IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v126y2017icp671-676.html
   My bibliography  Save this article

Reducing energy requirements for ETBE synthesis using reactive dividing wall distillation column

Author

Listed:
  • Kaur, Jasdeep
  • Sangal, Vikas Kumar

Abstract

Production of ETBE is one of most important industrial processes. It is used both as biofuel and bio additive in gasoline. The motivation behind its use is that, its blend with gasoline reduces greenhouse gas emissions. Present work focuses on the synthesis of ethyl tertiary butyl ether (ETBE) by using Reactive dividing wall column (RDWC) and a comparative assessment with three other process alternatives as-reactor followed by distillation sequence, reactor plus reactive distillation (RD), and RD. The comparison was done in terms of energy requirements, CO2 emissions, total annual costs (TAC), total investment costs (TIC) and total operating costs (TOC). RDWC proved its forte in saving energy therefore cutting CO2 emissions and handling the reactions limited by chemical equilibrium. RDWC was found to be the most promising alternative out of the four process alternatives. It gave highest purity of the product ETBE 99.999% (mol.), the CO2 emissions were reduced by 74% and 43% as compared to conventional sequence and RD respectively, and also the energy requirements were very less as compared to the conventional sequence and RD. TIC reduction as high as 68% was observed, this also established RDWC as a lucrative option for the synthesis of ETBE.

Suggested Citation

  • Kaur, Jasdeep & Sangal, Vikas Kumar, 2017. "Reducing energy requirements for ETBE synthesis using reactive dividing wall distillation column," Energy, Elsevier, vol. 126(C), pages 671-676.
    • Handle: RePEc:eee:energy:v:126:y:2017:i:c:p:671-676
    DOI: 10.1016/j.energy.2017.03.072
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217304462
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2017.03.072?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Rahmat, Norhasyimi & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2010. "Recent progress on innovative and potential technologies for glycerol transformation into fuel additives: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(3), pages 987-1000, April.
    2. Yee, Kian Fei & Mohamed, Abdul Rahman & Tan, Soon Huat, 2013. "A review on the evolution of ethyl tert-butyl ether (ETBE) and its future prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 604-620.
    3. Gadalla, M. & Olujić, Ž. & de Rijke, A. & Jansens, P.J., 2006. "Reducing CO2 emissions of internally heat-integrated distillation columns for separation of close boiling mixtures," Energy, Elsevier, vol. 31(13), pages 2409-2417.
    4. Tavan, Yadollah, 2014. "Feasibility and parametric study of tetrahydrofuran dehydration using reactive distillation with low energy requirement," Energy, Elsevier, vol. 76(C), pages 622-628.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yang, Ao & Sun, Shirui & Eslamimanesh, Ali & Wei, Shun'an & Shen, Weifeng, 2019. "Energy-saving investigation for diethyl carbonate synthesis through the reactive dividing wall column combining the vapor recompression heat pump or different pressure thermally coupled technique," Energy, Elsevier, vol. 172(C), pages 320-332.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Cornejo, A. & Barrio, I. & Campoy, M. & Lázaro, J. & Navarrete, B., 2017. "Oxygenated fuel additives from glycerol valorization. Main production pathways and effects on fuel properties and engine performance: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1400-1413.
    2. Rafael Estevez & Laura Aguado-Deblas & Diego Luna & Felipa M. Bautista, 2019. "An Overview of the Production of Oxygenated Fuel Additives by Glycerol Etherification, Either with Isobutene or tert -Butyl Alcohol, over Heterogeneous Catalysts," Energies, MDPI, vol. 12(12), pages 1-20, June.
    3. Beatrice, Carlo & Di Blasio, Gabriele & Lazzaro, Maurizio & Cannilla, Catia & Bonura, Giuseppe & Frusteri, Francesco & Asdrubali, Francesco & Baldinelli, Giorgio & Presciutti, Andrea & Fantozzi, Franc, 2013. "Technologies for energetic exploitation of biodiesel chain derived glycerol: Oxy-fuels production by catalytic conversion," Applied Energy, Elsevier, vol. 102(C), pages 63-71.
    4. Yee, Kian Fei & Mohamed, Abdul Rahman & Tan, Soon Huat, 2013. "A review on the evolution of ethyl tert-butyl ether (ETBE) and its future prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 604-620.
    5. Kiss, Anton A. & Flores Landaeta, Servando J. & Infante Ferreira, Carlos A., 2012. "Towards energy efficient distillation technologies – Making the right choice," Energy, Elsevier, vol. 47(1), pages 531-542.
    6. Francesco Asdrubali & Franco Cotana & Federico Rossi & Andrea Presciutti & Antonella Rotili & Claudia Guattari, 2015. "Life Cycle Assessment of New Oxy-Fuels from Biodiesel-Derived Glycerol," Energies, MDPI, vol. 8(3), pages 1-16, February.
    7. Okoye, P.U. & Hameed, B.H., 2016. "Review on recent progress in catalytic carboxylation and acetylation of glycerol as a byproduct of biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 558-574.
    8. Kong, Pei San & Aroua, Mohamed Kheireddine & Daud, Wan Mohd Ashri Wan, 2016. "Conversion of crude and pure glycerol into derivatives: A feasibility evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 533-555.
    9. E, Jiaqiang & Pham, Minhhieu & Zhao, D. & Deng, Yuanwang & Le, DucHieu & Zuo, Wei & Zhu, Hao & Liu, Teng & Peng, Qingguo & Zhang, Zhiqing, 2017. "Effect of different technologies on combustion and emissions of the diesel engine fueled with biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 620-647.
    10. Ayoub, Muhammad & Abdullah, Ahmad Zuhairi, 2012. "Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2671-2686.
    11. Herreros, J.M. & Jones, A. & Sukjit, E. & Tsolakis, A., 2014. "Blending lignin-derived oxygenate in enhanced multi-component diesel fuel for improved emissions," Applied Energy, Elsevier, vol. 116(C), pages 58-65.
    12. Galadima, Ahmad & Muraza, Oki, 2014. "Biodiesel production from algae by using heterogeneous catalysts: A critical review," Energy, Elsevier, vol. 78(C), pages 72-83.
    13. Hunsom, Mali & Saila, Payia, 2015. "Electrochemical conversion of enriched crude glycerol: Effect of operating parameters," Renewable Energy, Elsevier, vol. 74(C), pages 227-236.
    14. Beatrice, Carlo & Di Blasio, Gabriele & Guido, Chiara & Cannilla, Catia & Bonura, Giuseppe & Frusteri, Francesco, 2014. "Mixture of glycerol ethers as diesel bio-derivable oxy-fuel: Impact on combustion and emissions of an automotive engine combustion system," Applied Energy, Elsevier, vol. 132(C), pages 236-247.
    15. Sedghi, Reza & Shahbeik, Hossein & Rastegari, Hajar & Rafiee, Shahin & Peng, Wanxi & Nizami, Abdul-Sattar & Gupta, Vijai Kumar & Chen, Wei-Hsin & Lam, Su Shiung & Pan, Junting & Tabatabaei, Meisam & A, 2022. "Turning biodiesel glycerol into oxygenated fuel additives and their effects on the behavior of internal combustion engines: A comprehensive systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    16. Juan Francisco García-Martín & Francisco Javier Alés-Álvarez & Miguel Torres-García & Chao-Hui Feng & Paloma Álvarez-Mateos, 2019. "Production of Oxygenated Fuel Additives from Residual Glycerine Using Biocatalysts Obtained from Heavy-Metal-Contaminated Jatropha curcas L. Roots," Energies, MDPI, vol. 12(4), pages 1-12, February.
    17. Hejna, Aleksander & Kosmela, Paulina & Formela, Krzysztof & Piszczyk, Łukasz & Haponiuk, Józef T., 2016. "Potential applications of crude glycerol in polymer technology–Current state and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 66(C), pages 449-475.
    18. Calero, Juan & Luna, Diego & Sancho, Enrique D. & Luna, Carlos & Bautista, Felipa M. & Romero, Antonio A. & Posadillo, Alejandro & Berbel, Julio & Verdugo-Escamilla, Cristóbal, 2015. "An overview on glycerol-free processes for the production of renewable liquid biofuels, applicable in diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1437-1452.
    19. Najjar, Yousef S.H., 2013. "Protection of the environment by using innovative greening technologies in land transport," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 480-491.
    20. Is Fatimah & Imam Sahroni & Ganjar Fadillah & Muhammad Miqdam Musawwa & Teuku Meurah Indra Mahlia & Oki Muraza, 2019. "Glycerol to Solketal for Fuel Additive: Recent Progress in Heterogeneous Catalysts," Energies, MDPI, vol. 12(15), pages 1-14, July.

    More about this item

    Keywords

    ETBE; RDWC; Energy requirement; CO2 emissions;
    All these keywords.

    JEL classification:

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:126:y:2017:i:c:p:671-676. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.