IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v230y2018icp1347-1379.html
   My bibliography  Save this article

Oxidation of bio-renewable glycerol to value-added chemicals through catalytic and electro-chemical processes

Author

Listed:
  • Talebian-Kiakalaieh, Amin
  • Amin, Nor Aishah Saidina
  • Rajaei, Kourosh
  • Tarighi, Sara

Abstract

Due to its unique structure, characteristics, and bio-availability, glycerol transformation into value-added chemicals has been in the spotlight in recent years. This study provides a comprehensive review and critical analysis on catalytic and electro-chemical oxidation of glycerol into commodity chemicals, which have broad applications to the pharmaceutical, polymer, and food industries. Various synthesis methods (e.g. impregnation, sol-immobilization, incipient wetness, and deposition precipitation) for the preparation of the catalysts are discussed. Catalytic performance of mono-, bi-, multi-, and non-metal supported catalysts on carbon black, activated carbon, graphene, single- or multi wall-carbon nano-tubes, layered-double hydroxides, metal oxides, and polymers are evaluated. Among the methods, sol-immobilization is highly commended since fine metal NPs could be homogeneously distributed on the support, reported as an effective factor for controlling the selectivity of the desired product. In particular, the environmentally benign novel polymeric structures, illustrate significant breakthroughs in production of commodity chemicals compared to the conventional materials. Homogeneous oxidation of glycerol by enzymes and microorganisms also displayed acceptable performance particularly in production of DHA, but at the expense of long reaction time. Unlike the homogenous and heterogeneous catalytic processes, electro-chemical oxidation could be tuned for high product selectivity by controlling the nature, composition and structure of the electro-catalyst as well as the electrode potential. Most importantly, combination of electro-chemical oxidation of glycerol with oxygen or water reduction process in full- and electrolysis-cells, respectively could be the ultimate goal in this field. Simultaneous generation of value-added chemicals and electrical energy would have significant economical and environmental merits compared to the conventional processes. The current state-of-the-art of the glycerol oxidation process and recommendations for further research are also included.

Suggested Citation

  • Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Rajaei, Kourosh & Tarighi, Sara, 2018. "Oxidation of bio-renewable glycerol to value-added chemicals through catalytic and electro-chemical processes," Applied Energy, Elsevier, vol. 230(C), pages 1347-1379.
    • Handle: RePEc:eee:appene:v:230:y:2018:i:c:p:1347-1379
    DOI: 10.1016/j.apenergy.2018.09.006
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261918313072
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.09.006?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Nanda, Malaya R. & Yuan, Zhongshun & Qin, Wensheng & Ghaziaskar, Hassan S. & Poirier, Marc-Andre & Xu, Chunbao (Charles), 2014. "A new continuous-flow process for catalytic conversion of glycerol to oxygenated fuel additive: Catalyst screening," Applied Energy, Elsevier, vol. 123(C), pages 75-81.
    2. Budžaki, Sandra & Miljić, Goran & Sundaram, Smitha & Tišma, Marina & Hessel, Volker, 2018. "Cost analysis of enzymatic biodiesel production in small-scaled packed-bed reactors," Applied Energy, Elsevier, vol. 210(C), pages 268-278.
    3. Azadi, Pooya & Brownbridge, George & Mosbach, Sebastian & Smallbone, Andrew & Bhave, Amit & Inderwildi, Oliver & Kraft, Markus, 2014. "The carbon footprint and non-renewable energy demand of algae-derived biodiesel," Applied Energy, Elsevier, vol. 113(C), pages 1632-1644.
    4. Fantozzi, F. & Frassoldati, A. & Bartocci, P. & Cinti, G. & Quagliarini, F. & Bidini, G. & Ranzi, E.M., 2016. "An experimental and kinetic modeling study of glycerol pyrolysis," Applied Energy, Elsevier, vol. 184(C), pages 68-76.
    5. Varrone, C. & Liberatore, R. & Crescenzi, T. & Izzo, G. & Wang, A., 2013. "The valorization of glycerol: Economic assessment of an innovative process for the bioconversion of crude glycerol into ethanol and hydrogen," Applied Energy, Elsevier, vol. 105(C), pages 349-357.
    6. Tran, Nghiep Nam & Tišma, Marina & Budžaki, Sandra & McMurchie, Edward J. & Gonzalez, Olivia Maria Morales & Hessel, Volker & Ngothai, Yung, 2018. "Scale-up and economic analysis of biodiesel production from recycled grease trap waste," Applied Energy, Elsevier, vol. 229(C), pages 142-150.
    7. Guo, Yong & Azmat, Muhammad Usman & Liu, Xiaohui & Wang, Yanqin & Lu, Guanzhong, 2012. "Effect of support’s basic properties on hydrogen production in aqueous-phase reforming of glycerol and correlation between WGS and APR," Applied Energy, Elsevier, vol. 92(C), pages 218-223.
    8. Liam S. Sharninghausen & Jesús Campos & Michael G. Manas & Robert H. Crabtree, 2014. "Efficient selective and atom economic catalytic conversion of glycerol to lactic acid," Nature Communications, Nature, vol. 5(1), pages 1-9, December.
    9. Tan, H.W. & Abdul Aziz, A.R. & Aroua, M.K., 2013. "Glycerol production and its applications as a raw material: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 118-127.
    10. Zhang, Fang & Zhang, Yan & Chen, Yun & Dai, Kun & van Loosdrecht, Mark C.M. & Zeng, Raymond J., 2015. "Simultaneous production of acetate and methane from glycerol by selective enrichment of hydrogenotrophic methanogens in extreme-thermophilic (70°C) mixed culture fermentation," Applied Energy, Elsevier, vol. 148(C), pages 326-333.
    11. Zhang, Heng & Li, Hu & Pan, Hu & Wang, Anping & Souzanchi, Sadra & Xu, Chunbao (Charles) & Yang, Song, 2018. "Magnetically recyclable acidic polymeric ionic liquids decorated with hydrophobic regulators as highly efficient and stable catalysts for biodiesel production," Applied Energy, Elsevier, vol. 223(C), pages 416-429.
    12. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    13. Trchounian, Karen & Trchounian, Armen, 2015. "Hydrogen production from glycerol by Escherichia coli and other bacteria: An overview and perspectives," Applied Energy, Elsevier, vol. 156(C), pages 174-184.
    14. Quispe, César A.G. & Coronado, Christian J.R. & Carvalho Jr., João A., 2013. "Glycerol: Production, consumption, prices, characterization and new trends in combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 475-493.
    15. Budžaki, Sandra & Miljić, Goran & Tišma, Marina & Sundaram, Smitha & Hessel, Volker, 2017. "Is there a future for enzymatic biodiesel industrial production in microreactors?," Applied Energy, Elsevier, vol. 201(C), pages 124-134.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Is Fatimah & Imam Sahroni & Ganjar Fadillah & Muhammad Miqdam Musawwa & Teuku Meurah Indra Mahlia & Oki Muraza, 2019. "Glycerol to Solketal for Fuel Additive: Recent Progress in Heterogeneous Catalysts," Energies, MDPI, vol. 12(15), pages 1-14, July.
    2. Da Seul Kong & Eun Joo Park & Sakuntala Mutyala & Minsoo Kim & Yunchul Cho & Sang Eun Oh & Changman Kim & Jung Rae Kim, 2021. "Bioconversion of Crude Glycerol into 1,3-Propanediol(1,3-PDO) with Bioelectrochemical System and Zero-Valent Iron Using Klebsiella pneumoniae L17," Energies, MDPI, vol. 14(20), pages 1-10, October.
    3. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Cornejo, A. & Barrio, I. & Campoy, M. & Lázaro, J. & Navarrete, B., 2017. "Oxygenated fuel additives from glycerol valorization. Main production pathways and effects on fuel properties and engine performance: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1400-1413.
    2. Tamošiūnas, Andrius & Gimžauskaitė, Dovilė & Uscila, Rolandas & Aikas, Mindaugas, 2019. "Thermal arc plasma gasification of waste glycerol to syngas," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    3. Is Fatimah & Imam Sahroni & Ganjar Fadillah & Muhammad Miqdam Musawwa & Teuku Meurah Indra Mahlia & Oki Muraza, 2019. "Glycerol to Solketal for Fuel Additive: Recent Progress in Heterogeneous Catalysts," Energies, MDPI, vol. 12(15), pages 1-14, July.
    4. Zhang, Xiaolei & Yan, Song & Tyagi, Rajeshwar D. & Surampalli, RaoY. & Valéro, Jose R., 2014. "Wastewater sludge as raw material for microbial oils production," Applied Energy, Elsevier, vol. 135(C), pages 192-201.
    5. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    6. He, Quan (Sophia) & McNutt, Josiah & Yang, Jie, 2017. "Utilization of the residual glycerol from biodiesel production for renewable energy generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 63-76.
    7. Fantozzi, F. & Frassoldati, A. & Bartocci, P. & Cinti, G. & Quagliarini, F. & Bidini, G. & Ranzi, E.M., 2016. "An experimental and kinetic modeling study of glycerol pyrolysis," Applied Energy, Elsevier, vol. 184(C), pages 68-76.
    8. Hosseinzadeh-Bandbafha, Homa & Nizami, Abdul-Sattar & Kalogirou, Soteris A. & Gupta, Vijai Kumar & Park, Young-Kwon & Fallahi, Alireza & Sulaiman, Alawi & Ranjbari, Meisam & Rahnama, Hassan & Aghbashl, 2022. "Environmental life cycle assessment of biodiesel production from waste cooking oil: A systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    9. Tran, Nghiep Nam & Tišma, Marina & Budžaki, Sandra & McMurchie, Edward J. & Gonzalez, Olivia Maria Morales & Hessel, Volker & Ngothai, Yung, 2018. "Scale-up and economic analysis of biodiesel production from recycled grease trap waste," Applied Energy, Elsevier, vol. 229(C), pages 142-150.
    10. Chamkalani, A. & Zendehboudi, S. & Rezaei, N. & Hawboldt, K., 2020. "A critical review on life cycle analysis of algae biodiesel: current challenges and future prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    11. Seretis, A. & Tsiakaras, P., 2016. "Aqueous phase reforming (APR) of glycerol over platinum supported on Al2O3 catalyst," Renewable Energy, Elsevier, vol. 85(C), pages 1116-1126.
    12. Dutra, Luciana da Silva & Costa Cerqueira Pinto, Martina & Cipolatti, Eliane Pereira & Aguieiras, Erika Cristina G. & Manoel, Evelin Andrade & Greco-Duarte, Jaqueline & Guimarães Freire, Denise Maria , 2022. "How the biodiesel from immobilized enzymes production is going on: An advanced bibliometric evaluation of global research," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).
    13. Hejna, Aleksander & Kosmela, Paulina & Formela, Krzysztof & Piszczyk, Łukasz & Haponiuk, Józef T., 2016. "Potential applications of crude glycerol in polymer technology–Current state and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 66(C), pages 449-475.
    14. Juan Calero & Diego Luna & Carlos Luna & Felipa M. Bautista & Beatriz Hurtado & Antonio A. Romero & Alejandro Posadillo & Rafael Estevez, 2019. "Rhizomucor miehei Lipase Supported on Inorganic Solids, as Biocatalyst for the Synthesis of Biofuels: Improving the Experimental Conditions by Response Surface Methodology," Energies, MDPI, vol. 12(5), pages 1-15, March.
    15. Zhang, Jianan & Wang, Yuesen & Muldoon, Valerie L. & Deng, Sili, 2022. "Crude glycerol and glycerol as fuels and fuel additives in combustion applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    16. Gülşen, Ece & Olivetti, Elsa & Freire, Fausto & Dias, Luis & Kirchain, Randolph, 2014. "Impact of feedstock diversification on the cost-effectiveness of biodiesel," Applied Energy, Elsevier, vol. 126(C), pages 281-296.
    17. Feng, Weiliang & Xiong, Huan & Wang, Weiguo & Duan, Xiaoling & Yang, Tong & Wu, Cheng & Yang, Fang & Wang, Teilin & Wang, Cunwen, 2020. "A facile and mild one-pot process for direct extraction of lipids from wet energy insects of black soldier fly larvae," Renewable Energy, Elsevier, vol. 147(P1), pages 584-593.
    18. Muhammad Harussani Moklis & Shou Cheng & Jeffrey S. Cross, 2023. "Current and Future Trends for Crude Glycerol Upgrading to High Value-Added Products," Sustainability, MDPI, vol. 15(4), pages 1-30, February.
    19. Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.
    20. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:230:y:2018:i:c:p:1347-1379. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.