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Autothermal reforming process for efficient hydrogen production from crude glycerol using nickel supported catalyst: Parametric and statistical analyses

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  • Abdul Ghani, Ahmad
  • Torabi, Farshid
  • Ibrahim, Hussameldin

Abstract

In this work, crude glycerol was reformed over modified cerium-zirconium supports loaded with 5 wt% nickel catalyst by a combination of partial oxidation and steam reforming reactions to generate hydrogen via an auto-thermal process. Amongst the tested promoter elements, calcium showed the highest capability of enhancing the activity of the catalyst. Likewise, the composition of crude glycerol mixture generated at biodiesel plants, free glycerol, methanol, soap, free fatty acids and ashes (NaCl and KCl) were contained in the synthetic CG. The effects of reforming temperature, steam-to-carbon ratio (S/C), oxygen-to-carbon ratio (O/C), reduction temperature and calcination temperature were studied in a packed bed tubular reactor (PBTR). A reforming temperature of 550 °C, S/C of 2.6, O/C of 0.50, reduction temperature of 600 °C and calcination temperature of 550 °C were experimentally revealed as the optimum operating conditions. A statistical analysis was subsequently performed to quantify the significance of each factor on the overall performance.

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  • Abdul Ghani, Ahmad & Torabi, Farshid & Ibrahim, Hussameldin, 2018. "Autothermal reforming process for efficient hydrogen production from crude glycerol using nickel supported catalyst: Parametric and statistical analyses," Energy, Elsevier, vol. 144(C), pages 129-145.
    • Handle: RePEc:eee:energy:v:144:y:2018:i:c:p:129-145
    DOI: 10.1016/j.energy.2017.11.132
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    1. Ayoub, Muhammad & Abdullah, Ahmad Zuhairi, 2012. "Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2671-2686.
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    2. Li, Lin & Tang, Dawei & Song, Yongchen & Jiang, Bo & Zhang, Qian, 2018. "Hydrogen production from ethanol steam reforming on Ni-Ce/MMT catalysts," Energy, Elsevier, vol. 149(C), pages 937-943.
    3. Macedo, M. Salomé & Soria, M.A. & Madeira, Luis M., 2021. "Process intensification for hydrogen production through glycerol steam reforming," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
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    5. Zhang, Tie-qing & Malik, Fawad Rahim & Jung, Seunghun & Kim, Young-Bae, 2022. "Hydrogen production and temperature control for DME autothermal reforming process," Energy, Elsevier, vol. 239(PA).
    6. Ana Almeida & Rosa Pilão & Albina Ribeiro & Elisa Ramalho & Carlos Pinho, 2020. "Co-Gasification of Crude Glycerol/Animal Fat Mixtures," Energies, MDPI, vol. 13(7), pages 1-12, April.
    7. Garcia, Gabriel & Arriola, Emmanuel & Chen, Wei-Hsin & De Luna, Mark Daniel, 2021. "A comprehensive review of hydrogen production from methanol thermochemical conversion for sustainability," Energy, Elsevier, vol. 217(C).
    8. Marinho, Carolina M. & de S. Barrozo, Marcos A. & Hori, Carla E., 2020. "Optimization of glycerol etherification with ethanol in fixed bed reactor under various pressures," Energy, Elsevier, vol. 207(C).
    9. Tamošiūnas, Andrius & Gimžauskaitė, Dovilė & Uscila, Rolandas & Aikas, Mindaugas, 2019. "Thermal arc plasma gasification of waste glycerol to syngas," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
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