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Kinetics of Solid-Gas Reactions and Their Application to Carbonate Looping Systems

Author

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  • Larissa Fedunik-Hofman

    (Discipline of Chemistry, University of Newcastle, Callaghan, NSW 2308, Australia
    CSIRO Energy, P.O. Box 330, Newcastle, NSW 2300, Australia)

  • Alicia Bayon

    (CSIRO Energy, P.O. Box 330, Newcastle, NSW 2300, Australia)

  • Scott W. Donne

    (Discipline of Chemistry, University of Newcastle, Callaghan, NSW 2308, Australia)

Abstract

Reaction kinetics is an important field of study in chemical engineering to translate laboratory-scale studies to large-scale reactor conditions. The procedures used to determine kinetic parameters (activation energy, pre-exponential factor and the reaction model) include model-fitting, model-free and generalized methods, which have been extensively used in published literature to model solid-gas reactions. A comprehensive review of kinetic analysis methods will be presented using the example of carbonate looping, an important process applied to thermochemical energy storage and carbon capture technologies. The kinetic parameters obtained by different methods for both the calcination and carbonation reactions are compared. The experimental conditions, material properties and the kinetic method are found to strongly influence the kinetic parameters and recommendations are provided for the analysis of both reactions. Of the methods, isoconversional techniques are encouraged to arrive at non-mechanistic parameters for calcination, while for carbonation, material characterization is recommended before choosing a specific kinetic analysis method.

Suggested Citation

  • Larissa Fedunik-Hofman & Alicia Bayon & Scott W. Donne, 2019. "Kinetics of Solid-Gas Reactions and Their Application to Carbonate Looping Systems," Energies, MDPI, vol. 12(15), pages 1-35, August.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:15:p:2981-:d:254065
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    References listed on IDEAS

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    4. Xu, T.X. & Tian, X.K. & Khosa, A.A. & Yan, J. & Ye, Q. & Zhao, C.Y., 2021. "Reaction performance of CaCO3/CaO thermochemical energy storage with TiO2 dopant and experimental study in a fixed-bed reactor," Energy, Elsevier, vol. 236(C).
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    6. Akinola, Toluleke E. & Bonilla Prado, Phebe L. & Wang, Meihong, 2022. "Experimental studies, molecular simulation and process modelling\simulation of adsorption-based post-combustion carbon capture for power plants: A state-of-the-art review," Applied Energy, Elsevier, vol. 317(C).

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