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Shape-stabilized composite phase change materials with high thermal conductivity based on stearic acid and modified expanded vermiculite

Author

Listed:
  • Zhang, Xiaoguang
  • Yin, Zhaoyu
  • Meng, Dezhi
  • Huang, Zhaohui
  • Wen, Ruilong
  • Huang, Yaoting
  • Min, Xin
  • Liu, Yangai
  • Fang, Minghao
  • Wu, Xiaowen

Abstract

Stearic acid (SA) and modified expanded vermiculite (EV) shape-stabilized composite phase change materials (ss-CPCMs) with enhanced thermal conductivity were prepared. EV was impregnated with a starch solution, and then a composite of EV and carbon (EVC) was obtained by carbonizing starch in-situ in the EV layers. 63.12 wt % of SA was retained in the SA/EVC ss-CPCMs without leakage. Scanning electron microscopy (SEM) images showed that the EVC with highly porous micro-pores acted as a good support matrix for absorbing molten SA. The thermal conductivity of the SA/EVC ss-CPCMs was 0.52 W/(m K), and this was an increase of 52.9% compared with that of the SA/EV ss-CPCMs. The results from Fourier transform infrared spectroscopy (FT-IR), Differential scanning calorimeter (DSC), thermogravimetric analysis (TGA), and thermal cycling tests indicated that the prepared SA/EVC ss-CPCMs are a promising material for energy efficient buildings because of their optimum phase-change temperature, a high enthalpy of phase change, ideal thermal conductivity, and good chemical and thermal stability.

Suggested Citation

  • Zhang, Xiaoguang & Yin, Zhaoyu & Meng, Dezhi & Huang, Zhaohui & Wen, Ruilong & Huang, Yaoting & Min, Xin & Liu, Yangai & Fang, Minghao & Wu, Xiaowen, 2017. "Shape-stabilized composite phase change materials with high thermal conductivity based on stearic acid and modified expanded vermiculite," Renewable Energy, Elsevier, vol. 112(C), pages 113-123.
  • Handle: RePEc:eee:renene:v:112:y:2017:i:c:p:113-123
    DOI: 10.1016/j.renene.2017.05.026
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    1. Khodadadi, J.M. & Fan, Liwu & Babaei, Hasan, 2013. "Thermal conductivity enhancement of nanostructure-based colloidal suspensions utilized as phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 418-444.
    2. Qian, Yong & Wei, Ping & Jiang, Pingkai & Li, Zhi & Yan, Yonggang & Liu, Jiping, 2013. "Preparation of a novel PEG composite with halogen-free flame retardant supporting matrix for thermal energy storage application," Applied Energy, Elsevier, vol. 106(C), pages 321-327.
    3. Song, Shaokun & Dong, Lijie & Zhang, Yang & Chen, Shun & Li, Qi & Guo, Yi & Deng, Sufen & Si, Shuai & Xiong, Chuanxi, 2014. "Lauric acid/intercalated kaolinite as form-stable phase change material for thermal energy storage," Energy, Elsevier, vol. 76(C), pages 385-389.
    4. Sharif, M.K. Anuar & Al-Abidi, A.A. & Mat, S. & Sopian, K. & Ruslan, M.H. & Sulaiman, M.Y. & Rosli, M.A.M., 2015. "Review of the application of phase change material for heating and domestic hot water systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 557-568.
    5. Wei, Haiting & Xie, Xiuzhen & Li, Xiangqi & Lin, Xingshui, 2016. "Preparation and characterization of capric-myristic-stearic acid eutectic mixture/modified expanded vermiculite composite as a form-stable phase change material," Applied Energy, Elsevier, vol. 178(C), pages 616-623.
    6. Fang, Guiyin & Li, Hui & Chen, Zhi & Liu, Xu, 2010. "Preparation and characterization of stearic acid/expanded graphite composites as thermal energy storage materials," Energy, Elsevier, vol. 35(12), pages 4622-4626.
    7. Nourani, Moloud & Hamdami, Nasser & Keramat, Javad & Moheb, Ahmad & Shahedi, Mohammad, 2016. "Thermal behavior of paraffin-nano-Al2O3 stabilized by sodium stearoyl lactylate as a stable phase change material with high thermal conductivity," Renewable Energy, Elsevier, vol. 88(C), pages 474-482.
    8. Zeng, Ju-Lan & Zheng, Shuang-Hao & Yu, Sai-Bo & Zhu, Fu-Rong & Gan, Juan & Zhu, Ling & Xiao, Zhong-Liang & Zhu, Xin-Yu & Zhu, Zhen & Sun, Li-Xian & Cao, Zhong, 2014. "Preparation and thermal properties of palmitic acid/polyaniline/exfoliated graphite nanoplatelets form-stable phase change materials," Applied Energy, Elsevier, vol. 115(C), pages 603-609.
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    11. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
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    15. Zhang, Xialan & Lin, Qilang & Luo, Huijun & Luo, Shiyuan, 2020. "Three-dimensional graphitic hierarchical porous carbon/stearic acid composite as shape-stabilized phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 260(C).

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