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Hydrogen Storage System Attained by HCOOH-CO 2 Couple: Recent Developments in Pd-Based Carbon-Supported Heterogeneous Catalysts

Author

Listed:
  • Paula Riquelme-García

    (Department of Inorganic Chemistry and Materials Institute, University of Alicante, Ap. 99, E-03080 Alicante, Spain)

  • Miriam Navlani-García

    (Department of Inorganic Chemistry and Materials Institute, University of Alicante, Ap. 99, E-03080 Alicante, Spain)

  • Diego Cazorla-Amorós

    (Department of Inorganic Chemistry and Materials Institute, University of Alicante, Ap. 99, E-03080 Alicante, Spain)

Abstract

The present review revisits representative studies addressing the development of efficient Pd-based carbon-supported heterogeneous catalysts for two important reactions, namely, the production of hydrogen from formic acid and the hydrogenation of carbon dioxide into formic acid. The HCOOH-CO 2 system is considered a promising couple for a hydrogen storage system involving an ideal carbon-neutral cycle. Significant advancements have been achieved in the catalysts designed to catalyze the dehydrogenation of formic acid under mild reaction conditions, while much effort is still needed to catalyze the challenging CO 2 hydrogenation reaction. The design of Pd-based carbon-supported heterogeneous catalysts for these reactions encompasses both the modulation of the properties of the active phase (particle size, composition, and electronic properties) and the modification of the supports by means of the incorporation of nitrogen functional groups. These approaches are herein summarized to provide a compilation of the strategies followed in recent studies and to set the basis for a hydrogen storage system attained using the HCOOH-CO 2 couple.

Suggested Citation

  • Paula Riquelme-García & Miriam Navlani-García & Diego Cazorla-Amorós, 2024. "Hydrogen Storage System Attained by HCOOH-CO 2 Couple: Recent Developments in Pd-Based Carbon-Supported Heterogeneous Catalysts," Energies, MDPI, vol. 17(1), pages 1-28, January.
    • Handle: RePEc:gam:jeners:v:17:y:2024:i:1:p:260-:d:1313012
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    References listed on IDEAS

    as
    1. Olga Podyacheva & Alexander Lisitsyn & Lidiya Kibis & Andrei Boronin & Olga Stonkus & Vladimir Zaikovskii & Arina Suboch & Vladimir Sobolev & Valentin Parmon, 2019. "Nitrogen Doped Carbon Nanotubes and Nanofibers for Green Hydrogen Production: Similarities in the Nature of Nitrogen Species, Metal–Nitrogen Interaction, and Catalytic Properties," Energies, MDPI, vol. 12(20), pages 1-14, October.
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