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MW Synthesis of ZIF-7. The Effect of Solvent on Particle Size and Hydrogen Sorption Properties

Author

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  • Vladimir A. Polyakov

    (The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, Russia)

  • Vera V. Butova

    (The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, Russia)

  • Elena A. Erofeeva

    (The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, Russia)

  • Andrei A. Tereshchenko

    (The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, Russia)

  • Alexander V. Soldatov

    (The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, Russia)

Abstract

We report here fast (15 min) microwave-assisted solvothermal synthesis of zeolitic imidazolate framework material (ZIF-7). We have optimized solvent composition to achieve high porosity and hydrogen capacity and narrow particle size distribution. It was shown that synthesis in N,N-diethylformamide (DEF) results in a layered ZIF-7 III phase, while N,N-dimethylformamide (DMF) as solvent leads to a pure ZIF-7 phase in microwave conditions. A mixture of toluene with DMF allows the production of pure ZIF-7 material only with the triethylamine additive. Obtained materials were comprehensively characterized. We have pointed out that both X-ray diffraction and infrared spectroscopy could be used for the identification of ZIF-7 or ZIF-7 III phases. Although samples obtained in DMF, and in a mixture of DMF, toluene, and triethylamine were assigned to the pure ZIF-7 phase, solvent composition significantly affected the size of particles in the material and nitrogen and hydrogen adsorption process.

Suggested Citation

  • Vladimir A. Polyakov & Vera V. Butova & Elena A. Erofeeva & Andrei A. Tereshchenko & Alexander V. Soldatov, 2020. "MW Synthesis of ZIF-7. The Effect of Solvent on Particle Size and Hydrogen Sorption Properties," Energies, MDPI, vol. 13(23), pages 1-12, November.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:23:p:6306-:d:453451
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    References listed on IDEAS

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    1. Pu Zhao & Hong Fang & Sanghamitra Mukhopadhyay & Aurelia Li & Svemir Rudić & Ian J. McPherson & Chiu C. Tang & David Fairen-Jimenez & S. C. Edman Tsang & Simon A. T. Redfern, 2019. "Structural dynamics of a metal–organic framework induced by CO2 migration in its non-uniform porous structure," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    2. Barelli, L. & Bidini, G. & Gallorini, F. & Servili, S., 2008. "Hydrogen production through sorption-enhanced steam methane reforming and membrane technology: A review," Energy, Elsevier, vol. 33(4), pages 554-570.
    3. Mazloomi, Kaveh & Gomes, Chandima, 2012. "Hydrogen as an energy carrier: Prospects and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3024-3033.
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