IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v236y2021ics0360544221016996.html
   My bibliography  Save this article

Reaction performance of CaCO3/CaO thermochemical energy storage with TiO2 dopant and experimental study in a fixed-bed reactor

Author

Listed:
  • Xu, T.X.
  • Tian, X.K.
  • Khosa, A.A.
  • Yan, J.
  • Ye, Q.
  • Zhao, C.Y.

Abstract

The CaCO3/CaO reversible reaction pair is a promising thermochemical energy storage (TCES) technology for concentrating solar power (CSP) plants. However, the reaction performance and cyclic stability of this reaction pair is compromised because of sintering. In this study, TiO2-doped in CaCO3/CaO TCES system are systematically investigated by synchronous thermal analyzer (STA). The reaction kinetics of decarbonation process with and without TiO2 doping are compared in N2 and CO2 atmospheres. Furthermore, the performance of CaCO3/CaO TCES system is analyzed in a fixed-bed reactor for future application. It is found that doping TiO2 can improve the anti-sintering ability and cyclic stability of CaCO3, and the optimal doping ratio is 2.5 mol %, whose energy storage density is 1256.68 kJ/kgsample at first and improved by 2.26 times after 30 cycles. Moreover, doping TiO2 decreases the activation energy and initial decarbonation temperature in CO2 atmospheres. In exothermic experiments of fixed-bed reactor, the maximum exothermic temperature difference is 309.83 °C at 550 °C, and the highest absolute temperature reaches 848.7 °C at 750 °C. TiO2 dopant promotes the decarbonation at lower temperature, and obtains a higher overall conversion (0.506) at 850 °C. Overall, CaCO3 with TiO2 dopant is of great significance for future industrial and commercial applications.

Suggested Citation

  • Xu, T.X. & Tian, X.K. & Khosa, A.A. & Yan, J. & Ye, Q. & Zhao, C.Y., 2021. "Reaction performance of CaCO3/CaO thermochemical energy storage with TiO2 dopant and experimental study in a fixed-bed reactor," Energy, Elsevier, vol. 236(C).
    • Handle: RePEc:eee:energy:v:236:y:2021:i:c:s0360544221016996
    DOI: 10.1016/j.energy.2021.121451
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221016996
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.121451?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Han, Rui & Gao, Jihui & Wei, Siyu & Su, Yanlin & Sun, Fei & Zhao, Guangbo & Qin, Yukun, 2018. "Strongly coupled calcium carbonate/antioxidative graphite nanosheets composites with high cycling stability for thermochemical energy storage," Applied Energy, Elsevier, vol. 231(C), pages 412-422.
    2. Sánchez Jiménez, Pedro E. & Perejón, Antonio & Benítez Guerrero, Mónica & Valverde, José M. & Ortiz, Carlos & Pérez Maqueda, Luis A., 2019. "High-performance and low-cost macroporous calcium oxide based materials for thermochemical energy storage in concentrated solar power plants," Applied Energy, Elsevier, vol. 235(C), pages 543-552.
    3. Chauvy, Remi & Meunier, Nicolas & Thomas, Diane & De Weireld, Guy, 2019. "Selecting emerging CO2 utilization products for short- to mid-term deployment," Applied Energy, Elsevier, vol. 236(C), pages 662-680.
    4. Abedin, Ali Haji & Rosen, Marc A., 2012. "Closed and open thermochemical energy storage: Energy- and exergy-based comparisons," Energy, Elsevier, vol. 41(1), pages 83-92.
    5. Larissa Fedunik-Hofman & Alicia Bayon & Scott W. Donne, 2019. "Kinetics of Solid-Gas Reactions and Their Application to Carbonate Looping Systems," Energies, MDPI, vol. 12(15), pages 1-35, August.
    6. Sun, Hao & Li, Yingjie & Yan, Xianyao & Zhao, Jianli & Wang, Zeyan, 2020. "Thermochemical energy storage performance of Al2O3/CeO2 co-doped CaO-based material under high carbonation pressure," Applied Energy, Elsevier, vol. 263(C).
    7. Yang, Xiaoxia & Tian, Sicong & Kan, Tao & Zhu, Yuxiang & Xu, Honghui & Strezov, Vladimir & Nelson, Peter & Jiang, Yijiao, 2019. "Sorption-enhanced thermochemical conversion of sewage sludge to syngas with intensified carbon utilization," Applied Energy, Elsevier, vol. 254(C).
    8. Meier, Anton & Bonaldi, Enrico & Cella, Gian Mario & Lipinski, Wojciech & Wuillemin, Daniel & Palumbo, Robert, 2004. "Design and experimental investigation of a horizontal rotary reactor for the solar thermal production of lime," Energy, Elsevier, vol. 29(5), pages 811-821.
    9. Pan, Z.H. & Zhao, C.Y., 2017. "Gas–solid thermochemical heat storage reactors for high-temperature applications," Energy, Elsevier, vol. 130(C), pages 155-173.
    10. Xia, B.Q. & Zhao, C.Y. & Yan, J. & Khosa, A.A., 2020. "Development of granular thermochemical heat storage composite based on calcium oxide," Renewable Energy, Elsevier, vol. 147(P1), pages 969-978.
    11. Yan, J. & Zhao, C.Y. & Pan, Z.H., 2017. "The effect of CO2 on Ca(OH)2 and Mg(OH)2 thermochemical heat storage systems," Energy, Elsevier, vol. 124(C), pages 114-123.
    12. Nikulshina, V. & Hirsch, D. & Mazzotti, M. & Steinfeld, A., 2006. "CO2 capture from air and co-production of H2 via the Ca(OH)2–CaCO3 cycle using concentrated solar power–Thermodynamic analysis," Energy, Elsevier, vol. 31(12), pages 1715-1725.
    13. Santos, Sérgio F. & Fitiwi, Desta Z. & Cruz, Marco R.M. & Cabrita, Carlos M.P. & Catalão, João P.S., 2017. "Impacts of optimal energy storage deployment and network reconfiguration on renewable integration level in distribution systems," Applied Energy, Elsevier, vol. 185(P1), pages 44-55.
    14. Khosa, Azhar Abbas & Yan, J. & Zhao, C.Y., 2021. "Investigating the effects of ZnO dopant on the thermodynamic and kinetic properties of CaCO3/CaO TCES system," Energy, Elsevier, vol. 215(PA).
    15. Chen, Xiaoyi & Jin, Xiaogang & Ling, Xiang & Wang, Yan, 2020. "Indirect integration of thermochemical energy storage with the recompression supercritical CO2 Brayton cycle," Energy, Elsevier, vol. 209(C).
    16. Ortiz, C. & Romano, M.C. & Valverde, J.M. & Binotti, M. & Chacartegui, R., 2018. "Process integration of Calcium-Looping thermochemical energy storage system in concentrating solar power plants," Energy, Elsevier, vol. 155(C), pages 535-551.
    17. Chen, Xiaoyi & Jin, Xiaogang & Liu, Zhimin & Ling, Xiang & Wang, Yan, 2018. "Experimental investigation on the CaO/CaCO3 thermochemical energy storage with SiO2 doping," Energy, Elsevier, vol. 155(C), pages 128-138.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Francesca Di Lauro & Claudio Tregambi & Fabio Montagnaro & Laura Molignano & Piero Salatino & Roberto Solimene, 2023. "Influence of Fluidised Bed Inventory on the Performance of Limestone Sorbent in Calcium Looping for Thermochemical Energy Storage," Energies, MDPI, vol. 16(19), pages 1-19, October.
    2. Ying Yang & Yingjie Li & Xianyao Yan & Jianli Zhao & Chunxiao Zhang, 2021. "Development of Thermochemical Heat Storage Based on CaO/CaCO 3 Cycles: A Review," Energies, MDPI, vol. 14(20), pages 1-26, October.
    3. Selvan Bellan & Tatsuya Kodama & Nobuyuki Gokon & Koji Matsubara, 2022. "A review on high‐temperature thermochemical heat storage: Particle reactors and materials based on solid–gas reactions," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 11(5), September.
    4. Chen, Xiaoyi & Dong, Zhenbiao & Zhu, Liujuan & Ling, Xiang, 2023. "Mass transfer performance inside Ca-based thermochemical energy storage materials under different operating conditions," Renewable Energy, Elsevier, vol. 205(C), pages 340-348.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Laurie André & Stéphane Abanades, 2020. "Recent Advances in Thermochemical Energy Storage via Solid–Gas Reversible Reactions at High Temperature," Energies, MDPI, vol. 13(22), pages 1-23, November.
    2. Ying Yang & Yingjie Li & Xianyao Yan & Jianli Zhao & Chunxiao Zhang, 2021. "Development of Thermochemical Heat Storage Based on CaO/CaCO 3 Cycles: A Review," Energies, MDPI, vol. 14(20), pages 1-26, October.
    3. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    4. Sun, Hao & Li, Yingjie & Yan, Xianyao & Zhao, Jianli & Wang, Zeyan, 2020. "Thermochemical energy storage performance of Al2O3/CeO2 co-doped CaO-based material under high carbonation pressure," Applied Energy, Elsevier, vol. 263(C).
    5. Alvarez Rivero, M. & Rodrigues, D. & Pinheiro, C.I.C. & Cardoso, J.P. & Mendes, L.F., 2022. "Solid–gas reactors driven by concentrated solar energy with potential application to calcium looping: A comparative review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    6. Anti Kur & Jo Darkwa & John Calautit & Rabah Boukhanouf & Mark Worall, 2023. "Solid–Gas Thermochemical Energy Storage Materials and Reactors for Low to High-Temperature Applications: A Concise Review," Energies, MDPI, vol. 16(2), pages 1-35, January.
    7. Ma, Zhangke & Li, Yingjie & Zhang, Wan & Wang, Yuzhuo & Zhao, Jianli & Wang, Zeyan, 2020. "Energy storage and attrition performance of limestone under fluidization during CaO/CaCO3 cycles," Energy, Elsevier, vol. 207(C).
    8. Chen, Xiaoyi & Dong, Zhenbiao & Zhu, Liujuan & Ling, Xiang, 2023. "Mass transfer performance inside Ca-based thermochemical energy storage materials under different operating conditions," Renewable Energy, Elsevier, vol. 205(C), pages 340-348.
    9. Ortiz, C. & Valverde, J.M. & Chacartegui, R. & Perez-Maqueda, L.A. & Giménez, P., 2019. "The Calcium-Looping (CaCO3/CaO) process for thermochemical energy storage in Concentrating Solar Power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    10. Chen, Xiaoyi & Jin, Xiaogang & Ling, Xiang & Wang, Yan, 2020. "Indirect integration of thermochemical energy storage with the recompression supercritical CO2 Brayton cycle," Energy, Elsevier, vol. 209(C).
    11. Bravo, Ruben & Ortiz, Carlos & Chacartegui, Ricardo & Friedrich, Daniel, 2021. "Multi-objective optimisation and guidelines for the design of dispatchable hybrid solar power plants with thermochemical energy storage," Applied Energy, Elsevier, vol. 282(PB).
    12. Meroueh, Laureen & Yenduru, Karthik & Dasgupta, Arindam & Jiang, Duo & AuYeung, Nick, 2019. "Energy storage based on SrCO3 and Sorbents—A probabilistic analysis towards realizing solar thermochemical power plants," Renewable Energy, Elsevier, vol. 133(C), pages 770-786.
    13. Yan, Xianyao & Li, Yingjie & Sun, Chaoying & Zhang, Chunxiao & Yang, Liguo & Fan, Xiaoxu & Chu, Leizhe, 2022. "Enhanced H2 production from steam gasification of biomass by red mud-doped Ca-Al-Ce bi-functional material," Applied Energy, Elsevier, vol. 312(C).
    14. Cabeza, Luisa F. & de Gracia, Alvaro & Zsembinszki, Gabriel & Borri, Emiliano, 2021. "Perspectives on thermal energy storage research," Energy, Elsevier, vol. 231(C).
    15. Carro, A. & Chacartegui, R. & Ortiz, C. & Becerra, J.A., 2022. "Analysis of a thermochemical energy storage system based on the reversible Ca(OH)2/CaO reaction," Energy, Elsevier, vol. 261(PA).
    16. Dizaji, Hossein Beidaghy & Hosseini, Hannaneh, 2018. "A review of material screening in pure and mixed-metal oxide thermochemical energy storage (TCES) systems for concentrated solar power (CSP) applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 98(C), pages 9-26.
    17. Nobuyuki Gokon & Kosuke Hayashi & Hiroki Sawaguri & Fumiya Ohashi, 2022. "Long-Term Thermal Cycling Test and Heat-Charging Kinetics of Fe-Substituted Mn 2 O 3 for Next-Generation Concentrated Solar Power Using Thermochemical Energy Storage at High Temperatures," Energies, MDPI, vol. 15(13), pages 1-23, June.
    18. Jiří Bojanovský & Vítězslav Máša & Igor Hudák & Pavel Skryja & Josef Hopjan, 2022. "Rotary Kiln, a Unit on the Border of the Process and Energy Industry—Current State and Perspectives," Sustainability, MDPI, vol. 14(21), pages 1-34, October.
    19. Pan, Z.H. & Zhao, C.Y., 2017. "Gas–solid thermochemical heat storage reactors for high-temperature applications," Energy, Elsevier, vol. 130(C), pages 155-173.
    20. Koepf, E. & Alxneit, I. & Wieckert, C. & Meier, A., 2017. "A review of high temperature solar driven reactor technology: 25years of experience in research and development at the Paul Scherrer Institute," Applied Energy, Elsevier, vol. 188(C), pages 620-651.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:236:y:2021:i:c:s0360544221016996. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.