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Modeling of direct carbon solid oxide fuel cell for CO and electricity cogeneration

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  • Xu, Haoran
  • Chen, Bin
  • Liu, Jiang
  • Ni, Meng

Abstract

Direct carbon solid oxide fuel cell (DC-SOFC) is a promising energy conversion device for power generation using solid carbon fuel. In this paper, a 2D model is developed for a tubular DC-SOFC for CO and electricity co-generation. Parametric simulations are conducted to understand the physical/chemical processes in the DC-SOFC. Good performance of DC-SOFC is observed even at a large distance between the carbon bed and the porous anode, indicating the feasibility of large-scale DC-SOFC applications. The DC-SOFC performance is found to decrease with decreasing temperature due to the decreased Boudouard reaction kinetics. It’s also found that the molar fraction of CO at the anode can be well controlled by adjusting the operating conditions, enabling DC-SOFC for electricity and CO cogeneration. Another finding is that the current density in the DC-SOFC increases slightly along the cell length, which is different from the H2-fueled SOFC. In addition, the anode-supported configuration is found to be beneficial in improving the electrical output of the DC-SOFC but is unfavorable for CO generation. A small Dce and a high potential are recommended to improve CO generation from the DC-SOFC. The model can be used for design optimization of DC-SOFC at a system level.

Suggested Citation

  • Xu, Haoran & Chen, Bin & Liu, Jiang & Ni, Meng, 2016. "Modeling of direct carbon solid oxide fuel cell for CO and electricity cogeneration," Applied Energy, Elsevier, vol. 178(C), pages 353-362.
    • Handle: RePEc:eee:appene:v:178:y:2016:i:c:p:353-362
    DOI: 10.1016/j.apenergy.2016.06.064
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    4. Kong, Wei & Han, Zhen & Lu, Siyu & Ni, Meng, 2021. "A simple but effective design to enhance the performance and durability of direct carbon solid oxide fuel cells," Applied Energy, Elsevier, vol. 287(C).
    5. Xu, Haoran & Chen, Bin & Tan, Peng & Cai, Weizi & He, Wei & Farrusseng, David & Ni, Meng, 2018. "Modeling of all porous solid oxide fuel cells," Applied Energy, Elsevier, vol. 219(C), pages 105-113.
    6. Mushtaq, Usman & Mehran, Muhammad Taqi & Kim, Sun-Kyoung & Lim, Tak-Hyoung & Naqvi, Syed Asad Ali & Lee, Jong-Won & Lee, Seung-Bok & Park, Seok-Joo & Song, Rak-Hyun, 2017. "Evaluation of steady-state characteristics for solid oxide carbon fuel cell short-stacks," Applied Energy, Elsevier, vol. 187(C), pages 886-898.
    7. Chen, Qianyang & Qiu, Qianyuan & Yan, Xiaomin & Zhou, Mingyang & Zhang, Yapeng & Liu, Zhijun & Cai, Weizi & Wang, Wei & Liu, Jiang, 2020. "A compact and seal-less direct carbon solid oxide fuel cell stack stepping into practical application," Applied Energy, Elsevier, vol. 278(C).
    8. Nerat, Marko, 2017. "Modeling and analysis of short-period transient response of a single, planar, anode supported, solid oxide fuel cell during load variations," Energy, Elsevier, vol. 138(C), pages 728-738.
    9. Guk, Erdogan & Kim, Jung-Sik & Ranaweera, Manoj & Venkatesan, Vijay & Jackson, Lisa, 2018. "In-situ monitoring of temperature distribution in operating solid oxide fuel cell cathode using proprietary sensory techniques versus commercial thermocouples," Applied Energy, Elsevier, vol. 230(C), pages 551-562.
    10. Ma, Rui & Liu, Chen & Breaz, Elena & Briois, Pascal & Gao, Fei, 2018. "Numerical stiffness study of multi-physical solid oxide fuel cell model for real-time simulation applications," Applied Energy, Elsevier, vol. 226(C), pages 570-581.
    11. Zhu, Pengfei & Wu, Zhen & Yang, Yuchen & Wang, Huan & Li, Ruiqing & Yang, Fusheng & Zhang, Zaoxiao, 2023. "The dynamic response of solid oxide fuel cell fueled by syngas during the operating condition variations," Applied Energy, Elsevier, vol. 349(C).
    12. Li, Bangxin & Irvine, John T.S. & Ni, Jiupai & Ni, Chengsheng, 2022. "High-performance and durable alcohol-fueled symmetrical solid oxide fuel cell based on ferrite perovskite electrode," Applied Energy, Elsevier, vol. 306(PB).
    13. Xu, Haoran & Chen, Bin & Tan, Peng & Cai, Weizi & Wu, Yiyang & Zhang, Houcheng & Ni, Meng, 2018. "A feasible way to handle the heat management of direct carbon solid oxide fuel cells," Applied Energy, Elsevier, vol. 226(C), pages 881-890.
    14. Li, Ang & Song, Ce & Lin, Zijing, 2017. "A multiphysics fully coupled modeling tool for the design and operation analysis of planar solid oxide fuel cell stacks," Applied Energy, Elsevier, vol. 190(C), pages 1234-1244.
    15. Xu, Haoran & Chen, Bin & Tan, Peng & Sun, Qiong & Maroto-Valer, M. Mercedes & Ni, Meng, 2019. "Modelling of a hybrid system for on-site power generation from solar fuels," Applied Energy, Elsevier, vol. 240(C), pages 709-718.
    16. Xu, Haoran & Chen, Bin & Tan, Peng & Xuan, Jin & Maroto-Valer, M. Mercedes & Farrusseng, David & Sun, Qiong & Ni, Meng, 2019. "Modeling of all-porous solid oxide fuel cells with a focus on the electrolyte porosity design," Applied Energy, Elsevier, vol. 235(C), pages 602-611.

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