IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v178y2016icp616-623.html
   My bibliography  Save this article

Preparation and characterization of capric-myristic-stearic acid eutectic mixture/modified expanded vermiculite composite as a form-stable phase change material

Author

Listed:
  • Wei, Haiting
  • Xie, Xiuzhen
  • Li, Xiangqi
  • Lin, Xingshui

Abstract

A novel capric-myristic-stearic acid (CA-MA-SA)/modified expanded vermiculite composite phase change material (PCM) with simultaneously enhanced thermal conductivity and latent heat was prepared in this study. The expanded vermiculite/carbon composite (EVC), obtained by in-situ carbonizing cetyl trimethyl ammonium bromide in the layer of expanded vermiculite, was treated with nitric acid (aEVC) to be used as the CA-MA-SA supporting matrix. The results showed that the thermal conductivity of CA-MA-SA/aEVC was greatly enhanced by introducing carbon and the CA-MA-SA adsorption capacity was improved by the acid-treatment of EVC. The thermal conductivity of CA-MA-SA/aEVC was 0.667W/mK, which was 31.6% higher than that of CA-MA-SA/expanded vermiculite (EV). The latent heats of the CA-MA-SA/aEVC were 86.4J/g at the melting temperature of 22.92°C and 80.43J/g at the freezing temperature of 21.03°C, which were also greatly higher than those of CA-MA-SA/EV. The results of the thermo-gravimetric analysis (TGA), thermal cycling test and Fourier transform infrared spectroscopy (FT-IR) indicated that the CA-MA-SA/aEVC composite PCM was thermally stable and chemically inert. Thus, the prepared CA-MA-SA/aEVC composite PCM is a promising material for the building energy efficiency applications.

Suggested Citation

  • Wei, Haiting & Xie, Xiuzhen & Li, Xiangqi & Lin, Xingshui, 2016. "Preparation and characterization of capric-myristic-stearic acid eutectic mixture/modified expanded vermiculite composite as a form-stable phase change material," Applied Energy, Elsevier, vol. 178(C), pages 616-623.
    • Handle: RePEc:eee:appene:v:178:y:2016:i:c:p:616-623
    DOI: 10.1016/j.apenergy.2016.06.109
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916308844
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.06.109?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wang, Lijiu & Meng, Duo, 2010. "Fatty acid eutectic/polymethyl methacrylate composite as form-stable phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 87(8), pages 2660-2665, August.
    2. Karaipekli, Ali & Sarı, Ahmet, 2008. "Capric–myristic acid/expanded perlite composite as form-stable phase change material for latent heat thermal energy storage," Renewable Energy, Elsevier, vol. 33(12), pages 2599-2605.
    3. Xu, Biwan & Ma, Hongyan & Lu, Zeyu & Li, Zongjin, 2015. "Paraffin/expanded vermiculite composite phase change material as aggregate for developing lightweight thermal energy storage cement-based composites," Applied Energy, Elsevier, vol. 160(C), pages 358-367.
    4. Fang, Guiyin & Li, Hui & Chen, Zhi & Liu, Xu, 2010. "Preparation and characterization of stearic acid/expanded graphite composites as thermal energy storage materials," Energy, Elsevier, vol. 35(12), pages 4622-4626.
    5. Li, Min & Wu, Zhishen & Kao, Hongtao, 2011. "Study on preparation, structure and thermal energy storage property of capric–palmitic acid/attapulgite composite phase change materials," Applied Energy, Elsevier, vol. 88(9), pages 3125-3132.
    6. Li, Wei & Zhang, Rong & Jiang, Nan & Tang, Xiao-fen & Shi, Hai-feng & Zhang, Xing-xiang & Zhang, Yuankai & Dong, Lin & Zhang, Ningxin, 2013. "Composite macrocapsule of phase change materials/expanded graphite for thermal energy storage," Energy, Elsevier, vol. 57(C), pages 607-614.
    7. Zhou, D. & Zhao, C.Y. & Tian, Y., 2012. "Review on thermal energy storage with phase change materials (PCMs) in building applications," Applied Energy, Elsevier, vol. 92(C), pages 593-605.
    8. Kuznik, Frédéric & Virgone, Joseph, 2009. "Experimental assessment of a phase change material for wall building use," Applied Energy, Elsevier, vol. 86(10), pages 2038-2046, October.
    9. Karaipekli, Ali & Sarı, Ahmet & Kaygusuz, Kamil, 2007. "Thermal conductivity improvement of stearic acid using expanded graphite and carbon fiber for energy storage applications," Renewable Energy, Elsevier, vol. 32(13), pages 2201-2210.
    10. Xu, Biwan & Li, Zongjin, 2013. "Paraffin/diatomite composite phase change material incorporated cement-based composite for thermal energy storage," Applied Energy, Elsevier, vol. 105(C), pages 229-237.
    11. Yuan, Yanping & Zhang, Nan & Tao, Wenquan & Cao, Xiaoling & He, Yaling, 2014. "Fatty acids as phase change materials: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 482-498.
    12. Wang, Weilong & Yang, Xiaoxi & Fang, Yutang & Ding, Jing & Yan, Jinyue, 2009. "Enhanced thermal conductivity and thermal performance of form-stable composite phase change materials by using [beta]-Aluminum nitride," Applied Energy, Elsevier, vol. 86(7-8), pages 1196-1200, July.
    13. Zhao, Pin & Yue, Qinyan & He, Hongtao & Gao, Baoyu & Wang, Yan & Li, Qian, 2014. "Study on phase diagram of fatty acids mixtures to determine eutectic temperatures and the corresponding mixing proportions," Applied Energy, Elsevier, vol. 115(C), pages 483-490.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Xiaoguang & Yin, Zhaoyu & Meng, Dezhi & Huang, Zhaohui & Wen, Ruilong & Huang, Yaoting & Min, Xin & Liu, Yangai & Fang, Minghao & Wu, Xiaowen, 2017. "Shape-stabilized composite phase change materials with high thermal conductivity based on stearic acid and modified expanded vermiculite," Renewable Energy, Elsevier, vol. 112(C), pages 113-123.
    2. Li, Xinghui & Zhu, Ziqi & Yang, Pei & You, Zhenping & Dong, Yue & Tang, Miao & Chen, Minzhi & Zhou, Xiaoyan, 2021. "Carbonized wood loaded with carbon dots for preparation long-term shape-stabilized composite phase change materials with superior thermal energy conversion capacity," Renewable Energy, Elsevier, vol. 174(C), pages 19-30.
    3. Bian, Yadong & Wang, Kejian & Wang, Julian & Yu, Yongsheng & Liu, Mingyue & Lv, Yajun, 2021. "Preparation and properties of capric acid: Stearic acid/hydrophobic expanded perlite-aerogel composite phase change materials," Renewable Energy, Elsevier, vol. 179(C), pages 1027-1035.
    4. Rathore, Pushpendra Kumar Singh & Shukla, Shailendra kumar, 2021. "Improvement in thermal properties of PCM/Expanded vermiculite/expanded graphite shape stabilized composite PCM for building energy applications," Renewable Energy, Elsevier, vol. 176(C), pages 295-304.
    5. Sarı, Ahmet & Al-Ahmed, Amir & Bicer, Alper & Al-Sulaiman, Fahad A. & Hekimoğlu, Gökhan, 2019. "Investigation of thermal properties and enhanced energy storage/release performance of silica fume/myristic acid composite doped with carbon nanotubes," Renewable Energy, Elsevier, vol. 140(C), pages 779-788.
    6. Zhang, Xialan & Lin, Qilang & Luo, Huijun & Luo, Shiyuan, 2020. "Three-dimensional graphitic hierarchical porous carbon/stearic acid composite as shape-stabilized phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 260(C).
    7. Dongyi Zhou & Jiawei Yuan & Yuhong Zhou & Yicai Liu, 2020. "Preparation and Properties of Capric–Myristic Acid/Expanded Graphite Composite Phase Change Materials for Latent Heat Thermal Energy Storage," Energies, MDPI, vol. 13(10), pages 1-12, May.
    8. Lv, Laiquan & Wang, Jiankang & Ji, Mengting & Zhang, Yize & Huang, Shengyao & Cen, Kefa & Zhou, Hao, 2022. "Effect of structural characteristics and surface functional groups of biochar on thermal properties of different organic phase change materials: Dominant encapsulation mechanisms," Renewable Energy, Elsevier, vol. 195(C), pages 1238-1252.
    9. Lv, Peizhao & Ding, Mingyue & Liu, Chenzhen & Rao, Zhonghao, 2019. "Experimental investigation on thermal properties and thermal performance enhancement of octadecanol/expanded perlite form stable phase change materials for efficient thermal energy storage," Renewable Energy, Elsevier, vol. 131(C), pages 911-922.
    10. Monika Gandhi & Ashok Kumar & Rajasekar Elangovan & Chandan Swaroop Meena & Kishor S. Kulkarni & Anuj Kumar & Garima Bhanot & Nishant R. Kapoor, 2020. "A Review on Shape-Stabilized Phase Change Materials for Latent Energy Storage in Buildings," Sustainability, MDPI, vol. 12(22), pages 1-17, November.
    11. Zhou, Yunhong & Zeng, Jiwei & Guo, Yiyou & Chen, Haobin & Bi, Tiantian & Lin, Qilang, 2023. "Three-dimensional hierarchical porous carbon surface-decorated graphitic carbon foam/stearic acid composite as high-performance shape-stabilized phase change material with desirable photothermal conve," Applied Energy, Elsevier, vol. 352(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Cao, Lei & Su, Di & Tang, Yaojie & Fang, Guiyin & Tang, Fang, 2015. "Properties evaluation and applications of thermal energystorage materials in buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 500-522.
    2. Memon, Shazim Ali, 2014. "Phase change materials integrated in building walls: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 870-906.
    3. Yuan, Yanping & Zhang, Nan & Tao, Wenquan & Cao, Xiaoling & He, Yaling, 2014. "Fatty acids as phase change materials: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 482-498.
    4. Zhang, P. & Xiao, X. & Ma, Z.W., 2016. "A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement," Applied Energy, Elsevier, vol. 165(C), pages 472-510.
    5. Golestaneh, S.I. & Mosallanejad, A. & Karimi, G. & Khorram, M. & Khashi, M., 2016. "Fabrication and characterization of phase change material composite fibers with wide phase-transition temperature range by co-electrospinning method," Applied Energy, Elsevier, vol. 182(C), pages 409-417.
    6. Cai, Yibing & Gao, Chuntao & Zhang, Ting & Zhang, Zhen & Wei, Qufu & Du, Jinmei & Hu, Yuan & Song, Lei, 2013. "Influences of expanded graphite on structural morphology and thermal performance of composite phase change materials consisting of fatty acid eutectics and electrospun PA6 nanofibrous mats," Renewable Energy, Elsevier, vol. 57(C), pages 163-170.
    7. Mi, Xuming & Liu, Ran & Cui, Hongzhi & Memon, Shazim Ali & Xing, Feng & Lo, Yiu, 2016. "Energy and economic analysis of building integrated with PCM in different cities of China," Applied Energy, Elsevier, vol. 175(C), pages 324-336.
    8. Qian, Yong & Wei, Ping & Jiang, Pingkai & Li, Zhi & Yan, Yonggang & Liu, Jiping, 2013. "Preparation of a novel PEG composite with halogen-free flame retardant supporting matrix for thermal energy storage application," Applied Energy, Elsevier, vol. 106(C), pages 321-327.
    9. Lv, Peizhao & Liu, Chenzhen & Rao, Zhonghao, 2017. "Review on clay mineral-based form-stable phase change materials: Preparation, characterization and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 707-726.
    10. Cao, Lei & Tang, Yaojie & Fang, Guiyin, 2015. "Preparation and properties of shape-stabilized phase change materials based on fatty acid eutectics and cellulose composites for thermal energy storage," Energy, Elsevier, vol. 80(C), pages 98-103.
    11. Johra, Hicham & Heiselberg, Per, 2017. "Influence of internal thermal mass on the indoor thermal dynamics and integration of phase change materials in furniture for building energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 19-32.
    12. Chen, Weiwang & Weng, Wenguo, 2016. "Ultrafine lauric–myristic acid eutectic/poly (meta-phenylene isophthalamide) form-stable phase change fibers for thermal energy storage by electrospinning," Applied Energy, Elsevier, vol. 173(C), pages 168-176.
    13. Dongyi Zhou & Jiawei Yuan & Yuhong Zhou & Yicai Liu, 2020. "Preparation and Properties of Capric–Myristic Acid/Expanded Graphite Composite Phase Change Materials for Latent Heat Thermal Energy Storage," Energies, MDPI, vol. 13(10), pages 1-12, May.
    14. Kahwaji, Samer & Johnson, Michel B. & Kheirabadi, Ali C. & Groulx, Dominic & White, Mary Anne, 2016. "Stable, low-cost phase change material for building applications: The eutectic mixture of decanoic acid and tetradecanoic acid," Applied Energy, Elsevier, vol. 168(C), pages 457-464.
    15. Ren, Miao & Liu, Yushi & Gao, Xiaojian, 2020. "Incorporation of phase change material and carbon nanofibers into lightweight aggregate concrete for thermal energy regulation in buildings," Energy, Elsevier, vol. 197(C).
    16. Feng, Daili & Feng, Yanhui & Qiu, Lin & Li, Pei & Zang, Yuyang & Zou, Hanying & Yu, Zepei & Zhang, Xinxin, 2019. "Review on nanoporous composite phase change materials: Fabrication, characterization, enhancement and molecular simulation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 109(C), pages 578-605.
    17. Zeinelabdein, Rami & Omer, Siddig & Gan, Guohui, 2018. "Critical review of latent heat storage systems for free cooling in buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2843-2868.
    18. Kenisarin, Murat & Mahkamov, Khamid, 2016. "Passive thermal control in residential buildings using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 371-398.
    19. Fang, Guiyin & Tang, Fang & Cao, Lei, 2014. "Preparation, thermal properties and applications of shape-stabilized thermal energy storage materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 237-259.
    20. Mingli Li & Guoqing Gui & Zhibin Lin & Long Jiang & Hong Pan & Xingyu Wang, 2018. "Numerical Thermal Characterization and Performance Metrics of Building Envelopes Containing Phase Change Materials for Energy-Efficient Buildings," Sustainability, MDPI, vol. 10(8), pages 1-23, July.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:178:y:2016:i:c:p:616-623. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.