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Oxygenated fuel additives from glycerol valorization. Main production pathways and effects on fuel properties and engine performance: A critical review

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  • Cornejo, A.
  • Barrio, I.
  • Campoy, M.
  • Lázaro, J.
  • Navarrete, B.

Abstract

The projected growth of biodiesel world production has led to an increasing interest in finding new routes to valorize the large amount of glycerol produced linked to this biofuel obtaining process. One of these routes is glycerol transformation in value added products such as oxygen fuel additives. This review collects the latest advances in routes of glycerol valorization, considering the great majority of reactions with ketones and aldehydes, among other reactants. In order to justify the interest in these processes, this work includes a discussion of the main effects on fuel properties and engine performance. The characteristics that glycerol derivatives can provide to fuel blends, such as increasing in octane index, improving some cold flow properties or mitigating some negative aspects of other oxygenated compounds, such as environmental issues, flash point or gums formation will be exposed and discussed.

Suggested Citation

  • Cornejo, A. & Barrio, I. & Campoy, M. & Lázaro, J. & Navarrete, B., 2017. "Oxygenated fuel additives from glycerol valorization. Main production pathways and effects on fuel properties and engine performance: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1400-1413.
    • Handle: RePEc:eee:rensus:v:79:y:2017:i:c:p:1400-1413
    DOI: 10.1016/j.rser.2017.04.005
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    Cited by:

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    2. Ribeiro, Mariana B. & Cavalcante, Raquel M. & Young, André F., 2022. "Simulation and economic evaluation of fuel additives production from glycerol," Renewable Energy, Elsevier, vol. 181(C), pages 1081-1099.
    3. Mamtani, Kapil & Shahbaz, Kaveh & Farid, Mohammed M., 2021. "Glycerolysis of free fatty acids: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    4. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    5. Rafael Estevez & Laura Aguado-Deblas & Diego Luna & Felipa M. Bautista, 2019. "An Overview of the Production of Oxygenated Fuel Additives by Glycerol Etherification, Either with Isobutene or tert -Butyl Alcohol, over Heterogeneous Catalysts," Energies, MDPI, vol. 12(12), pages 1-20, June.
    6. Sedghi, Reza & Shahbeik, Hossein & Rastegari, Hajar & Rafiee, Shahin & Peng, Wanxi & Nizami, Abdul-Sattar & Gupta, Vijai Kumar & Chen, Wei-Hsin & Lam, Su Shiung & Pan, Junting & Tabatabaei, Meisam & A, 2022. "Turning biodiesel glycerol into oxygenated fuel additives and their effects on the behavior of internal combustion engines: A comprehensive systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    7. Kumar, Komal & Pathak, Shailesh & Upadhyayula, Sreedevi, 2021. "Acetalization of 5-hydroxymethyl furfural into biofuel additive cyclic acetal using protic ionic liquid catalyst- A thermodynamic and kinetic analysis," Renewable Energy, Elsevier, vol. 167(C), pages 282-293.

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