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Efficiency of two-step solar thermochemical non-stoichiometric redox cycles with heat recovery

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  • Lapp, J.
  • Davidson, J.H.
  • Lipiński, W.

Abstract

Improvements in the effectiveness of solid phase heat recovery and in the thermodynamic properties of metal oxides are the most important paths to achieving unprecedented thermal efficiencies of 10% and higher in non-stoichiometric solar redox reactors. In this paper, the impact of solid and gas phase heat recovery on the efficiency of a non-stoichiometric cerium dioxide-based H2O/CO2 splitting cycle realized in a solar-driven reactor are evaluated in a parametric thermodynamic analysis. Application of solid phase heat recovery to the cycling metal oxide allows for lower reduction zone operating temperatures, simplifying reactor design. An optimum temperature for metal oxide reduction results from two competing phenomena as the reduction temperature is increased: increasing re-radiation losses from the reactor aperture and decreasing heat loss due to imperfect solid phase heat recovery. Additionally, solid phase heat recovery increases the efficiency gains made possible by gas phase heat recovery.

Suggested Citation

  • Lapp, J. & Davidson, J.H. & Lipiński, W., 2012. "Efficiency of two-step solar thermochemical non-stoichiometric redox cycles with heat recovery," Energy, Elsevier, vol. 37(1), pages 591-600.
    • Handle: RePEc:eee:energy:v:37:y:2012:i:1:p:591-600
    DOI: 10.1016/j.energy.2011.10.045
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    12. Matthews, L. & Lipiński, W., 2012. "Thermodynamic analysis of solar thermochemical CO2 capture via carbonation/calcination cycle with heat recovery," Energy, Elsevier, vol. 45(1), pages 900-907.
    13. Kong, Hui & Kong, Xianghui & Wang, Jian & Zhang, Jun, 2019. "Thermodynamic analysis of a solar thermochemical cycle-based direct coal liquefaction system for oil production," Energy, Elsevier, vol. 179(C), pages 1279-1287.
    14. Koepf, E. & Alxneit, I. & Wieckert, C. & Meier, A., 2017. "A review of high temperature solar driven reactor technology: 25years of experience in research and development at the Paul Scherrer Institute," Applied Energy, Elsevier, vol. 188(C), pages 620-651.
    15. Fuqiang, Wang & Lanxin, Ma & Ziming, Cheng & Jianyu, Tan & Xing, Huang & Linhua, Liu, 2017. "Radiative heat transfer in solar thermochemical particle reactor: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 935-949.
    16. Albrecht, Kevin J. & Jackson, Gregory S. & Braun, Robert J., 2016. "Thermodynamically consistent modeling of redox-stable perovskite oxides for thermochemical energy conversion and storage," Applied Energy, Elsevier, vol. 165(C), pages 285-296.
    17. Sheline, W. & Matthews, L. & Lindeke, N. & Duncan, S. & Palumbo, R., 2013. "An exploratory study of the solar thermal electrolytic production of Mg from MgO," Energy, Elsevier, vol. 51(C), pages 163-170.
    18. Zhu, Liya & Lu, Youjun & Shen, Shaohua, 2016. "Solar fuel production at high temperatures using ceria as a dense membrane," Energy, Elsevier, vol. 104(C), pages 53-63.
    19. Imponenti, Luca & Albrecht, Kevin J. & Kharait, Rounak & Sanders, Michael D. & Jackson, Gregory S., 2018. "Redox cycles with doped calcium manganites for thermochemical energy storage to 1000 °C," Applied Energy, Elsevier, vol. 230(C), pages 1-18.
    20. Christopher L. Muhich & Brian D. Ehrhart & Ibraheam Al-Shankiti & Barbara J. Ward & Charles B. Musgrave & Alan W. Weimer, 2016. "A review and perspective of efficient hydrogen generation via solar thermal water splitting," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 5(3), pages 261-287, May.
    21. Michalsky, Ronald & Parman, Bryon J. & Amanor-Boadu, Vincent & Pfromm, Peter H., 2012. "Solar thermochemical production of ammonia from water, air and sunlight: Thermodynamic and economic analyses," Energy, Elsevier, vol. 42(1), pages 251-260.

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