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Modeling of all-porous solid oxide fuel cells with a focus on the electrolyte porosity design

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  • Xu, Haoran
  • Chen, Bin
  • Tan, Peng
  • Xuan, Jin
  • Maroto-Valer, M. Mercedes
  • Farrusseng, David
  • Sun, Qiong
  • Ni, Meng

Abstract

Conventional solid oxide fuel cells (SOFCs) could suffer from carbon deposition when fueled with hydrocarbons. For comparison, a new type of SOFC with porous electrolyte can resist carbon deposition because it allows oxygen molecules to transport from the cathode to the anode. As the transport of O2 to the anode lowers the fuel cell performance and causes the risk of explosion, the rate of O2 transport must be well controlled to ensure efficient and safe operation. Following our previous model, this paper focuses on electrolyte porosity optimization under various inlet methane mole fractions, inlet oxygen mole fractions and inlet gas flow rates. Furthermore, a new design with a partial porous electrolyte is proposed and numerically evaluated. The new design significantly improves the electrochemical performance compared with all-porous one. A conversion rate >90% from methane to syngas is achieved at the 0.33 inlet CH4 mole fraction with the new design. The results enhance the understanding of all porous solid oxide fuel cells and the mechanism underlying, inspiring novel designs of solid oxide fuel cells.

Suggested Citation

  • Xu, Haoran & Chen, Bin & Tan, Peng & Xuan, Jin & Maroto-Valer, M. Mercedes & Farrusseng, David & Sun, Qiong & Ni, Meng, 2019. "Modeling of all-porous solid oxide fuel cells with a focus on the electrolyte porosity design," Applied Energy, Elsevier, vol. 235(C), pages 602-611.
    • Handle: RePEc:eee:appene:v:235:y:2019:i:c:p:602-611
    DOI: 10.1016/j.apenergy.2018.10.069
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    References listed on IDEAS

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    Cited by:

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    2. Thieu, Cam-Anh & Ji, Ho-Il & Kim, Hyoungchul & Yoon, Kyung Joong & Lee, Jong-Ho & Son, Ji-Won, 2019. "Palladium incorporation at the anode of thin-film solid oxide fuel cells and its effect on direct utilization of butane fuel at 600 °C," Applied Energy, Elsevier, vol. 243(C), pages 155-164.
    3. Dehghan, Ali Reza & Fanaei, Mohammad Ali & Panahi, Mehdi, 2022. "Economic plantwide control of a hybrid solid oxide fuel cell - gas turbine system," Applied Energy, Elsevier, vol. 328(C).
    4. Li, Bangxin & Irvine, John T.S. & Ni, Jiupai & Ni, Chengsheng, 2022. "High-performance and durable alcohol-fueled symmetrical solid oxide fuel cell based on ferrite perovskite electrode," Applied Energy, Elsevier, vol. 306(PB).
    5. Ma, Shuai & Lin, Meng & Lin, Tzu-En & Lan, Tian & Liao, Xun & Maréchal, François & Van herle, Jan & Yang, Yongping & Dong, Changqing & Wang, Ligang, 2021. "Fuel cell-battery hybrid systems for mobility and off-grid applications: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    6. Xu, Haoran & Chen, Bin & Tan, Peng & Sun, Qiong & Maroto-Valer, M. Mercedes & Ni, Meng, 2019. "Modelling of a hybrid system for on-site power generation from solar fuels," Applied Energy, Elsevier, vol. 240(C), pages 709-718.

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