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Thermodynamic properties of ammonia–water mixtures for power-cycle applications

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  • Xu, Feng
  • Goswami, D.Yogi

Abstract

Ammonia–water mixtures have been used as working fluids in absorption–refrigeration cycles for several decades. Their use as multi-component working fluids for power cycles has been investigated recently. The thermodynamic properties required are known or may be calculated at elevated temperatures and pressures. We present a new method for these computations using Gibbs free energies and empirical equations for bubble and dew point temperature to calculate phase equilibria. Comparisons of calculated and experimental data show excellent agreement.

Suggested Citation

  • Xu, Feng & Goswami, D.Yogi, 1999. "Thermodynamic properties of ammonia–water mixtures for power-cycle applications," Energy, Elsevier, vol. 24(6), pages 525-536.
    • Handle: RePEc:eee:energy:v:24:y:1999:i:6:p:525-536
    DOI: 10.1016/S0360-5442(99)00007-9
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    Cited by:

    1. Sochard, Sabine & Castillo Garcia, Lorenzo & Serra, Sylvain & Vitupier, Yann & Reneaume, Jean-Michel, 2017. "Modelling a solar absorption chiller using positive flash to estimate the physical state of streams and theoretical plate concept for the generator," Renewable Energy, Elsevier, vol. 109(C), pages 121-134.
    2. Zare, V. & Mahmoudi, S.M.S. & Yari, M., 2013. "An exergoeconomic investigation of waste heat recovery from the Gas Turbine-Modular Helium Reactor (GT-MHR) employing an ammonia–water power/cooling cycle," Energy, Elsevier, vol. 61(C), pages 397-409.
    3. Battisti, Felipe G. & Cardemil, José M. & da Silva, Alexandre K., 2016. "A multivariable optimization of a Brayton power cycle operating with CO2 as working fluid," Energy, Elsevier, vol. 112(C), pages 908-916.
    4. Ustaoglu, Abid, 2020. "Parametric study of absorption refrigeration with vapor compression refrigeration cycle using wet, isentropic and azeotropic working fluids: Conventional and advanced exergy approach," Energy, Elsevier, vol. 201(C).
    5. Ayou, Dereje S. & Bruno, Joan Carles & Saravanan, Rajagopal & Coronas, Alberto, 2013. "An overview of combined absorption power and cooling cycles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 728-748.
    6. Peng, Shuo & Hong, Hui & Jin, Hongguang & Wang, Zhifeng, 2012. "An integrated solar thermal power system using intercooled gas turbine and Kalina cycle," Energy, Elsevier, vol. 44(1), pages 732-740.
    7. Vijayaraghavan, S. & Goswami, D.Y., 2006. "A combined power and cooling cycle modified to improve resource utilization efficiency using a distillation stage," Energy, Elsevier, vol. 31(8), pages 1177-1196.
    8. Kyoung Hoon Kim & Chul Ho Han & Hyung Jong Ko, 2018. "Comparative Thermodynamic Analysis of Kalina and Kalina Flash Cycles for Utilizing Low-Grade Heat Sources," Energies, MDPI, vol. 11(12), pages 1-14, November.
    9. Saffari, Hamid & Sadeghi, Sadegh & Khoshzat, Mohsen & Mehregan, Pooyan, 2016. "Thermodynamic analysis and optimization of a geothermal Kalina cycle system using Artificial Bee Colony algorithm," Renewable Energy, Elsevier, vol. 89(C), pages 154-167.
    10. Kyoung Hoon Kim, 2019. "Thermodynamic Analysis of Kalina Based Power and Cooling Cogeneration Cycle Employed Once Through Configuration," Energies, MDPI, vol. 12(8), pages 1-17, April.
    11. Zhang, Xinxin & He, Maogang & Zhang, Ying, 2012. "A review of research on the Kalina cycle," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5309-5318.
    12. Wang, J.L. & Zhao, L. & Wang, X.D., 2012. "An experimental study on the recuperative low temperature solar Rankine cycle using R245fa," Applied Energy, Elsevier, vol. 94(C), pages 34-40.
    13. Wang, Jiangfeng & Dai, Yiping & Gao, Lin, 2008. "Parametric analysis and optimization for a combined power and refrigeration cycle," Applied Energy, Elsevier, vol. 85(11), pages 1071-1085, November.
    14. Ben Ezzine, N. & Garma, R. & Bellagi, A., 2010. "A numerical investigation of a diffusion-absorption refrigeration cycle based on R124-DMAC mixture for solar cooling," Energy, Elsevier, vol. 35(5), pages 1874-1883.
    15. Mendiburu, Andrés Z. & Roberts, Justo J. & Rodrigues, Letícia Jenisch & Verma, Sujit Kr, 2023. "Thermodynamic modelling for absorption refrigeration cycles powered by solar energy and a case study for Porto Alegre, Brazil," Energy, Elsevier, vol. 266(C).
    16. Bahlouli, K. & Khoshbakhti Saray, R. & Sarabchi, N., 2015. "Parametric investigation and thermo-economic multi-objective optimization of an ammonia–water power/cooling cycle coupled with an HCCI (homogeneous charge compression ignition) engine," Energy, Elsevier, vol. 86(C), pages 672-684.
    17. Tan, Luzhi & Dong, Xiaoming & Gong, Zhiqiang & Wang, Mingtao, 2017. "Investigation on performance of an integrated SOFC-GE-KC power generation system using gaseous fuel from biomass gasification," Renewable Energy, Elsevier, vol. 107(C), pages 448-461.
    18. Singh, Omendra Kumar & Kaushik, Subhash C., 2013. "Reducing CO2 emission and improving exergy based performance of natural gas fired combined cycle power plants by coupling Kalina cycle," Energy, Elsevier, vol. 55(C), pages 1002-1013.
    19. Brian Agnew & Sara Walker & Bobo Ng & Ivan C. K. Tam, 2015. "Finite Time Analysis of a Tri-Generation Cycle," Energies, MDPI, vol. 8(6), pages 1-15, June.
    20. Padilla, Ricardo Vasquez & Demirkaya, Gökmen & Goswami, D. Yogi & Stefanakos, Elias & Rahman, Muhammad M., 2010. "Analysis of power and cooling cogeneration using ammonia-water mixture," Energy, Elsevier, vol. 35(12), pages 4649-4657.
    21. Kim, Kyoung Hoon & Ko, Hyung Jong & Kim, Kyoungjin, 2014. "Assessment of pinch point characteristics in heat exchangers and condensers of ammonia–water based power cycles," Applied Energy, Elsevier, vol. 113(C), pages 970-981.
    22. Xu, Feng & Yogi Goswami, D & S. Bhagwat, Sunil, 2000. "A combined power/cooling cycle," Energy, Elsevier, vol. 25(3), pages 233-246.
    23. Moradpoor, Iraj & Ebrahimi, Masood, 2019. "Thermo-environ analyses of a novel trigeneration cycle based on clean technologies of molten carbonate fuel cell, stirling engine and Kalina cycle," Energy, Elsevier, vol. 185(C), pages 1005-1016.

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