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Thermodynamic Analysis of Waste Vegetable Oil Conversion to Biodiesel with Solar Energy

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  • José A. León

    (Instituto de Ingeniería, Universidad Autónoma de Baja California, Boulevard Benito Juárez y Calle de la Normal S/N, Colonia Insurgentes Este, Mexicali 21280, Mexico)

  • Gisela Montero

    (Instituto de Ingeniería, Universidad Autónoma de Baja California, Boulevard Benito Juárez y Calle de la Normal S/N, Colonia Insurgentes Este, Mexicali 21280, Mexico)

  • Marcos A. Coronado

    (Instituto de Ingeniería, Universidad Autónoma de Baja California, Boulevard Benito Juárez y Calle de la Normal S/N, Colonia Insurgentes Este, Mexicali 21280, Mexico)

  • José R. Ayala

    (Instituto de Ingeniería, Universidad Autónoma de Baja California, Boulevard Benito Juárez y Calle de la Normal S/N, Colonia Insurgentes Este, Mexicali 21280, Mexico)

  • Daniela G. Montes

    (Instituto de Ingeniería, Universidad Autónoma de Baja California, Boulevard Benito Juárez y Calle de la Normal S/N, Colonia Insurgentes Este, Mexicali 21280, Mexico)

  • Laura J. Pérez

    (Instituto de Ingeniería, Universidad Autónoma de Baja California, Boulevard Benito Juárez y Calle de la Normal S/N, Colonia Insurgentes Este, Mexicali 21280, Mexico)

  • Lisandra Quintana

    (Instituto de Ingeniería, Universidad Autónoma de Baja California, Boulevard Benito Juárez y Calle de la Normal S/N, Colonia Insurgentes Este, Mexicali 21280, Mexico)

  • Jesús M. Armenta

    (Instituto de Ingeniería, Universidad Autónoma de Baja California, Boulevard Benito Juárez y Calle de la Normal S/N, Colonia Insurgentes Este, Mexicali 21280, Mexico)

Abstract

Exergy and energy analyses of two biodiesel production processes that integrate solar energy as the main energy source were developed to determine the process with the higher efficiency from an energy and exergy approach. The biodiesel production processes were simulated in ASPEN PLUS ®, and the solar energy supply was studied in TRNSYS ® , using EXCEL ® simultaneously for the exergetic analysis. The solar thermal energy collection system can supply 81% of the energy required by the alkali process in the Flash separation equipment. For the supercritical process, solar thermal energy can supply 74.5% of the energy in the preheating and separation stages. The energy efficiency of the supercritical process is higher; nevertheless, the exergetic efficiency of the alkaline process is higher than the supercritical one. Solar collection systems contribute from 85% to 93% of the exergy destroyed by the global process for both cases. The alkaline biodiesel production process has the highest advantages when using solar energy as the main source of energy, compared to a process in supercritical conditions that presents greater irreversibilities and requires more infrastructure to collect the solar resource. However, using solar energy as the foremost energy source offers an alternative to fossil fuels, and it provides an environmental benefit concurrently with the use of biodiesel.

Suggested Citation

  • José A. León & Gisela Montero & Marcos A. Coronado & José R. Ayala & Daniela G. Montes & Laura J. Pérez & Lisandra Quintana & Jesús M. Armenta, 2022. "Thermodynamic Analysis of Waste Vegetable Oil Conversion to Biodiesel with Solar Energy," Energies, MDPI, vol. 15(5), pages 1-17, March.
  • Handle: RePEc:gam:jeners:v:15:y:2022:i:5:p:1834-:d:762349
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    References listed on IDEAS

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    1. Jegannathan, Kenthorai Raman & Eng-Seng, Chan & Ravindra, Pogaku, 2011. "Economic assessment of biodiesel production: Comparison of alkali and biocatalyst processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 745-751, January.
    2. Talens, Laura & Villalba, Gara & Gabarrell, Xavier, 2007. "Exergy analysis applied to biodiesel production," Resources, Conservation & Recycling, Elsevier, vol. 51(2), pages 397-407.
    3. Ang, Gaik Tin & Tan, Kok Tat & Lee, Keat Teong, 2014. "Recent development and economic analysis of glycerol-free processes via supercritical fluid transesterification for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 61-70.
    4. Kallas, Zein & Gil, José María, 2015. "Do the Spanish want biodiesel? A case study in the Catalan transport sector," Renewable Energy, Elsevier, vol. 83(C), pages 398-406.
    5. Talens Peiró, L. & Villalba Méndez, G. & Sciubba, E. & Gabarrell i Durany, X., 2010. "Extended exergy accounting applied to biodiesel production," Energy, Elsevier, vol. 35(7), pages 2861-2869.
    6. Khoobbakht, Golmohammad & Kheiralipour, Kamran & Rasouli, Hamed & Rafiee, Mojtaba & Hadipour, Mehrdad & Karimi, Mahmoud, 2020. "Experimental exergy analysis of transesterification in biodiesel production," Energy, Elsevier, vol. 196(C).
    7. Gholami, Ali & Hajinezhad, Ahmad & Pourfayaz, Fathollah & Ahmadi, Mohammad Hossein, 2018. "The effect of hydrodynamic and ultrasonic cavitation on biodiesel production: An exergy analysis approach," Energy, Elsevier, vol. 160(C), pages 478-489.
    8. Castro Gonzáles, Nirza Fabiola, 2016. "International experiences with the cultivation of Jatropha curcas for biodiesel production," Energy, Elsevier, vol. 112(C), pages 1245-1258.
    9. Amelio, A. & Van de Voorde, T. & Creemers, C. & Degrève, J. & Darvishmanesh, S. & Luis, P. & Van der Bruggen, B., 2016. "Comparison between exergy and energy analysis for biodiesel production," Energy, Elsevier, vol. 98(C), pages 135-145.
    10. Goli, Jibril & Sahu, Omprakash, 2018. "Development of heterogeneous alkali catalyst from waste chicken eggshell for biodiesel production," Renewable Energy, Elsevier, vol. 128(PA), pages 142-154.
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    1. Audrius Bagdanavicius, 2022. "Energy and Exergy Analysis of Renewable Energy Conversion Systems," Energies, MDPI, vol. 15(15), pages 1-2, July.

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