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Efficient syngas generation for electricity storage through carbon gasification assisted solid oxide co-electrolysis

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  • Lei, Libin
  • Wang, Yao
  • Fang, Shumin
  • Ren, Cong
  • Liu, Tong
  • Chen, Fanglin

Abstract

High temperature CO2 and H2O co-electrolysis is a promising way to produce syngas for the storage of electrical energy harvested from renewable energy sources. However, a significant portion of electricity input is consumed to overcome a large oxygen potential gradient between the electrodes in conventional solid oxide electrolysis cells (SOECs). In this study, we present a novel and efficient syngas generator integrating carbon gasification and solid oxide co-electrolysis to improve the system efficiency. The feasibility of this new system is demonstrated in La0.9Sr0.1Ga0.8Mg0.2O3 (LSGM) electrolyte-supported SOECs. Both thermodynamic calculation and experimental results show that the potential barrier for co-electrolysis can be reduced by about 1V and the electricity input can be saved by more than 90% upon integration of SOECs with carbon gasification. On the anode side, “CO shuttle” between the electrochemical reaction sites and solid carbon is realized through the Boudouard reaction (C+CO2=2CO). Simultaneous production of CO on the anode side and CO/H2 on the cathode side generates syngas that can serve as fuel for power generation or feedstock for chemical plants. The integration of carbon gasification and SOECs provides a potential pathway for efficient utilization of electricity, coal/biomass, and CO2 to store electrical energy, produce clean fuel, and achieve a carbon neutral sustainable energy supply.

Suggested Citation

  • Lei, Libin & Wang, Yao & Fang, Shumin & Ren, Cong & Liu, Tong & Chen, Fanglin, 2016. "Efficient syngas generation for electricity storage through carbon gasification assisted solid oxide co-electrolysis," Applied Energy, Elsevier, vol. 173(C), pages 52-58.
    • Handle: RePEc:eee:appene:v:173:y:2016:i:c:p:52-58
    DOI: 10.1016/j.apenergy.2016.03.116
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    1. Duan, Nan-Qi & Cao, Yong & Hua, Bin & Chi, Bo & Pu, Jian & Luo, Jingli & Jian, Li, 2016. "Tubular direct carbon solid oxide fuel cells with molten antimony anode and refueling feasibility," Energy, Elsevier, vol. 95(C), pages 274-278.
    2. Jiao, Yong & Tian, Wenjuan & Chen, Huili & Shi, Huangang & Yang, Binbin & Li, Chao & Shao, Zongping & Zhu, Zhenping & Li, Si-Dian, 2015. "In situ catalyzed Boudouard reaction of coal char for solid oxide-based carbon fuel cells with improved performance," Applied Energy, Elsevier, vol. 141(C), pages 200-208.
    3. Bruce C.R. Ewan & Olalekan D. Adeniyi, 2013. "A Demonstration of Carbon-Assisted Water Electrolysis," Energies, MDPI, vol. 6(3), pages 1-12, March.
    4. Duan, Nan-Qi & Tan, Yuan & Yan, Dong & Jia, Lichao & Chi, Bo & Pu, Jian & Li, Jian, 2016. "Biomass carbon fueled tubular solid oxide fuel cells with molten antimony anode," Applied Energy, Elsevier, vol. 165(C), pages 983-989.
    5. Irfan, Muhammad F. & Usman, Muhammad R. & Kusakabe, K., 2011. "Coal gasification in CO2 atmosphere and its kinetics since 1948: A brief review," Energy, Elsevier, vol. 36(1), pages 12-40.
    6. Cinti, Giovanni & Baldinelli, Arianna & Di Michele, Alessandro & Desideri, Umberto, 2016. "Integration of Solid Oxide Electrolyzer and Fischer-Tropsch: A sustainable pathway for synthetic fuel," Applied Energy, Elsevier, vol. 162(C), pages 308-320.
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