IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v13y2020i22p6040-d447474.html
   My bibliography  Save this article

Potential Liquid-Organic Hydrogen Carrier (LOHC) Systems: A Review on Recent Progress

Author

Listed:
  • Purna Chandra Rao

    (Department of Chemistry & Green-Nano Materials Research Center, Kyungpook National University, Daegu 41566, Korea)

  • Minyoung Yoon

    (Department of Chemistry & Green-Nano Materials Research Center, Kyungpook National University, Daegu 41566, Korea)

Abstract

The depletion of fossil fuels and rising global warming challenges encourage to find safe and viable energy storage and delivery technologies. Hydrogen is a clean, efficient energy carrier in various mobile fuel-cell applications and owned no adverse effects on the environment and human health. However, hydrogen storage is considered a bottleneck problem for the progress of the hydrogen economy. Liquid-organic hydrogen carriers (LOHCs) are organic substances in liquid or semi-solid states that store hydrogen by catalytic hydrogenation and dehydrogenation processes over multiple cycles and may support a future hydrogen economy. Remarkably, hydrogen storage in LOHC systems has attracted dramatically more attention than conventional storage systems, such as high-pressure compression, liquefaction, and absorption/adsorption techniques. Potential LOHC media must provide fully reversible hydrogen storage via catalytic processes, thermal stability, low melting points, favorable hydrogenation thermodynamics and kinetics, large-scale availability, and compatibility with current fuel energy infrastructure to practically employ these molecules in various applications. In this review, we present various considerable aspects for the development of ideal LOHC systems. We highlight the recent progress of LOHC candidates and their catalytic approach, as well as briefly discuss the theoretical insights for understanding the reaction mechanism.

Suggested Citation

  • Purna Chandra Rao & Minyoung Yoon, 2020. "Potential Liquid-Organic Hydrogen Carrier (LOHC) Systems: A Review on Recent Progress," Energies, MDPI, vol. 13(22), pages 1-23, November.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:22:p:6040-:d:447474
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/13/22/6040/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/13/22/6040/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Daniel Forberg & Tobias Schwob & Muhammad Zaheer & Martin Friedrich & Nobuyoshi Miyajima & Rhett Kempe, 2016. "Single-catalyst high-weight% hydrogen storage in an N-heterocycle synthesized from lignin hydrogenolysis products and ammonia," Nature Communications, Nature, vol. 7(1), pages 1-6, December.
    2. Eypasch, Martin & Schimpe, Michael & Kanwar, Aastha & Hartmann, Tobias & Herzog, Simon & Frank, Torsten & Hamacher, Thomas, 2017. "Model-based techno-economic evaluation of an electricity storage system based on Liquid Organic Hydrogen Carriers," Applied Energy, Elsevier, vol. 185(P1), pages 320-330.
    3. Haupt, Axel & Müller, Karsten, 2017. "Integration of a LOHC storage into a heat-controlled CHP system," Energy, Elsevier, vol. 118(C), pages 1123-1130.
    4. Saxena, R.C. & Seal, Diptendu & Kumar, Satinder & Goyal, H.B., 2008. "Thermo-chemical routes for hydrogen rich gas from biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(7), pages 1909-1927, September.
    5. Teichmann, Daniel & Stark, Katharina & Müller, Karsten & Zöttl, Gregor & Wasserscheid, Peter & Arlt, Wolfgang, 2012. "Energy storage in residential and commercial buildings via Liquid Organic Hydrogen Carriers (LOHC)," Munich Reprints in Economics 18079, University of Munich, Department of Economics.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Alina E. Kozhukhova & Stephanus P. du Preez & Dmitri G. Bessarabov, 2021. "Catalytic Hydrogen Combustion for Domestic and Safety Applications: A Critical Review of Catalyst Materials and Technologies," Energies, MDPI, vol. 14(16), pages 1-32, August.
    2. Zhan Xu & Ning Zhao & Stuart Hillmansen & Clive Roberts & Yan Yan, 2022. "Techno-Economic Analysis of Hydrogen Storage Technologies for Railway Engineering: A Review," Energies, MDPI, vol. 15(17), pages 1-22, September.
    3. Muhammad Aziz, 2021. "Liquid Hydrogen: A Review on Liquefaction, Storage, Transportation, and Safety," Energies, MDPI, vol. 14(18), pages 1-29, September.
    4. Usman, Muhammad R., 2022. "Hydrogen storage methods: Review and current status," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    5. Nguyen Van Duc Long & Le Cao Nhien & Moonyong Lee, 2023. "Advanced Technologies in Hydrogen Revolution," Energies, MDPI, vol. 16(5), pages 1-4, February.
    6. Farea Asif & Muhammad Haris Hamayun & Murid Hussain & Arif Hussain & Ibrahim M. Maafa & Young-Kwon Park, 2021. "Performance Analysis of the Perhydro-Dibenzyl-Toluene Dehydrogenation System—A Simulation Study," Sustainability, MDPI, vol. 13(11), pages 1-14, June.
    7. Carlos A. Castilla-Martinez & Romain Moury & Salem Ould-Amara & Umit B. Demirci, 2021. "Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances," Energies, MDPI, vol. 14(21), pages 1-50, October.
    8. Joakim Andersson, 2021. "Application of Liquid Hydrogen Carriers in Hydrogen Steelmaking," Energies, MDPI, vol. 14(5), pages 1-26, March.
    9. Hong, Sanghyun & Kim, Eunsung & Jeong, Saerok, 2023. "Evaluating the sustainability of the hydrogen economy using multi-criteria decision-making analysis in Korea," Renewable Energy, Elsevier, vol. 204(C), pages 485-492.
    10. Dmitri A. Bulushev, 2021. "Progress in Catalytic Hydrogen Production from Formic Acid over Supported Metal Complexes," Energies, MDPI, vol. 14(5), pages 1-14, March.
    11. Oner, Oytun & Khalilpour, Kaveh, 2022. "Evaluation of green hydrogen carriers: A multi-criteria decision analysis tool," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    12. Omran, Ahmed & Nesterenko, Nikolay & Valtchev, Valentin, 2022. "Zeolitic ice: A route toward net zero emissions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    13. Baldi, Francesco & Coraddu, Andrea & Kalikatzarakis, Miltiadis & Jeleňová, Diana & Collu, Maurizio & Race, Julia & Maréchal, François, 2022. "Optimisation-based system designs for deep offshore wind farms including power to gas technologies," Applied Energy, Elsevier, vol. 310(C).
    14. Godinho, João & Hoefnagels, Ric & Braz, Catarina G. & Sousa, Ana M. & Granjo, José F.O., 2023. "An economic and greenhouse gas footprint assessment of international maritime transportation of hydrogen using liquid organic hydrogen carriers," Energy, Elsevier, vol. 278(PA).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yee Mah, Angel Xin & Ho, Wai Shin & Hassim, Mimi H. & Hashim, Haslenda & Liew, Peng Yen & Muis, Zarina Ab, 2021. "Targeting and scheduling of standalone renewable energy system with liquid organic hydrogen carrier as energy storage," Energy, Elsevier, vol. 218(C).
    2. Fikrt, André & Brehmer, Richard & Milella, Vito-Oronzo & Müller, Karsten & Bösmann, Andreas & Preuster, Patrick & Alt, Nicolas & Schlücker, Eberhard & Wasserscheid, Peter & Arlt, Wolfgang, 2017. "Dynamic power supply by hydrogen bound to a liquid organic hydrogen carrier," Applied Energy, Elsevier, vol. 194(C), pages 1-8.
    3. Brigljević, Boris & Byun, Manhee & Lim, Hankwon, 2020. "Design, economic evaluation, and market uncertainty analysis of LOHC-based, CO2 free, hydrogen delivery systems," Applied Energy, Elsevier, vol. 274(C).
    4. Jiecheng Zhu & Xitian Wang & Da Xie & Chenghong Gu, 2019. "Control Strategy for MGT Generation System Optimized by Improved WOA to Enhance Demand Response Capability," Energies, MDPI, vol. 12(16), pages 1-20, August.
    5. Smoliński, A. & Howaniec, N. & Stańczyk, K., 2011. "A comparative experimental study of biomass, lignite and hard coal steam gasification," Renewable Energy, Elsevier, vol. 36(6), pages 1836-1842.
    6. Abadie, Luis Mª & Chamorro, José M., 2023. "Investment in wind-based hydrogen production under economic and physical uncertainties," Applied Energy, Elsevier, vol. 337(C).
    7. Hong, Sanghyun & Kim, Eunsung & Jeong, Saerok, 2023. "Evaluating the sustainability of the hydrogen economy using multi-criteria decision-making analysis in Korea," Renewable Energy, Elsevier, vol. 204(C), pages 485-492.
    8. M. Faizal & L. S. Chuah & C. Lee & A. Hameed & J. Lee & M. Shankar, 2019. "Review Of Hydrogen Fuel For Internal Combustion Engines," Journal of Mechanical Engineering Research & Developments (JMERD), Zibeline International Publishing, vol. 42(3), pages 35-46, April.
    9. Zhou, Hui & Park, Ah-Hyung Alissa, 2020. "Bio-energy with carbon capture and storage via alkaline thermal Treatment: Production of high purity H2 from wet wheat straw grass with CO2 capture," Applied Energy, Elsevier, vol. 264(C).
    10. Duo Wei & Rui Sang & Peter Sponholz & Henrik Junge & Matthias Beller, 2022. "Reversible hydrogenation of carbon dioxide to formic acid using a Mn-pincer complex in the presence of lysine," Nature Energy, Nature, vol. 7(5), pages 438-447, May.
    11. Eypasch, Martin & Schimpe, Michael & Kanwar, Aastha & Hartmann, Tobias & Herzog, Simon & Frank, Torsten & Hamacher, Thomas, 2017. "Model-based techno-economic evaluation of an electricity storage system based on Liquid Organic Hydrogen Carriers," Applied Energy, Elsevier, vol. 185(P1), pages 320-330.
    12. Li, Nan & Zhao, Xunwen & Shi, Xunpeng & Pei, Zhenwei & Mu, Hailin & Taghizadeh-Hesary, Farhad, 2021. "Integrated energy systems with CCHP and hydrogen supply: A new outlet for curtailed wind power," Applied Energy, Elsevier, vol. 303(C).
    13. Burra, K.G. & Hussein, M.S. & Amano, R.S. & Gupta, A.K., 2016. "Syngas evolutionary behavior during chicken manure pyrolysis and air gasification," Applied Energy, Elsevier, vol. 181(C), pages 408-415.
    14. Stöckl, Fabian & Schill, Wolf-Peter & Zerrahn, Alexander, 2021. "Optimal supply chains and power sector benefits of green hydrogen," EconStor Open Access Articles and Book Chapters, ZBW - Leibniz Information Centre for Economics, vol. 11.
    15. Lee, Sanghun & Kim, Taehong & Han, Gwangwoo & Kang, Sungmin & Yoo, Young-Sung & Jeon, Sang-Yun & Bae, Joongmyeon, 2021. "Comparative energetic studies on liquid organic hydrogen carrier: A net energy analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    16. Klamka, Jonas & Wolf, André & Ehrlich, Lars G., 2020. "Photovoltaic self-consumption after the support period: Will it pay off in a cross-sector perspective?," Renewable Energy, Elsevier, vol. 147(P1), pages 2374-2386.
    17. Hughes, Ben Richard & Chaudhry, Hassam Nasarullah & Calautit, John Kaiser, 2014. "Passive energy recovery from natural ventilation air streams," Applied Energy, Elsevier, vol. 113(C), pages 127-140.
    18. Frank, Matthias & Deja, Robert & Peters, Roland & Blum, Ludger & Stolten, Detlef, 2018. "Bypassing renewable variability with a reversible solid oxide cell plant," Applied Energy, Elsevier, vol. 217(C), pages 101-112.
    19. Groll, Manfred, 2023. "Can climate change be avoided? Vision of a hydrogen-electricity energy economy," Energy, Elsevier, vol. 264(C).
    20. Hoffmann, Maximilian & Priesmann, Jan & Nolting, Lars & Praktiknjo, Aaron & Kotzur, Leander & Stolten, Detlef, 2021. "Typical periods or typical time steps? A multi-model analysis to determine the optimal temporal aggregation for energy system models," Applied Energy, Elsevier, vol. 304(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:13:y:2020:i:22:p:6040-:d:447474. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.