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The Impact of Additives on the Main Properties of Phase Change Materials

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  • Ewelina Radomska

    (Department of Thermal and Fluid Flow Machines, Faculty of Energy and Fuels, AGH University of Science and Technology, Mickiewicza 30 St., 30-059 Krakow, Poland)

  • Lukasz Mika

    (Department of Thermal and Fluid Flow Machines, Faculty of Energy and Fuels, AGH University of Science and Technology, Mickiewicza 30 St., 30-059 Krakow, Poland)

  • Karol Sztekler

    (Department of Thermal and Fluid Flow Machines, Faculty of Energy and Fuels, AGH University of Science and Technology, Mickiewicza 30 St., 30-059 Krakow, Poland)

Abstract

The main drawback of phase change materials (PCMs) is their low thermal conductivity, which limits the possibilities of a wide range of implementations. Therefore, the researchers, as found in the literature, proposed several methods to improve the thermal conductivity of PCMs, including inserting high thermal conductivity materials in nano-, micro-, and macro-scales, as well as encapsulation of PCMs. However, these inserts impact the other properties of PCMs like latent heat, melting temperature, thermal stability, and cycling stability. Hence, this paper aims to review the available in the open literature research on the main properties of enhanced PCMs that undergo solid–liquid transition. It is found that inserting high thermal conductivity materials and encapsulation results in improved thermal conductivity of PCMs, but it decreases their latent heat. Moreover, the insertions can act as nucleating agents, and the supercooling degree can be reduced. Some of the thermal conductivity enhancers (TCEs) may prevent PCMs from leakage. However, some test results are inconsistent and some seem to be questionable. Therefore, this review indicates these discrepancies and gaps in knowledge and points out possible directions for further research.

Suggested Citation

  • Ewelina Radomska & Lukasz Mika & Karol Sztekler, 2020. "The Impact of Additives on the Main Properties of Phase Change Materials," Energies, MDPI, vol. 13(12), pages 1-34, June.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:12:p:3064-:d:371013
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    as
    1. Iqbal, Kashif & Sun, Danmei, 2014. "Development of thermo-regulating polypropylene fibre containing microencapsulated phase change materials," Renewable Energy, Elsevier, vol. 71(C), pages 473-479.
    2. Mohamed, Shamseldin A. & Al-Sulaiman, Fahad A. & Ibrahim, Nasiru I. & Zahir, Md. Hasan & Al-Ahmed, Amir & Saidur, R. & Yılbaş, B.S. & Sahin, A.Z., 2017. "A review on current status and challenges of inorganic phase change materials for thermal energy storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1072-1089.
    3. Zhong, Yajuan & Zhao, Bingchen & Lin, Jun & Zhang, Feng & Wang, Haoran & Zhu, Zhiyong & Dai, Zhimin, 2019. "Encapsulation of high-temperature inorganic phase change materials using graphite as heat transfer enhancer," Renewable Energy, Elsevier, vol. 133(C), pages 240-247.
    4. Scapino, Luca & Zondag, Herbert A. & Van Bael, Johan & Diriken, Jan & Rindt, Camilo C.M., 2017. "Sorption heat storage for long-term low-temperature applications: A review on the advancements at material and prototype scale," Applied Energy, Elsevier, vol. 190(C), pages 920-948.
    5. Zhu, Xiao & Han, Liang & Lu, Yunfeng & Wei, Fei & Jia, Xilai, 2019. "Geometry-induced thermal storage enhancement of shape-stabilized phase change materials based on oriented carbon nanotubes," Applied Energy, Elsevier, vol. 254(C).
    6. Juan Duan & Yongliang Xiong & Dan Yang, 2019. "Melting Behavior of Phase Change Material in Honeycomb Structures with Different Geometrical Cores," Energies, MDPI, vol. 12(15), pages 1-19, July.
    7. Du, Kun & Calautit, John & Wang, Zhonghua & Wu, Yupeng & Liu, Hao, 2018. "A review of the applications of phase change materials in cooling, heating and power generation in different temperature ranges," Applied Energy, Elsevier, vol. 220(C), pages 242-273.
    8. Li, Chuan & Li, Qi & Cong, Lin & jiang, Feng & Zhao, Yanqi & Liu, Chuanping & Xiong, Yaxuan & Chang, Chun & Ding, Yulong, 2019. "MgO based composite phase change materials for thermal energy storage: The effects of MgO particle density and size on microstructural characteristics as well as thermophysical and mechanical properti," Applied Energy, Elsevier, vol. 250(C), pages 81-91.
    9. Jiang, Z.Y. & Qu, Z.G., 2019. "Lithium–ion battery thermal management using heat pipe and phase change material during discharge–charge cycle: A comprehensive numerical study," Applied Energy, Elsevier, vol. 242(C), pages 378-392.
    10. Wu, Weixiong & Wu, Wei & Wang, Shuangfeng, 2019. "Form-stable and thermally induced flexible composite phase change material for thermal energy storage and thermal management applications," Applied Energy, Elsevier, vol. 236(C), pages 10-21.
    11. Li, Chaoen & Yu, Hang & Song, Yuan & Wang, Meng & Liu, Zhiyuan, 2020. "A n-octadecane/hierarchically porous TiO2 form-stable PCM for thermal energy storage," Renewable Energy, Elsevier, vol. 145(C), pages 1465-1473.
    12. Zhang, Zhishan & Lian, Yadong & Xu, Xibin & Xu, Xiaonong & Fang, Guiyin & Gu, Min, 2019. "Synthesis and characterization of microencapsulated sodium sulfate decahydrate as phase change energy storage materials," Applied Energy, Elsevier, vol. 255(C).
    13. Huanpei Zheng & Changhong Wang, 2017. "Numerical and Experimental Studies on the Heat Transfer Performance of Copper Foam Filled with Paraffin," Energies, MDPI, vol. 10(7), pages 1-13, July.
    14. Tatsidjodoung, Parfait & Le Pierrès, Nolwenn & Luo, Lingai, 2013. "A review of potential materials for thermal energy storage in building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 327-349.
    15. Alva, Guruprasad & Lin, Yaxue & Fang, Guiyin, 2018. "An overview of thermal energy storage systems," Energy, Elsevier, vol. 144(C), pages 341-378.
    16. Li, Dacheng & Wang, Jihong & Ding, Yulong & Yao, Hua & Huang, Yun, 2019. "Dynamic thermal management for industrial waste heat recovery based on phase change material thermal storage," Applied Energy, Elsevier, vol. 236(C), pages 1168-1182.
    17. Yuan, Mengdi & Ren, Yunxiu & Xu, Chao & Ye, Feng & Du, Xiaoze, 2019. "Characterization and stability study of a form-stable erythritol/expanded graphite composite phase change material for thermal energy storage," Renewable Energy, Elsevier, vol. 136(C), pages 211-222.
    18. Liu, Lingkun & Su, Di & Tang, Yaojie & Fang, Guiyin, 2016. "Thermal conductivity enhancement of phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 305-317.
    19. Rajendran Prabakaran & Shaji Sidney & Dhasan Mohan Lal & C. Selvam & Sivasankaran Harish, 2019. "Solidification of Graphene-Assisted Phase Change Nanocomposites inside a Sphere for Cold Storage Applications," Energies, MDPI, vol. 12(18), pages 1-16, September.
    20. Lizana, Jesús & Chacartegui, Ricardo & Barrios-Padura, Angela & Valverde, José Manuel, 2017. "Advances in thermal energy storage materials and their applications towards zero energy buildings: A critical review," Applied Energy, Elsevier, vol. 203(C), pages 219-239.
    21. Lin, Yaxue & Jia, Yuting & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal conductivity enhancement, thermal properties and applications of phase change materials in thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2730-2742.
    22. Gu, Xiaobin & Liu, Peng & Bian, Liang & He, Huichao, 2019. "Enhanced thermal conductivity of palmitic acid/mullite phase change composite with graphite powder for thermal energy storage," Renewable Energy, Elsevier, vol. 138(C), pages 833-841.
    23. Soni, Vikram & Kumar, Arvind & Jain, V.K., 2018. "Performance evaluation of nano-enhanced phase change materials during discharge stage in waste heat recovery," Renewable Energy, Elsevier, vol. 127(C), pages 587-601.
    24. Bolin Chen & Meng Han & Bowei Zhang & Gaoyuan Ouyang & Behrouz Shafei & Xinwei Wang & Shan Hu, 2019. "Efficient Solar-to-Thermal Energy Conversion and Storage with High-Thermal-Conductivity and Form-Stabilized Phase Change Composite Based on Wood-Derived Scaffolds," Energies, MDPI, vol. 12(7), pages 1-11, April.
    25. Damien Mathis & Pierre Blanchet & Philippe Lagière & Véronic Landry, 2018. "Performance of Wood-Based Panels Integrated with a Bio-Based Phase Change Material: A Full-Scale Experiment in a Cold Climate with Timber-Frame Huts," Energies, MDPI, vol. 11(11), pages 1-15, November.
    26. Xue Chen & Xiaolei Li & Xinlin Xia & Chuang Sun & Rongqiang Liu, 2019. "Thermal Performance of a PCM-Based Thermal Energy Storage with Metal Foam Enhancement," Energies, MDPI, vol. 12(17), pages 1-18, August.
    27. Li, Shuang-Fei & Liu, Zhen-hua & Wang, Xue-Jiao, 2019. "A comprehensive review on positive cold energy storage technologies and applications in air conditioning with phase change materials," Applied Energy, Elsevier, vol. 255(C).
    28. Xu, Yang & Li, Ming-Jia & Zheng, Zhang-Jing & Xue, Xiao-Dai, 2018. "Melting performance enhancement of phase change material by a limited amount of metal foam: Configurational optimization and economic assessment," Applied Energy, Elsevier, vol. 212(C), pages 868-880.
    29. Qu, Y. & Wang, S. & Zhou, D. & Tian, Y., 2020. "Experimental study on thermal conductivity of paraffin-based shape-stabilized phase change material with hybrid carbon nano-additives," Renewable Energy, Elsevier, vol. 146(C), pages 2637-2645.
    30. Said, M.A. & Hassan, Hamdy, 2018. "Parametric study on the effect of using cold thermal storage energy of phase change material on the performance of air-conditioning unit," Applied Energy, Elsevier, vol. 230(C), pages 1380-1402.
    31. M. Mofijur & Teuku Meurah Indra Mahlia & Arridina Susan Silitonga & Hwai Chyuan Ong & Mahyar Silakhori & Muhammad Heikal Hasan & Nandy Putra & S.M. Ashrafur Rahman, 2019. "Phase Change Materials (PCM) for Solar Energy Usages and Storage: An Overview," Energies, MDPI, vol. 12(16), pages 1-20, August.
    32. Xiao, X. & Zhang, P. & Li, M., 2013. "Preparation and thermal characterization of paraffin/metal foam composite phase change material," Applied Energy, Elsevier, vol. 112(C), pages 1357-1366.
    33. Yan, T. & Wang, R.Z. & Li, T.X. & Wang, L.W. & Fred, Ishugah T., 2015. "A review of promising candidate reactions for chemical heat storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 13-31.
    34. Yang, Xiaohu & Wei, Pan & Cui, Xin & Jin, Liwen & He, Ya-Ling, 2019. "Thermal response of annuli filled with metal foam for thermal energy storage: An experimental study," Applied Energy, Elsevier, vol. 250(C), pages 1457-1467.
    35. Zhu, Yalin & Qin, Yaosong & Liang, Shuen & Chen, Keping & Tian, Chunrong & Wang, Jianhua & Luo, Xuan & Zhang, Lin, 2019. "Graphene/SiO2/n-octadecane nanoencapsulated phase change material with flower like morphology, high thermal conductivity, and suppressed supercooling," Applied Energy, Elsevier, vol. 250(C), pages 98-108.
    36. Yu, Shiyu & Wang, Xiaodong & Wu, Dezhen, 2014. "Microencapsulation of n-octadecane phase change material with calcium carbonate shell for enhancement of thermal conductivity and serving durability: Synthesis, microstructure, and performance evaluat," Applied Energy, Elsevier, vol. 114(C), pages 632-643.
    37. Abdelsalam, M.Y. & Teamah, H.M. & Lightstone, M.F. & Cotton, J.S., 2020. "Hybrid thermal energy storage with phase change materials for solar domestic hot water applications: Direct versus indirect heat exchange systems," Renewable Energy, Elsevier, vol. 147(P1), pages 77-88.
    38. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
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    1. Yousefi, Esmaeil & Nejad, Ali Abbas & Rezania, Alireza, 2022. "Higher power output in thermoelectric generator integrated with phase change material and metal foams under transient boundary condition," Energy, Elsevier, vol. 256(C).
    2. Sylwia Wciślik, 2020. "Efficient Stabilization of Mono and Hybrid Nanofluids," Energies, MDPI, vol. 13(15), pages 1-26, July.
    3. Ewelina Radomska & Łukasz Mika & Karol Sztekler & Wojciech Kalawa & Łukasz Lis & Kinga Pielichowska & Magdalena Szumera & Paweł Rutkowski, 2023. "Experimental and Theoretical Investigation of Single-Slope Passive Solar Still with Phase-Change Materials," Energies, MDPI, vol. 16(3), pages 1-29, January.
    4. Atul Bhattad & Vinay Atgur & Boggarapu Nageswar Rao & N. R. Banapurmath & T. M. Yunus Khan & Chandramouli Vadlamudi & Sanjay Krishnappa & A. M. Sajjan & R. Prasanna Shankara & N. H. Ayachit, 2023. "Review on Mono and Hybrid Nanofluids: Preparation, Properties, Investigation, and Applications in IC Engines and Heat Transfer," Energies, MDPI, vol. 16(7), pages 1-40, March.
    5. Ewelina Radomska & Lukasz Mika & Karol Sztekler & Lukasz Lis, 2020. "The Impact of Heat Exchangers’ Constructions on the Melting and Solidification Time of Phase Change Materials," Energies, MDPI, vol. 13(18), pages 1-44, September.

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