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Application of Liquid Hydrogen Carriers in Hydrogen Steelmaking

Author

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  • Joakim Andersson

    (Department of Chemical Engineering, Division of Energy Processes, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden)

Abstract

Steelmaking is responsible for approximately one third of total industrial carbon dioxide (CO 2 ) emissions. Hydrogen (H 2 ) direct reduction (H-DR) may be a feasible route towards the decarbonization of primary steelmaking if H 2 is produced via electrolysis using fossil-free electricity. However, electrolysis is an electricity-intensive process. Therefore, it is preferable that H 2 is predominantly produced during times of low electricity prices, which is enabled by the storage of H 2 . This work compares the integration of H 2 storage in four liquid carriers, methanol (MeOH), formic acid (FA), ammonia (NH 3 ) and perhydro-dibenzyltoluene (H18-DBT), in H-DR processes. In contrast to conventional H 2 storage methods, these carriers allow for H 2 storage in liquid form at moderate overpressures, reducing the storage capacity cost. The main downside to liquid H 2 carriers is that thermochemical processes are necessary for both the storage and release processes, often with significant investment and operational costs. The carriers are compared using thermodynamic and economic data to estimate operational and capital costs in the H-DR context considering process integration options. It is concluded that the use of MeOH is promising compared to the other considered carriers. For large storage volumes, MeOH-based H 2 storage may also be an attractive option to the underground storage of compressed H 2 . The other considered liquid H 2 carriers suffer from large thermodynamic barriers for hydrogenation (FA) or dehydrogenation (NH 3 , H18-DBT) and higher investment costs. However, for the use of MeOH in an H-DR process to be practically feasible, questions regarding process flexibility and the optimal sourcing of CO 2 and heat must be answered.

Suggested Citation

  • Joakim Andersson, 2021. "Application of Liquid Hydrogen Carriers in Hydrogen Steelmaking," Energies, MDPI, vol. 14(5), pages 1-26, March.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:5:p:1392-:d:509836
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    References listed on IDEAS

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    1. Bos, M.J. & Kersten, S.R.A. & Brilman, D.W.F., 2020. "Wind power to methanol: Renewable methanol production using electricity, electrolysis of water and CO2 air capture," Applied Energy, Elsevier, vol. 264(C).
    2. Eypasch, Martin & Schimpe, Michael & Kanwar, Aastha & Hartmann, Tobias & Herzog, Simon & Frank, Torsten & Hamacher, Thomas, 2017. "Model-based techno-economic evaluation of an electricity storage system based on Liquid Organic Hydrogen Carriers," Applied Energy, Elsevier, vol. 185(P1), pages 320-330.
    3. Arpagaus, Cordin & Bless, Frédéric & Uhlmann, Michael & Schiffmann, Jürg & Bertsch, Stefan S., 2018. "High temperature heat pumps: Market overview, state of the art, research status, refrigerants, and application potentials," Energy, Elsevier, vol. 152(C), pages 985-1010.
    4. Panagiota Stathi & Maria Solakidou & Maria Louloudi & Yiannis Deligiannakis, 2020. "From Homogeneous to Heterogenized Molecular Catalysts for H 2 Production by Formic Acid Dehydrogenation: Mechanistic Aspects, Role of Additives, and Co-Catalysts," Energies, MDPI, vol. 13(3), pages 1-25, February.
    5. Lundgren, J. & Ekbom, T. & Hulteberg, C. & Larsson, M. & Grip, C.-E. & Nilsson, L. & Tunå, P., 2013. "Methanol production from steel-work off-gases and biomass based synthesis gas," Applied Energy, Elsevier, vol. 112(C), pages 431-439.
    6. Reuß, M. & Grube, T. & Robinius, M. & Preuster, P. & Wasserscheid, P. & Stolten, D., 2017. "Seasonal storage and alternative carriers: A flexible hydrogen supply chain model," Applied Energy, Elsevier, vol. 200(C), pages 290-302.
    7. Fikrt, André & Brehmer, Richard & Milella, Vito-Oronzo & Müller, Karsten & Bösmann, Andreas & Preuster, Patrick & Alt, Nicolas & Schlücker, Eberhard & Wasserscheid, Peter & Arlt, Wolfgang, 2017. "Dynamic power supply by hydrogen bound to a liquid organic hydrogen carrier," Applied Energy, Elsevier, vol. 194(C), pages 1-8.
    8. Schulte Beerbühl, S. & Fröhling, M. & Schultmann, F., 2015. "Combined scheduling and capacity planning of electricity-based ammonia production to integrate renewable energies," European Journal of Operational Research, Elsevier, vol. 241(3), pages 851-862.
    9. Nikolaidis, Pavlos & Poullikkas, Andreas, 2017. "A comparative overview of hydrogen production processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 597-611.
    10. Gabrielli, Paolo & Poluzzi, Alessandro & Kramer, Gert Jan & Spiers, Christopher & Mazzotti, Marco & Gazzani, Matteo, 2020. "Seasonal energy storage for zero-emissions multi-energy systems via underground hydrogen storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    11. Marinos Theodorakopoulos & Maria Solakidou & Yiannis Deligiannakis & Maria Louloudi, 2021. "A Use-Store-Reuse (USR) Concept in Catalytic HCOOH Dehydrogenation: Case-Study of a Ru-Based Catalytic System for Long-Term USR under Ambient O 2," Energies, MDPI, vol. 14(2), pages 1-10, January.
    12. Kim, Dongin & Han, Jeehoon, 2020. "Comprehensive analysis of two catalytic processes to produce formic acid from carbon dioxide," Applied Energy, Elsevier, vol. 264(C).
    13. Pérez-Fortes, Mar & Schöneberger, Jan C. & Boulamanti, Aikaterini & Tzimas, Evangelos, 2016. "Methanol synthesis using captured CO2 as raw material: Techno-economic and environmental assessment," Applied Energy, Elsevier, vol. 161(C), pages 718-732.
    14. Purna Chandra Rao & Minyoung Yoon, 2020. "Potential Liquid-Organic Hydrogen Carrier (LOHC) Systems: A Review on Recent Progress," Energies, MDPI, vol. 13(22), pages 1-23, November.
    15. Buttler, Alexander & Spliethoff, Hartmut, 2018. "Current status of water electrolysis for energy storage, grid balancing and sector coupling via power-to-gas and power-to-liquids: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2440-2454.
    16. Muhammad Aziz & Agung Tri Wijayanta & Asep Bayu Dani Nandiyanto, 2020. "Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization," Energies, MDPI, vol. 13(12), pages 1-25, June.
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    1. Ju-Yeol Ryu & Sungho Park & Changhyeong Lee & Seonghyeon Hwang & Jongwoong Lim, 2023. "Techno-Economic Analysis of Hydrogen–Natural Gas Blended Fuels for 400 MW Combined Cycle Power Plants (CCPPs)," Energies, MDPI, vol. 16(19), pages 1-19, September.
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    3. Zaiter, Issa & Ramadan, Mohamad & Bouabid, Ali & El-Fadel, Mutasem & Mezher, Toufic, 2023. "Potential utilization of hydrogen in the UAE's industrial sector," Energy, Elsevier, vol. 280(C).

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