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Catalytic Hot Gas Cleanup of Biomass Gasification Producer Gas via Steam Reforming Using Nickel-Supported Clay Minerals

Author

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  • Prashanth Reddy Buchireddy

    (Chemical Engineering Department, University of Louisiana at Lafayette, Lafayette, LA 70504, USA)

  • Devin Peck

    (Chemical Engineering Department, University of Louisiana at Lafayette, Lafayette, LA 70504, USA)

  • Mark Zappi

    (Chemical Engineering Department, University of Louisiana at Lafayette, Lafayette, LA 70504, USA)

  • Ray Mark Bricka

    (Dave C. Swalm School of Chemical Engineering, Mississippi State University, Mississippi State, MS 39762, USA)

Abstract

Amongst the issues associated with the commercialization of biomass gasification, the presence of tars has been one of the most difficult aspects to address. Tars are an impurity generated from the gasifier and upon their condensation cause problems in downstream equipment including plugging, blockages, corrosion, and major catalyst deactivation. These problems lead to losses of efficiency as well as potential maintenance issues resulting from damaged processing units. Therefore, the removal of tars is necessary in order for the effective operation of a biomass gasification facility for the production of high-value fuel gas. The catalytic activity of montmorillonite and montmorillonite-supported nickel as tar removal catalysts will be investigated in this study. Ni-montmorillonite catalyst was prepared, characterized, and tested in a laboratory-scale reactor for its efficiency in reforming tars using naphthalene as a tar model compound. Efficacy of montmorillonite-supported nickel catalyst was tested as a function of nickel content, reaction temperature, steam-to-carbon ratio, and naphthalene loading. The results demonstrate that montmorillonite is catalytically active in removing naphthalene. Ni-montmorillonite had high activity towards naphthalene removal via steam reforming, with removal efficiencies greater than 99%. The activation energy was calculated for Ni-montmorillonite assuming first-order kinetics and was found to be 84.5 kJ/mole in accordance with the literature. Long-term activity tests were also conducted and showed that the catalyst was active with naphthalene removal efficiencies greater than 95% maintained over a 97-h test period. A little loss of activity was observed with a removal decrease from 97% to 95%. To investigate the decrease in catalytic activity, characterization of fresh and used catalyst samples was performed using thermogravimetric analysis, transmission electron microscopy, X-ray diffraction, and surface area analysis. The loss in activity was attributed to a decrease in catalyst surface area caused by nickel sintering and coke formation.

Suggested Citation

  • Prashanth Reddy Buchireddy & Devin Peck & Mark Zappi & Ray Mark Bricka, 2021. "Catalytic Hot Gas Cleanup of Biomass Gasification Producer Gas via Steam Reforming Using Nickel-Supported Clay Minerals," Energies, MDPI, vol. 14(7), pages 1-21, March.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:7:p:1875-:d:526042
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    References listed on IDEAS

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    1. Jinling Song & Chuyang Tang & Xinyuan An & Yi Wang & Shankun Zhou & Chunhong Huang, 2022. "Catalytic Pyrolysis of Sawdust with Desulfurized Fly Ash for Pyrolysis Gas Upgrading," IJERPH, MDPI, vol. 19(23), pages 1-11, November.
    2. Marcin Pajak & Grzegorz Brus & Janusz S. Szmyd, 2021. "Catalyst Distribution Optimization Scheme for Effective Green Hydrogen Production from Biogas Reforming," Energies, MDPI, vol. 14(17), pages 1-14, September.
    3. Mateusz Wnukowski & Wojciech Moroń, 2021. "Warm Plasma Application in Tar Conversion and Syngas Valorization: The Fate of Hydrogen Sulfide," Energies, MDPI, vol. 14(21), pages 1-16, November.
    4. Jhulimar Castro & Jonathan Leaver & Shusheng Pang, 2022. "Simulation and Techno-Economic Assessment of Hydrogen Production from Biomass Gasification-Based Processes: A Review," Energies, MDPI, vol. 15(22), pages 1-37, November.

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