonizing cetyl trimethyl ammonium bromide in the layer of expanded vermiculite, was treated with nitric acid (aEVC) to be used as the CA-MA-SA supporting matrix. The results showed that the thermal conductivity of CA-MA-SA/aEVC was greatly enhanced by introducing carbon and the CA-MA-SA adsorption capacity was improved by the acid-treatment of EVC. The thermal conductivity of CA-MA-SA/aEVC was 0.667W/mK, which was 31.6% higher than that of CA-MA-SA/expanded vermiculite (EV). The latent heats of the CA-MA-SA/aEVC were 86.4J/g at the melting temperature of 22.92°C and 80.43J/g at the freezing temperature of 21.03°C, which were also greatly higher than those of CA-MA-SA/EV. The results of the thermo-gravimetric analysis (TGA), thermal cycling test and Fourier transform infrared spectroscopy (FT-IR) indicated that the CA-MA-SA/aEVC composite PCM was thermally stable and chemically inert. Thus, the prepared CA-MA-SA/aEVC composite PCM is a promising material for the building energy efficiency applications.

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  • Wei, Haiting & Xie, Xiuzhen & Li, Xiangqi & Lin, Xingshui, 2016. "Preparation and characterization of capric-myristic-stearic acid eutectic mixture/modified expanded vermiculite composite as a form-stable phase change material," Applied Energy, Elsevier, vol. 178(C), pages 616-623.
    • Handle: RePEc:eee:appene:v:178:y:2016:i:c:p:616-623
    DOI: 10.1016/j.apenergy.2016.06.109
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    6. Bian, Yadong & Wang, Kejian & Wang, Julian & Yu, Yongsheng & Liu, Mingyue & Lv, Yajun, 2021. "Preparation and properties of capric acid: Stearic acid/hydrophobic expanded perlite-aerogel composite phase change materials," Renewable Energy, Elsevier, vol. 179(C), pages 1027-1035.
    7. Monika Gandhi & Ashok Kumar & Rajasekar Elangovan & Chandan Swaroop Meena & Kishor S. Kulkarni & Anuj Kumar & Garima Bhanot & Nishant R. Kapoor, 2020. "A Review on Shape-Stabilized Phase Change Materials for Latent Energy Storage in Buildings," Sustainability, MDPI, vol. 12(22), pages 1-17, November.
    8. Rathore, Pushpendra Kumar Singh & Shukla, Shailendra kumar, 2021. "Improvement in thermal properties of PCM/Expanded vermiculite/expanded graphite shape stabilized composite PCM for building energy applications," Renewable Energy, Elsevier, vol. 176(C), pages 295-304.
    9. Sarı, Ahmet & Al-Ahmed, Amir & Bicer, Alper & Al-Sulaiman, Fahad A. & Hekimoğlu, Gökhan, 2019. "Investigation of thermal properties and enhanced energy storage/release performance of silica fume/myristic acid composite doped with carbon nanotubes," Renewable Energy, Elsevier, vol. 140(C), pages 779-788.
    10. Chang, Yunwei & Gu, Heng & Yao, Xiaoyan & Qing, Chunyao & Zou, Deqiu, 2024. "Preparation of a novel microencapsulated phase change material (MEPCM)/adipic acid ceramic composite and its thermal performance," Energy, Elsevier, vol. 292(C).
    11. Zhou, Yunhong & Zeng, Jiwei & Guo, Yiyou & Chen, Haobin & Bi, Tiantian & Lin, Qilang, 2023. "Three-dimensional hierarchical porous carbon surface-decorated graphitic carbon foam/stearic acid composite as high-performance shape-stabilized phase change material with desirable photothermal conve," Applied Energy, Elsevier, vol. 352(C).
    12. Zhang, Xialan & Lin, Qilang & Luo, Huijun & Luo, Shiyuan, 2020. "Three-dimensional graphitic hierarchical porous carbon/stearic acid composite as shape-stabilized phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 260(C).

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