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Thermodynamic analysis of solar thermochemical CO2 capture via carbonation/calcination cycle with heat recovery

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  • Matthews, L.
  • Lipiński, W.

Abstract

Thermodynamic analysis of an ideal solar-driven cycle for the capture of carbon dioxide using a CaO-based carbonation/calcination cycle is performed for gas mixtures with compositions corresponding to those of atmospheric air and power plant flue gases. Solar energy input requirements are examined as a function of CO2 molar fraction in the input gas, gas phase heat recovery, solid phase heat recovery, and carbonation and calcination temperatures. Gas phase heat recovery can reduce the solar energy input requirements by 22–99%, with the largest gains occurring at lower CO2 molar fractions. Solid phase heat recovery can reduce the solar energy input requirements by 0.1–26%, with the largest gains occurring at higher CO2 molar fractions. For a carbonation temperature of 673 K and a calcination temperature of 1273 K, over 45 MJ per mol of CO2 captured is required for a CO2 concentration of 300 ppm with no heat recovery. The minimum solar energy input required with perfect gas and solid heat recovery is 207 kJ per mol of CO2 captured.

Suggested Citation

  • Matthews, L. & Lipiński, W., 2012. "Thermodynamic analysis of solar thermochemical CO2 capture via carbonation/calcination cycle with heat recovery," Energy, Elsevier, vol. 45(1), pages 900-907.
    • Handle: RePEc:eee:energy:v:45:y:2012:i:1:p:900-907
    DOI: 10.1016/j.energy.2012.06.072
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    Cited by:

    1. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    2. Chen, Xiaoyi & Jin, Xiaogang & Liu, Zhimin & Ling, Xiang & Wang, Yan, 2018. "Experimental investigation on the CaO/CaCO3 thermochemical energy storage with SiO2 doping," Energy, Elsevier, vol. 155(C), pages 128-138.
    3. Guillermo Martinez Castilla & Diana Carolina Guío-Pérez & Stavros Papadokonstantakis & David Pallarès & Filip Johnsson, 2021. "Techno-Economic Assessment of Calcium Looping for Thermochemical Energy Storage with CO 2 Capture," Energies, MDPI, vol. 14(11), pages 1-17, May.
    4. Krekel, Daniel & Samsun, Remzi Can & Peters, Ralf & Stolten, Detlef, 2018. "The separation of CO2 from ambient air – A techno-economic assessment," Applied Energy, Elsevier, vol. 218(C), pages 361-381.
    5. Zhao, Ruikai & Deng, Shuai & Liu, Yinan & Zhao, Qing & He, Junnan & Zhao, Li, 2017. "Carbon pump: Fundamental theory and applications," Energy, Elsevier, vol. 119(C), pages 1131-1143.
    6. Sheline, W. & Matthews, L. & Lindeke, N. & Duncan, S. & Palumbo, R., 2013. "An exploratory study of the solar thermal electrolytic production of Mg from MgO," Energy, Elsevier, vol. 51(C), pages 163-170.
    7. Liu, Yinan & Deng, Shuai & Zhao, Ruikai & He, Junnan & Zhao, Li, 2017. "Energy-saving pathway exploration of CCS integrated with solar energy: A review of innovative concepts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 652-669.
    8. Li, Canbing & Shi, Haiqing & Cao, Yijia & Kuang, Yonghong & Zhang, Yongjun & Gao, Dan & Sun, Liang, 2015. "Modeling and optimal operation of carbon capture from the air driven by intermittent and volatile wind power," Energy, Elsevier, vol. 87(C), pages 201-211.

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    Keywords

    CO2 capture; Thermodynamics; Solar; Calcination; Carbonation;
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