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Hydrolytic Dehydrogenation of Ammonia Borane Attained by Ru-Based Catalysts: An Auspicious Option to Produce Hydrogen from a Solid Hydrogen Carrier Molecule

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  • Miriam Navlani-García

    (Department of Inorganic Chemistry and Materials Institute, University of Alicante, 03080 Alicante, Spain)

  • David Salinas-Torres

    (Department of Physical Chemistry and Materials Institute, University of Alicante, 03080 Alicante, Spain)

  • Diego Cazorla-Amorós

    (Department of Inorganic Chemistry and Materials Institute, University of Alicante, 03080 Alicante, Spain)

Abstract

Chemical hydrogen storage stands as a promising option to conventional storage methods. There are numerous hydrogen carrier molecules that afford satisfactory hydrogen capacity. Among them, ammonia borane has attracted great interest due to its high hydrogen capacity. Great efforts have been devoted to design and develop suitable catalysts to boost the production of hydrogen from ammonia borane, which is preferably attained by Ru catalysts. The present review summarizes some of the recent Ru-based heterogeneous catalysts applied in the hydrolytic dehydrogenation of ammonia borane, paying particular attention to those supported on carbon materials and oxides.

Suggested Citation

  • Miriam Navlani-García & David Salinas-Torres & Diego Cazorla-Amorós, 2021. "Hydrolytic Dehydrogenation of Ammonia Borane Attained by Ru-Based Catalysts: An Auspicious Option to Produce Hydrogen from a Solid Hydrogen Carrier Molecule," Energies, MDPI, vol. 14(8), pages 1-20, April.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:8:p:2199-:d:536487
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    References listed on IDEAS

    as
    1. Umit Bilge Demirci, 2020. "Ammonia Borane: An Extensively Studied, Though Not Yet Implemented, Hydrogen Carrier," Energies, MDPI, vol. 13(12), pages 1-45, June.
    2. Mazloomi, Kaveh & Gomes, Chandima, 2012. "Hydrogen as an energy carrier: Prospects and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3024-3033.
    3. Changjun Zhang, 2017. "Hydrogen storage: Improving reversibility," Nature Energy, Nature, vol. 2(4), pages 1-1, April.
    4. Miriam Navlani-García & David Salinas-Torres & Diego Cazorla-Amorós, 2019. "Hydrogen Production from Formic Acid Attained by Bimetallic Heterogeneous PdAg Catalytic Systems," Energies, MDPI, vol. 12(21), pages 1-27, October.
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