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Sulfur-tolerant Fe-doped La0·3Sr0·7TiO3 perovskite as anode of direct carbon solid oxide fuel cells

Author

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  • Cai, Weizi
  • Cao, Dan
  • Zhou, Mingyang
  • Yan, Xiaomin
  • Li, Yuzhi
  • Wu, Zhen
  • Lü, Shengping
  • Mao, Caiyun
  • Xie, Yongmin
  • Zhao, Caiwen
  • Yu, Jialing
  • Ni, Meng
  • Liu, Jiang
  • Wang, Hailin

Abstract

Fe-doped La0·3Sr0·7TiO3 (LSFT) is synthesized and systematically characterized towards application as an anode material for direct carbon solid oxide fuel cells (DC-SOFCs). The structural, electrical and electrochemical properties of LSFT under the operation conditions of DC-SOFCs have been evaluated. High structural stability, improved ionic conductivity, electrocatalytic activity, and electrochemical performance are demonstrated. Electrolyte-supported DC-SOFC with LSFT anode provides a maximum power density of 292 mW cm−2 at 850 °C, which is comparable to those state-of-the-art Ni-YSZ anode for DC-SOFC. In addition, it shows excellent long-term operational stability (over 110 h) in H2S-containing CO atmosphere. It thus promises as a novel anode candidate for DC-SOFCs with whole-solid-state configuration.

Suggested Citation

  • Cai, Weizi & Cao, Dan & Zhou, Mingyang & Yan, Xiaomin & Li, Yuzhi & Wu, Zhen & Lü, Shengping & Mao, Caiyun & Xie, Yongmin & Zhao, Caiwen & Yu, Jialing & Ni, Meng & Liu, Jiang & Wang, Hailin, 2020. "Sulfur-tolerant Fe-doped La0·3Sr0·7TiO3 perovskite as anode of direct carbon solid oxide fuel cells," Energy, Elsevier, vol. 211(C).
    • Handle: RePEc:eee:energy:v:211:y:2020:i:c:s036054422032065x
    DOI: 10.1016/j.energy.2020.118958
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    References listed on IDEAS

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