IDEAS home Printed from https://ideas.repec.org/a/gam/jsusta/v12y2020i13p5482-d381492.html
   My bibliography  Save this article

Performance of Different Catalysts for the In Situ Cracking of the Oil-Waxes Obtained by the Pyrolysis of Polyethylene Film Waste

Author

Listed:
  • Lucía Quesada

    (Department of Chemical Engineering, University of Granada, 18071 Granada, Spain)

  • Mónica Calero de Hoces

    (Department of Chemical Engineering, University of Granada, 18071 Granada, Spain)

  • M. A. Martín-Lara

    (Department of Chemical Engineering, University of Granada, 18071 Granada, Spain)

  • Germán Luzón

    (Department of Chemical Engineering, University of Granada, 18071 Granada, Spain)

  • G. Blázquez

    (Department of Chemical Engineering, University of Granada, 18071 Granada, Spain)

Abstract

Currently, society is facing a great environmental problem, due to the large amount of plastic waste generated, most of which is not subjected to any type of treatment. In this work, polyethylene film waste from the non-selectively collected fraction was catalytically pyrolyzed at 500 °C, 20 °C/min for 2 h, in a discontinuous reactor using nitrogen as an inert gas stream. The main objective of this paper is to find catalysts that decrease the viscosity of the liquid fraction, since this property is quite meaningful in thermal pyrolysis. For this purpose, the three products of catalytic pyrolysis, the gaseous fraction, the solid fraction and the liquid fraction, were separated, obtaining the yield values. After that, the aspect of the liquid fraction was studied, differentiating which catalysts produced a larger quantity of waxy fraction and which ones did not. The viscosity of these samples was measured in order to confirm the catalysts that helped to obtain a less waxy fraction. The results showed that the zeolites Y and the zeolites β used in this study favor the obtaining of a compound with a smaller amount of waxes than for example catalysts such as FCC, ZSM-5 or SnCl 2 .

Suggested Citation

  • Lucía Quesada & Mónica Calero de Hoces & M. A. Martín-Lara & Germán Luzón & G. Blázquez, 2020. "Performance of Different Catalysts for the In Situ Cracking of the Oil-Waxes Obtained by the Pyrolysis of Polyethylene Film Waste," Sustainability, MDPI, vol. 12(13), pages 1-15, July.
    • Handle: RePEc:gam:jsusta:v:12:y:2020:i:13:p:5482-:d:381492
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2071-1050/12/13/5482/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/2071-1050/12/13/5482/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Quesada, L. & Calero, M. & Martín-Lara, M.A. & Pérez, A. & Blázquez, G., 2019. "Characterization of fuel produced by pyrolysis of plastic film obtained of municipal solid waste," Energy, Elsevier, vol. 186(C).
    2. Chattopadhyay, Jayeeta & Pathak, T.S. & Srivastava, R. & Singh, A.C., 2016. "Catalytic co-pyrolysis of paper biomass and plastic mixtures (HDPE (high density polyethylene), PP (polypropylene) and PET (polyethylene terephthalate)) and product analysis," Energy, Elsevier, vol. 103(C), pages 513-521.
    3. Kunwar, Bidhya & Cheng, H.N. & Chandrashekaran, Sriram R & Sharma, Brajendra K, 2016. "Plastics to fuel: a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 421-428.
    4. Lopez, Gartzen & Artetxe, Maite & Amutio, Maider & Bilbao, Javier & Olazar, Martin, 2017. "Thermochemical routes for the valorization of waste polyolefinic plastics to produce fuels and chemicals. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 346-368.
    5. Hongloi, Nitchakul & Prapainainar, Paweena & Seubsai, Anusorn & Sudsakorn, Kandis & Prapainainar, Chaiwat, 2019. "Nickel catalyst with different supports for green diesel production," Energy, Elsevier, vol. 182(C), pages 306-320.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chaudhary, Amita & Lakhani, Jay & Dalsaniya, Priyank & Chaudhary, Prins & Trada, Akshit & Shah, Niraj K. & Upadhyay, Darshit S., 2023. "Slow pyrolysis of low-density Poly-Ethylene (LDPE): A batch experiment and thermodynamic analysis," Energy, Elsevier, vol. 263(PB).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Anna Matuszewska & Adam Hańderek & Maciej Paczuski & Krzysztof Biernat, 2021. "Hydrocarbon Fractions from Thermolysis of Waste Plastics as Components of Engine Fuels," Energies, MDPI, vol. 14(21), pages 1-14, November.
    2. Wang, Shuang & Hwang, Sung-Chul & Yuan, Xiangzhou & Nam, Hyungseok, 2025. "Experimental investigation of oxy-combustion using plastic waste pyrolysis fuel for CO2 capture technology," Energy, Elsevier, vol. 325(C).
    3. Anna Matuszewska & Marlena Owczuk & Krzysztof Biernat, 2022. "Current Trends in Waste Plastics’ Liquefaction into Fuel Fraction: A Review," Energies, MDPI, vol. 15(8), pages 1-32, April.
    4. Choi, Dongho & Jung, Sungyup & Lee, Sang Soo & Lin, Kun-Yi Andrew & Park, Young-Kwon & Kim, Hana & Tsang, Yiu Fai & Kwon, Eilhann E., 2021. "Leveraging carbon dioxide to control the H2/CO ratio in catalytic pyrolysis of fishing net waste," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    5. Zhang, Yayun & Duan, Dengle & Lei, Hanwu & Villota, Elmar & Ruan, Roger, 2019. "Jet fuel production from waste plastics via catalytic pyrolysis with activated carbons," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    6. Natacha Phetyim & Sommai Pivsa-Art, 2018. "Prototype Co-Pyrolysis of Used Lubricant Oil and Mixed Plastic Waste to Produce a Diesel-Like Fuel," Energies, MDPI, vol. 11(11), pages 1-11, November.
    7. Zhao, Xiang & Klemeš, Jiří Jaromír & Fengqi You,, 2022. "Energy and environmental sustainability of waste personal protective equipment (PPE) treatment under COVID-19," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).
    8. Alexey Paukov & Romen Magaril & Elena Magaril, 2019. "An Investigation of the Feasibility of the Organic Municipal Solid Waste Processing by Coking," Sustainability, MDPI, vol. 11(2), pages 1-13, January.
    9. Farihahusnah Hussin & Mohamed Kheireddine Aroua & Mohd Azlan Kassim & Umi Fazara Md. Ali, 2021. "Transforming Plastic Waste into Porous Carbon for Capturing Carbon Dioxide: A Review," Energies, MDPI, vol. 14(24), pages 1-22, December.
    10. Kumar, Akash & Yan, Beibei & Tao, Junyu & Li, Jian & Kumari, Lata & Oba, Belay Tafa & Aborisade, Moses Akintayo & Chen, Guanyi, 2022. "Influence of waste plastic on pyrolysis of low-lipid microalgae: A study on thermokinetics, behaviors, evolved gas characteristics, and products distribution," Renewable Energy, Elsevier, vol. 185(C), pages 416-430.
    11. Huang, Jijiang & Veksha, Andrei & Chan, Wei Ping & Giannis, Apostolos & Lisak, Grzegorz, 2022. "Chemical recycling of plastic waste for sustainable material management: A prospective review on catalysts and processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    12. Chhabra, Vibhuti & Bambery, Keith & Bhattacharya, Sankar & Shastri, Yogendra, 2020. "Thermal and in situ infrared analysis to characterise the slow pyrolysis of mixed municipal solid waste (MSW) and its components," Renewable Energy, Elsevier, vol. 148(C), pages 388-401.
    13. Nawaz, Ahmad & Razzak, Shaikh Abdur, 2024. "Co-pyrolysis of biomass and different plastic waste to reduce hazardous waste and subsequent production of energy products: A review on advancement, synergies, and future prospects," Renewable Energy, Elsevier, vol. 224(C).
    14. Suarez, Mayra Alejandra & Januszewicz, Katarzyna & Cortazar, Maria & Lopez, Gartzen & Santamaria, Laura & Olazar, Martin & Artetxe, Maite & Amutio, Maider, 2024. "Selective H2 production from plastic waste through pyrolysis and in-line oxidative steam reforming," Energy, Elsevier, vol. 302(C).
    15. Marlina, Ena & Alhikami, Akhmad Faruq & Siyamuddin, Mursit & Aniza, Ria & Wang, Wei Cheng & Tijani, Alhassan Salami & Mustapa, Mohammad Sukri & Trismawati,, 2025. "Enhancing the combustion characteristics of plastic pyrolytic oils by doping nanocarbon additives for alternative energy," Energy, Elsevier, vol. 322(C).
    16. Muthukumar, K. & Kasiraman, G., 2024. "Utilization of fuel energy from single-use Low-density polyethylene plastic waste on CI engine with hydrogen enrichment – An experimental study," Energy, Elsevier, vol. 289(C).
    17. Fivga, Antzela & Dimitriou, Ioanna, 2018. "Pyrolysis of plastic waste for production of heavy fuel substitute: A techno-economic assessment," Energy, Elsevier, vol. 149(C), pages 865-874.
    18. Fernanda Paula da Costa Assunção & Diogo Oliveira Pereira & Jéssica Cristina Conte da Silva & Jorge Fernando Hungria Ferreira & Kelly Christina Alves Bezerra & Lucas Pinto Bernar & Caio Campos Ferreir, 2022. "A Systematic Approach to Thermochemical Treatment of Municipal Household Solid Waste into Valuable Products: Analysis of Routes, Gravimetric Analysis, Pre-Treatment of Solid Mixtures, Thermochemical P," Energies, MDPI, vol. 15(21), pages 1-30, October.
    19. Stefania Lucantonio & Andrea Di Giuliano & Leucio Rossi & Katia Gallucci, 2023. "Green Diesel Production via Deoxygenation Process: A Review," Energies, MDPI, vol. 16(2), pages 1-44, January.
    20. Ounsuk, Patravee & Prapainainar, Chaiwat & Hongloi, Nitchakul & Sudsakorn, Kandis & Lalitpattarakit, Montida & Seubsai, Anusorn & Kiatkittipong, Worapon & Wongsakulphasatch, Suwimol & Assabumrungrat, , 2024. "Box-Behnken design optimizing operating conditions in bio-hydrogenated diesel production by using BHD product as a solvent," Renewable Energy, Elsevier, vol. 232(C).

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:12:y:2020:i:13:p:5482-:d:381492. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.