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Effect of heat-treatment on the performance of PtM/C (M = Cr, Pd, Co) catalysts towards the oxygen reduction reaction in PEM fuel cell

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  • Chaisubanan, Napapat
  • Maniwan, Witchaya
  • Hunsom, Mali

Abstract

Effect of heat-treatment on the performance of the PtM/C (M = Cr, Pd, Co) catalysts towards the oxygen reduction reaction (ORR) in acid solution and in proton exchange membrane (PEM) fuel cell was explored. Compared with the Pt/C catalyst, the heat-treatment induced the formation of a more crystallite PtM structure and an agglomeration of Pt particles in all PtM catalysts, resulting in a decreased electrochemical surface area (ESA). Besides, the heat-treatment increased the electrical conductivity, which consequently affected the ORR activity and stability of the PtM/C catalyst. Among all prepared PtM/C catalysts, the PtCo/C catalyst exhibited the highest ORR activity, with a current density of around 392.8 mA/cm2 (235.7 mW/cm2) at 0.6 V under a H2/air environment at 60 °C and ambient pressure with the ESA loss of 58.7% after 500 cycles of cyclic voltamogram (CV). Heat-treatment of this catalyst under a N2 atmosphere slightly decreased the ORR activity by 3.41% but significantly increased the stability by ∼17.2%.

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  • Chaisubanan, Napapat & Maniwan, Witchaya & Hunsom, Mali, 2017. "Effect of heat-treatment on the performance of PtM/C (M = Cr, Pd, Co) catalysts towards the oxygen reduction reaction in PEM fuel cell," Energy, Elsevier, vol. 127(C), pages 454-461.
    • Handle: RePEc:eee:energy:v:127:y:2017:i:c:p:454-461
    DOI: 10.1016/j.energy.2017.03.162
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    2. Miao, He & Wang, Zhouhang & Wang, Qin & Sun, Shanshan & Xue, Yejian & Wang, Fu & Zhao, Jiapei & Liu, Zhaoping & Yuan, Jinliang, 2018. "A new family of Mn-based perovskite (La1-xYxMnO3) with improved oxygen electrocatalytic activity for metal-air batteries," Energy, Elsevier, vol. 154(C), pages 561-570.
    3. Bhuvanendran, Narayanamoorthy & Ravichandran, Sabarinathan & Jayaseelan, Santhana Sivabalan & Xu, Qian & Khotseng, Lindiwe & Su, Huaneng, 2020. "Improved bi-functional oxygen electrocatalytic performance of Pt–Ir alloy nanoparticles embedded on MWCNT with Pt-enriched surfaces," Energy, Elsevier, vol. 211(C).
    4. Ogungbemi, Emmanuel & Ijaodola, Oluwatosin & Khatib, F.N. & Wilberforce, Tabbi & El Hassan, Zaki & Thompson, James & Ramadan, Mohamad & Olabi, A.G., 2019. "Fuel cell membranes – Pros and cons," Energy, Elsevier, vol. 172(C), pages 155-172.
    5. Yuan, Wenjing & Xu, Wanghua & Xie, Anjian & Zhang, Hui & Wang, Cuiping & Shen, Yuhua, 2017. "An effective strategy for the preparation of nitrogen-doped carbon from Imperata cylindrica panicle and its use as a metal-free catalyst for the oxygen reduction reaction," Energy, Elsevier, vol. 141(C), pages 1324-1331.
    6. Flores-Lasluisa, J.X. & Huerta, F. & Cazorla-Amorós, D. & Morallón, E., 2023. "LaNi1-xCoxO3 perovskites for application in electrochemical reactions involving molecular oxygen," Energy, Elsevier, vol. 273(C).

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