IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v251y2019ic58.html
   My bibliography  Save this article

Thermal arc plasma gasification of waste glycerol to syngas

Author

Listed:
  • Tamošiūnas, Andrius
  • Gimžauskaitė, Dovilė
  • Uscila, Rolandas
  • Aikas, Mindaugas

Abstract

In this experimental study, waste glycerol gasification to syngas was investigated by utilizing direct current thermal arc plasma of 46–62 kW power. Two gasifying mediums were used: water vapor and air. The plasma-chemical reactor capacity exceeded up to 39 kg/h. Glycerol gasification to synthesis gas process was evaluated in terms of the H2/CO ratio, H2 and CO yield, energy conversion efficiency, carbon conversion efficiency, and specific energy requirements. Experimental results were compared between and also with other research work. Water vapor used as the main gasifying medium for waste glycerol utilization to syngas demonstrated a higher process performance over the air used. Full waste glycerol conversion to synthesis gas was achieved for the case of water vapor, whereas that in the case of air gasification only 75.7%. The lower heating value of the produced syngas exceeded 9.82 MJ/Nm3 and 7.32 MJ/Nm3 for the water vapor plasma and air plasma gasification, respectively. The energy conversion efficiency was calculated to be higher for the water vapor used as a gasifying agent exceeding 63.86%, whereas that of the air plasma gasification only 43.64%. The specific energy consumption required to treat one kilogram of waste glycerol in the environment of water vapor plasma accounted to 191.6 kJ/mol and 266.45 kJ/mol for the air plasma treatment. As conclusion, it was demonstrated that syngas can be successfully produced from waste glycerol by both water vapor and air plasma gasification. However, the use of water vapor as a gasifying agent gave a better process efficiency over the air in all the parameters studied.

Suggested Citation

  • Tamošiūnas, Andrius & Gimžauskaitė, Dovilė & Uscila, Rolandas & Aikas, Mindaugas, 2019. "Thermal arc plasma gasification of waste glycerol to syngas," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    • Handle: RePEc:eee:appene:v:251:y:2019:i:c:58
    DOI: 10.1016/j.apenergy.2019.113306
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261919309687
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2019.113306?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kong, Pei San & Aroua, Mohamed Kheireddine & Daud, Wan Mohd Ashri Wan, 2016. "Conversion of crude and pure glycerol into derivatives: A feasibility evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 533-555.
    2. Abel Rodrigues & João Carlos Bordado & Rui Galhano dos Santos, 2017. "Upgrading the Glycerol from Biodiesel Production as a Source of Energy Carriers and Chemicals—A Technological Review for Three Chemical Pathways," Energies, MDPI, vol. 10(11), pages 1-36, November.
    3. Cheng Li & Keaton L. Lesnik & Hong Liu, 2013. "Microbial Conversion of Waste Glycerol from Biodiesel Production into Value-Added Products," Energies, MDPI, vol. 6(9), pages 1-30, September.
    4. Fantozzi, F. & Frassoldati, A. & Bartocci, P. & Cinti, G. & Quagliarini, F. & Bidini, G. & Ranzi, E.M., 2016. "An experimental and kinetic modeling study of glycerol pyrolysis," Applied Energy, Elsevier, vol. 184(C), pages 68-76.
    5. He, Quan (Sophia) & McNutt, Josiah & Yang, Jie, 2017. "Utilization of the residual glycerol from biodiesel production for renewable energy generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 63-76.
    6. Quispe, César A.G. & Coronado, Christian J.R. & Carvalho Jr., João A., 2013. "Glycerol: Production, consumption, prices, characterization and new trends in combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 475-493.
    7. Zhang, Ming & Xue, Wenfeng & Su, Baogen & Bao, Zongbi & Wen, Guangdong & Xing, Huabin & Ren, Qilong, 2017. "Conversion of glycerol into syngas by rotating DC arc plasma," Energy, Elsevier, vol. 123(C), pages 1-8.
    8. Abdul Ghani, Ahmad & Torabi, Farshid & Ibrahim, Hussameldin, 2018. "Autothermal reforming process for efficient hydrogen production from crude glycerol using nickel supported catalyst: Parametric and statistical analyses," Energy, Elsevier, vol. 144(C), pages 129-145.
    9. Budžaki, Sandra & Miljić, Goran & Tišma, Marina & Sundaram, Smitha & Hessel, Volker, 2017. "Is there a future for enzymatic biodiesel industrial production in microreactors?," Applied Energy, Elsevier, vol. 201(C), pages 124-134.
    10. Tran, Dang-Thuan & Chang, Jo-Shu & Lee, Duu-Jong, 2017. "Recent insights into continuous-flow biodiesel production via catalytic and non-catalytic transesterification processes," Applied Energy, Elsevier, vol. 185(P1), pages 376-409.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chu, C. & Boré, A. & Liu, X.W. & Cui, J.C. & Wang, P. & Liu, X. & Chen, G.Y. & Liu, B. & Ma, W.C. & Lou, Z.Y. & Tao, Y. & Bary, A., 2022. "Modeling the impact of some independent parameters on the syngas characteristics during plasma gasification of municipal solid waste using artificial neural network and stepwise linear regression meth," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    2. Lu, Lianmei & Liu, Wu & Wang, Jianxin & Wang, Yudong & Xia, Changrong & Zhou, Xiao-Dong & Chen, Ming & Guan, Wanbing, 2020. "Long-term stability of carbon dioxide electrolysis in a large-scale flat-tube solid oxide electrolysis cell based on double-sided air electrodes," Applied Energy, Elsevier, vol. 259(C).
    3. Andrius Tamošiūnas & Dovilė Gimžauskaitė & Mindaugas Aikas & Rolandas Uscila & Marius Praspaliauskas & Justas Eimontas, 2019. "Gasification of Waste Cooking Oil to Syngas by Thermal Arc Plasma," Energies, MDPI, vol. 12(13), pages 1-13, July.
    4. Fang, Neng & Li, Zhengqi & Liu, Shuxuan & Xie, Cheng & Zeng, Lingyan & Chen, Zhichao, 2021. "Experimental air/particle flow characteristics of an 80,000 Nm3/h fly ash entrained-flow gasifier with different multi-burner arrangements," Energy, Elsevier, vol. 215(PB).
    5. Chu, Chu & Wang, Ping & Boré, Abdoulaye & Ma, Wenchao & Chen, Guanyi & Wang, Pan, 2023. "Thermal plasma co-gasification of polyvinylchloride and biomass mixtures under steam atmospheres: Gasification characteristics and chlorine release behavior," Energy, Elsevier, vol. 262(PB).
    6. Henryka Danuta Stryczewska & Mariusz Adam Stępień & Oleksandr Boiko, 2022. "Plasma and Superconductivity for the Sustainable Development of Energy and the Environment," Energies, MDPI, vol. 15(11), pages 1-30, June.
    7. Moreira, Rui & Bimbela, Fernando & Gandía, Luis M. & Ferreira, Abel & Sánchez, Jose Luis & Portugal, António, 2021. "Oxidative steam reforming of glycerol. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Is Fatimah & Imam Sahroni & Ganjar Fadillah & Muhammad Miqdam Musawwa & Teuku Meurah Indra Mahlia & Oki Muraza, 2019. "Glycerol to Solketal for Fuel Additive: Recent Progress in Heterogeneous Catalysts," Energies, MDPI, vol. 12(15), pages 1-14, July.
    2. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Rajaei, Kourosh & Tarighi, Sara, 2018. "Oxidation of bio-renewable glycerol to value-added chemicals through catalytic and electro-chemical processes," Applied Energy, Elsevier, vol. 230(C), pages 1347-1379.
    3. Cornejo, A. & Barrio, I. & Campoy, M. & Lázaro, J. & Navarrete, B., 2017. "Oxygenated fuel additives from glycerol valorization. Main production pathways and effects on fuel properties and engine performance: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1400-1413.
    4. Francesco Asdrubali & Franco Cotana & Federico Rossi & Andrea Presciutti & Antonella Rotili & Claudia Guattari, 2015. "Life Cycle Assessment of New Oxy-Fuels from Biodiesel-Derived Glycerol," Energies, MDPI, vol. 8(3), pages 1-16, February.
    5. He, Quan (Sophia) & McNutt, Josiah & Yang, Jie, 2017. "Utilization of the residual glycerol from biodiesel production for renewable energy generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 63-76.
    6. Moreira, Rui & Bimbela, Fernando & Gandía, Luis M. & Ferreira, Abel & Sánchez, Jose Luis & Portugal, António, 2021. "Oxidative steam reforming of glycerol. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    7. Stanislaw Szwaja & Michal Gruca & Michal Pyrc & Romualdas Juknelevičius, 2021. "Performance and Exhaust Emissions of a Spark Ignition Internal Combustion Engine Fed with Butanol–Glycerol Blend," Energies, MDPI, vol. 14(20), pages 1-15, October.
    8. Sedghi, Reza & Shahbeik, Hossein & Rastegari, Hajar & Rafiee, Shahin & Peng, Wanxi & Nizami, Abdul-Sattar & Gupta, Vijai Kumar & Chen, Wei-Hsin & Lam, Su Shiung & Pan, Junting & Tabatabaei, Meisam & A, 2022. "Turning biodiesel glycerol into oxygenated fuel additives and their effects on the behavior of internal combustion engines: A comprehensive systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    9. Zhang, Jianan & Wang, Yuesen & Muldoon, Valerie L. & Deng, Sili, 2022. "Crude glycerol and glycerol as fuels and fuel additives in combustion applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    10. Zhao, Man & Wang, Yanan & Zhou, Wenting & Zhou, Wei & Gong, Zhiwei, 2023. "Co-valorization of crude glycerol and low-cost substrates via oleaginous yeasts to micro-biodiesel: Status and outlook," Renewable and Sustainable Energy Reviews, Elsevier, vol. 180(C).
    11. Muhammad Harussani Moklis & Shou Cheng & Jeffrey S. Cross, 2023. "Current and Future Trends for Crude Glycerol Upgrading to High Value-Added Products," Sustainability, MDPI, vol. 15(4), pages 1-30, February.
    12. Metawea, Rodaina & Zewail, Taghreed & El-Ashtoukhy, El-Sayed & El Gheriany, Iman & Hamad, Hesham, 2018. "Process intensification of the transesterification of palm oil to biodiesel in a batch agitated vessel provided with mesh screen extended baffles," Energy, Elsevier, vol. 158(C), pages 111-120.
    13. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    14. Chuepeng, Sathaporn & Komintarachat, Cholada, 2018. "Interesterification optimization of waste cooking oil and ethyl acetate over homogeneous catalyst for biofuel production with engine validation," Applied Energy, Elsevier, vol. 232(C), pages 728-739.
    15. Sidhu, Manpreet Singh & Roy, Murari Mohon & Wang, Wilson, 2018. "Glycerine emulsions of diesel-biodiesel blends and their performance and emissions in a diesel engine," Applied Energy, Elsevier, vol. 230(C), pages 148-159.
    16. Robert White & Freddy Segundo Navarro-Pineda & Timothy Cockerill & Valerie Dupont & Julio César Sacramento Rivero, 2019. "Techno-Economic and Life Cycle Impacts Analysis of Direct Methanation of Glycerol to Bio-Synthetic Natural Gas at a Biodiesel Refinery," Energies, MDPI, vol. 12(4), pages 1-20, February.
    17. Michal Gruca & Michal Pyrc & Magdalena Szwaja & Stanislaw Szwaja, 2020. "Effective Combustion of Glycerol in a Compression Ignition Engine Equipped with Double Direct Fuel Injection," Energies, MDPI, vol. 13(23), pages 1-14, December.
    18. Alves, Luís & Pereira, Vítor & Lagarteira, Tiago & Mendes, Adélio, 2021. "Catalytic methane decomposition to boost the energy transition: Scientific and technological advancements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    19. Wu, Zuliang & Zhou, Weili & Hao, Xiaodong & Zhang, Xuming, 2019. "Plasma reforming of n-pentane as a simulated gasoline to hydrogen and cleaner carbon-based fuels," Energy, Elsevier, vol. 189(C).
    20. Emilia Neag & Zamfira Stupar & S. Andrada Maicaneanu & Cecilia Roman, 2023. "Advances in Biodiesel Production from Microalgae," Energies, MDPI, vol. 16(3), pages 1-18, January.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:251:y:2019:i:c:58. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.