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Application of zeolitic materials prepared from fly ash to water vapor adsorption for solar cooling

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  • Karamanis, D.
  • Vardoulakis, E.

Abstract

The water vapor adsorption properties of raw and hydrothermally treated fly ashes with NaOH and their application prospect as evaporative coolers of roof surfaces were studied. Initially, samples were characterized through techniques like elemental analysis, X-ray diffraction, thermogravimetry, reflectance measurements and water vapor adsorption isotherms. Moreover, the water adsorption properties and the associated temperature variations were determined in a specific wind tunnel with controllable environmental conditions. The adsorption isotherms for fly ash were of type III indicating hydrophobic material with low water vapor adsorption. The hydrothermal treatment in an alkaline solution transformed the fly ash in hydrophilic material of type IV. Moreover, the treated samples were capable of lowering their surface temperatures due to water evaporation and the release of the latent heat. The maximum difference of temperature increase under simulated solar irradiation was observed between the treated fly ash and the concrete with values of 5.0, 5.4 and 7.5°C for the surface, middle and bottom position, respectively. The results indicate that the zeolitic materials prepared from the fly ash samples have a significant potential for solar cooling applications.

Suggested Citation

  • Karamanis, D. & Vardoulakis, E., 2012. "Application of zeolitic materials prepared from fly ash to water vapor adsorption for solar cooling," Applied Energy, Elsevier, vol. 97(C), pages 334-339.
  • Handle: RePEc:eee:appene:v:97:y:2012:i:c:p:334-339
    DOI: 10.1016/j.apenergy.2011.12.078
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    5. Hassan, H.Z. & Mohamad, A.A. & Al-Ansary, H.A. & Alyousef, Y.M., 2014. "Dynamic analysis of the CTAR (constant temperature adsorption refrigeration) cycle," Energy, Elsevier, vol. 77(C), pages 852-858.
    6. Ji, Xu & Li, Ming & Fan, Jieqing & Zhang, Peng & Luo, Bin & Wang, Liuling, 2014. "Structure optimization and performance experiments of a solar-powered finned-tube adsorption refrigeration system," Applied Energy, Elsevier, vol. 113(C), pages 1293-1300.
    7. Solmuş, İsmail & Yamalı, Cemil & Yıldırım, Cihan & Bilen, Kadir, 2015. "Transient behavior of a cylindrical adsorbent bed during the adsorption process," Applied Energy, Elsevier, vol. 142(C), pages 115-124.
    8. Mahesh, A., 2017. "Solar collectors and adsorption materials aspects of cooling system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 1300-1312.
    9. Hassan Zohair Hassan, 2014. "Performance Evaluation of a Continuous Operation Adsorption Chiller Powered by Solar Energy Using Silica Gel and Water as the Working Pair," Energies, MDPI, vol. 7(10), pages 1-19, October.
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    12. Agata Mlonka-Mędrala, 2023. "Recent Findings on Fly Ash-Derived Zeolites Synthesis and Utilization According to the Circular Economy Concept," Energies, MDPI, vol. 16(18), pages 1-21, September.

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