IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v227y2021ics0360544221007052.html
   My bibliography  Save this article

Highly efficient utilization of walnut shell biochar through a facile designed portable direct carbon solid oxide fuel cell stack

Author

Listed:
  • Xie, Yongmin
  • Xiao, Jie
  • Liu, Qingsheng
  • Wang, Xiaoqiang
  • Liu, Jiang
  • Wu, Peijia
  • Ouyang, Shaobo

Abstract

The direct carbon solid oxide fuel cell (DC-SOFC) is a green and efficient energy conversion device with all-solid-state structure, which can convert carbon fuel into electricity directly. Recently, using biomasses as fuels for DC-SOFC has become fascinating due to their abundance and renewable property. However, it usually provides inferior performance compared to that with gas fuel feeding (hydrogen). Here, we report a promising and high-performing tubular segmented-in-series YSZ electrolyte-supported DC-SOFC stack. Thereinto, the YSZ electrolyte supports are fabricated by dip-coating and both pure walnut shell biochar and Fe-loaded biochar are used as fuels. The single cell can achieve a maximum power density of 147 mW cm−2 at 800 °C and it is improved to 205 mW cm−2 as FenOm catalyst is loaded on the biochar fuel. Furthermore, a two-cell-stack of DC-SOFC operated with Fe-loaded walnut shell char is assembled and tested. It delivers an outstanding performance, with an OCV of 1.98 V, an output power of 1.11 W and a maximum volumetric power density of 505 mW cm−3 at 800 °C, indicating high potentials for developing into a high performance battery for portable or distributed applications.

Suggested Citation

  • Xie, Yongmin & Xiao, Jie & Liu, Qingsheng & Wang, Xiaoqiang & Liu, Jiang & Wu, Peijia & Ouyang, Shaobo, 2021. "Highly efficient utilization of walnut shell biochar through a facile designed portable direct carbon solid oxide fuel cell stack," Energy, Elsevier, vol. 227(C).
    • Handle: RePEc:eee:energy:v:227:y:2021:i:c:s0360544221007052
    DOI: 10.1016/j.energy.2021.120456
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221007052
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.120456?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Xu, Haoran & Chen, Bin & Tan, Peng & Zhang, Houcheng & Yuan, Jinliang & Liu, Jiang & Ni, Meng, 2017. "Performance improvement of a direct carbon solid oxide fuel cell system by combining with a Stirling cycle," Energy, Elsevier, vol. 140(P1), pages 979-987.
    2. Chen, Qianyang & Qiu, Qianyuan & Yan, Xiaomin & Zhou, Mingyang & Zhang, Yapeng & Liu, Zhijun & Cai, Weizi & Wang, Wei & Liu, Jiang, 2020. "A compact and seal-less direct carbon solid oxide fuel cell stack stepping into practical application," Applied Energy, Elsevier, vol. 278(C).
    3. Duan, Nan-Qi & Cao, Yong & Hua, Bin & Chi, Bo & Pu, Jian & Luo, Jingli & Jian, Li, 2016. "Tubular direct carbon solid oxide fuel cells with molten antimony anode and refueling feasibility," Energy, Elsevier, vol. 95(C), pages 274-278.
    4. Wang, Chaoqi & Lü, Zhe & Li, Jingwei & Cao, Zhiqun & Wei, Bo & Li, Huan & Shang, Minghao & Su, Chaoxiang, 2020. "Efficient use of waste carton for power generation, tar and fertilizer through direct carbon solid oxide fuel cell," Renewable Energy, Elsevier, vol. 158(C), pages 410-420.
    5. Cai, Weizi & Zhou, Qian & Xie, Yongmin & Liu, Jiang & Long, Guohui & Cheng, Shuang & Liu, Meilin, 2016. "A direct carbon solid oxide fuel cell operated on a plant derived biofuel with natural catalyst," Applied Energy, Elsevier, vol. 179(C), pages 1232-1241.
    6. Shafiee, Shahriar & Topal, Erkan, 2009. "When will fossil fuel reserves be diminished?," Energy Policy, Elsevier, vol. 37(1), pages 181-189, January.
    7. Duan, Nan-Qi & Tan, Yuan & Yan, Dong & Jia, Lichao & Chi, Bo & Pu, Jian & Li, Jian, 2016. "Biomass carbon fueled tubular solid oxide fuel cells with molten antimony anode," Applied Energy, Elsevier, vol. 165(C), pages 983-989.
    8. Hao, Wenbin & Mi, Yongli, 2016. "Evaluation of waste paper as a source of carbon fuel for hybrid direct carbon fuel cells," Energy, Elsevier, vol. 107(C), pages 122-130.
    9. Nishiguchi, Sho & Tabata, Tomohiro, 2016. "Assessment of social, economic, and environmental aspects of woody biomass energy utilization: Direct burning and wood pellets," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1279-1286.
    10. Xie, Heping & Zhai, Shuo & Chen, Bin & Liu, Tao & Zhang, Yuan & Ni, Meng & Shao, Zongping, 2020. "Coal pretreatment and Ag-infiltrated anode for high-performance hybrid direct coal fuel cell," Applied Energy, Elsevier, vol. 260(C).
    11. Cai, Weizi & Cao, Dan & Zhou, Mingyang & Yan, Xiaomin & Li, Yuzhi & Wu, Zhen & Lü, Shengping & Mao, Caiyun & Xie, Yongmin & Zhao, Caiwen & Yu, Jialing & Ni, Meng & Liu, Jiang & Wang, Hailin, 2020. "Sulfur-tolerant Fe-doped La0·3Sr0·7TiO3 perovskite as anode of direct carbon solid oxide fuel cells," Energy, Elsevier, vol. 211(C).
    12. Giddey, S. & Kulkarni, A. & Munnings, C. & Badwal, S.P.S., 2014. "Performance evaluation of a tubular direct carbon fuel cell operating in a packed bed of carbon," Energy, Elsevier, vol. 68(C), pages 538-547.
    13. Wu, Hao & Xiao, Jie & Zeng, Xiaoyuan & Li, Xue & Yang, Jing & Zou, Yuling & Liu, Sudongfang & Dong, Peng & Zhang, Yingjie & Liu, Jiang, 2019. "A high performance direct carbon solid oxide fuel cell – A green pathway for brown coal utilization," Applied Energy, Elsevier, vol. 248(C), pages 679-687.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Dong, Weijie & He, Guoqing & Cui, Quansheng & Sun, Wenwen & Hu, Zhenlong & Ahli raad, Erfan, 2022. "Self-scheduling of a novel hybrid GTSOFC unit in day-ahead energy and spinning reserve markets within ancillary services using a novel energy storage," Energy, Elsevier, vol. 239(PE).
    2. Muzyka, Roksana & Misztal, Edyta & Hrabak, Joanna & Banks, Scott W. & Sajdak, Marcin, 2023. "Various biomass pyrolysis conditions influence the porosity and pore size distribution of biochar," Energy, Elsevier, vol. 263(PE).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Cao, Tianyu & Shi, Yixiang & Jiang, Yanqi & Cai, Ningsheng & Gong, Qianming, 2017. "Performance enhancement of liquid antimony anode fuel cell by in-situ electrochemical assisted oxidation process," Energy, Elsevier, vol. 125(C), pages 526-532.
    2. Lei, Libin & Keels, Jayson M. & Tao, Zetian & Zhang, Jihao & Chen, Fanglin, 2018. "Thermodynamic and experimental assessment of proton conducting solid oxide fuel cells with internal methane steam reforming," Applied Energy, Elsevier, vol. 224(C), pages 280-288.
    3. Chen, Qianyang & Qiu, Qianyuan & Yan, Xiaomin & Zhou, Mingyang & Zhang, Yapeng & Liu, Zhijun & Cai, Weizi & Wang, Wei & Liu, Jiang, 2020. "A compact and seal-less direct carbon solid oxide fuel cell stack stepping into practical application," Applied Energy, Elsevier, vol. 278(C).
    4. Kong, Wei & Han, Zhen & Lu, Siyu & Ni, Meng, 2021. "A simple but effective design to enhance the performance and durability of direct carbon solid oxide fuel cells," Applied Energy, Elsevier, vol. 287(C).
    5. Jiang, Yidong & Gu, Xin & Shi, Jixin & Shi, Yixiang & Cai, Ningsheng, 2023. "Co-generation of gas and electricity on liquid antimony anode solid oxide fuel cells for high efficiency, long-term kerosene power generation," Energy, Elsevier, vol. 263(PC).
    6. Eom, Seongyong & Ahn, Seongyool & Kang, Kijoong & Choi, Gyungmin, 2017. "Correlations between electrochemical resistances and surface properties of acid-treated fuel in coal fuel cells," Energy, Elsevier, vol. 140(P1), pages 885-892.
    7. Lei, Libin & Wang, Yao & Fang, Shumin & Ren, Cong & Liu, Tong & Chen, Fanglin, 2016. "Efficient syngas generation for electricity storage through carbon gasification assisted solid oxide co-electrolysis," Applied Energy, Elsevier, vol. 173(C), pages 52-58.
    8. Dongxu Zhang & Ting Min & Ming Jiang & Yaxiong Yu & Qiang Zhou, 2021. "Numerical Simulation of Fluidized Bed Gasifier Coupled with Solid Oxide Fuel Cell Fed with Solid Carbon," Energies, MDPI, vol. 14(10), pages 1-24, May.
    9. Houcheng Zhang & Jiatang Wang & Jiapei Zhao & Fu Wang & He Miao & Jinliang Yuan, 2019. "Performance Analysis of a Hybrid System Consisting of a Molten Carbonate Direct Carbon Fuel Cell and an Absorption Refrigerator," Energies, MDPI, vol. 12(3), pages 1-13, January.
    10. Mushtaq, Usman & Mehran, Muhammad Taqi & Kim, Sun-Kyoung & Lim, Tak-Hyoung & Naqvi, Syed Asad Ali & Lee, Jong-Won & Lee, Seung-Bok & Park, Seok-Joo & Song, Rak-Hyun, 2017. "Evaluation of steady-state characteristics for solid oxide carbon fuel cell short-stacks," Applied Energy, Elsevier, vol. 187(C), pages 886-898.
    11. Ozalp, N. & Abedini, H. & Abuseada, M. & Davis, R. & Rutten, J. & Verschoren, J. & Ophoff, C. & Moens, D., 2022. "An overview of direct carbon fuel cells and their promising potential on coupling with solar thermochemical carbon production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    12. Aye, Goodness & Gupta, Rangan & Hammoudeh, Shawkat & Kim, Won Joong, 2015. "Forecasting the price of gold using dynamic model averaging," International Review of Financial Analysis, Elsevier, vol. 41(C), pages 257-266.
    13. Ali Mubarak Al-Qahtani, 2023. "A Comprehensive Review in Microwave Pyrolysis of Biomass, Syngas Production and Utilisation," Energies, MDPI, vol. 16(19), pages 1-16, September.
    14. Jen-Yu Lee & Tien-Thinh Nguyen & Hong-Giang Nguyen & Jen-Yao Lee, 2022. "Towards Predictive Crude Oil Purchase: A Case Study in the USA and Europe," Energies, MDPI, vol. 15(11), pages 1-15, May.
    15. Mollik, Sazib & Rashid, M.M. & Hasanuzzaman, M. & Karim, M.E. & Hosenuzzaman, M., 2016. "Prospects, progress, policies, and effects of rural electrification in Bangladesh," Renewable and Sustainable Energy Reviews, Elsevier, vol. 65(C), pages 553-567.
    16. Steve Newbold & Charles Griffiths & Christopher C. Moore & Ann Wolverton & Elizabeth Kopits, 2010. "The "Social Cost of Carbon" Made Simple," NCEE Working Paper Series 201007, National Center for Environmental Economics, U.S. Environmental Protection Agency, revised Aug 2010.
    17. Ritter, Hendrik & Zimmermann, Karl, 2019. "Cap-and-Trade Policy vs. Carbon Taxation: Of Leakage and Linkage," EconStor Preprints 197796, ZBW - Leibniz Information Centre for Economics.
    18. Yassir El Karkri & Alexis B. Rey-Boué & Hassan El Moussaoui & Johannes Stöckl & Thomas I. Strasser, 2019. "Improved Control of Grid-connected DFIG-based Wind Turbine using Proportional-Resonant Regulators during Unbalanced Grid," Energies, MDPI, vol. 12(21), pages 1-21, October.
    19. Jānis Krūmiņš & Māris Kļaviņš, 2023. "Investigating the Potential of Nuclear Energy in Achieving a Carbon-Free Energy Future," Energies, MDPI, vol. 16(9), pages 1-31, April.
    20. Cai, Weizi & Cao, Dan & Zhou, Mingyang & Yan, Xiaomin & Li, Yuzhi & Wu, Zhen & Lü, Shengping & Mao, Caiyun & Xie, Yongmin & Zhao, Caiwen & Yu, Jialing & Ni, Meng & Liu, Jiang & Wang, Hailin, 2020. "Sulfur-tolerant Fe-doped La0·3Sr0·7TiO3 perovskite as anode of direct carbon solid oxide fuel cells," Energy, Elsevier, vol. 211(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:227:y:2021:i:c:s0360544221007052. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.