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Local impact of load cycling on degradation in polymer electrolyte fuel cells

Author

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  • Garcia-Sanchez, D.
  • Morawietz, T.
  • da Rocha, P. Gama
  • Hiesgen, R.
  • Gazdzicki, P.
  • Friedrich, K.A.

Abstract

Degradation mechanisms occurring during proton exchange membrane fuel cells (PEMFC) operation critically depend on the applied electrical load profile. In this work, durability tests were performed using different load cycling ranges. The tests include refresh procedures in order to recover temporary performance losses. Operando current density distribution measurements as well as electrochemical characterization techniques were applied to obtain essential data for understanding degradation behavior of the components of the membrane electrode assembly (MEA). The analysis is supported by scanning electron microscopy (SEM) and energy dispersive x-ray diffraction (EDX) analysis of MEA components. Dynamic load cycling has proven to lead to lower performance losses as compared to constant load operation. Moreover, reversible performance losses were associated with an increased heterogeneity of the current density distribution along the flow field. Thereby, areas with high local current density exhibit particularly strong Pt band formation in the membrane linked with a thinning of the cathode catalyst layer.

Suggested Citation

  • Garcia-Sanchez, D. & Morawietz, T. & da Rocha, P. Gama & Hiesgen, R. & Gazdzicki, P. & Friedrich, K.A., 2020. "Local impact of load cycling on degradation in polymer electrolyte fuel cells," Applied Energy, Elsevier, vol. 259(C).
    • Handle: RePEc:eee:appene:v:259:y:2020:i:c:s0306261919318975
    DOI: 10.1016/j.apenergy.2019.114210
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    References listed on IDEAS

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    1. Pérez, Luis C. & Brandão, Lúcia & Sousa, José M. & Mendes, Adélio, 2011. "Segmented polymer electrolyte membrane fuel cells--A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 169-185, January.
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    3. Panha, Karachakorn & Fowler, Michael & Yuan, Xiao-Zi & Wang, Haijiang, 2012. "Accelerated durability testing via reactants relative humidity cycling on PEM fuel cells," Applied Energy, Elsevier, vol. 93(C), pages 90-97.
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    Cited by:

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    3. Indro Biswas & Daniel G. Sánchez & Mathias Schulze & Jens Mitzel & Benjamin Kimmel & Aldo Saul Gago & Pawel Gazdzicki & K. Andreas Friedrich, 2020. "Advancement of Segmented Cell Technology in Low Temperature Hydrogen Technologies," Energies, MDPI, vol. 13(9), pages 1-22, May.
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    5. Zou, Wei & Froning, Dieter & Shi, Yan & Lehnert, Werner, 2021. "An online adaptive model for the nonlinear dynamics of fuel cell voltage," Applied Energy, Elsevier, vol. 288(C).
    6. Zhang, Qian & Schulze, Mathias & Gazdzicki, Pawel & Friedrich, K. Andreas, 2021. "Comparison of different performance recovery procedures for polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 302(C).
    7. Yin, Cong & Cao, Jishen & Tang, Qilin & Su, Yanghuai & Wang, Renkang & Li, Kai & Tang, Hao, 2022. "Study of internal performance of commercial-size fuel cell stack with 3D multi-physical model and high resolution current mapping," Applied Energy, Elsevier, vol. 323(C).
    8. Ding, Feng & Zou, Tingting & Wei, Tao & Chen, Lei & Qin, Xiaoping & Shao, Zhigang & Yang, Jianjun, 2023. "The pinhole effect on proton exchange membrane fuel cell (PEMFC) current density distribution and temperature distribution," Applied Energy, Elsevier, vol. 342(C).
    9. Meng, Kai & Chen, Ben & Zhou, Haoran & Shen, Jun & Shen, Zuguo & Tu, Zhengkai, 2022. "Investigation on degradation mechanism of hydrogen–oxygen proton exchange membrane fuel cell under current cyclic loading," Energy, Elsevier, vol. 242(C).

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