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Solidification of Graphene-Assisted Phase Change Nanocomposites inside a Sphere for Cold Storage Applications

Author

Listed:
  • Rajendran Prabakaran

    (Department of Mechanical Engineering, Anna University, College of Engineering Campus, Chennai 600 025, India)

  • Shaji Sidney

    (Department of Mechanical Engineering, Anna University, College of Engineering Campus, Chennai 600 025, India)

  • Dhasan Mohan Lal

    (Department of Mechanical Engineering, Anna University, College of Engineering Campus, Chennai 600 025, India)

  • C. Selvam

    (Department of Mechanical Engineering, SRM Institute of Science and Technology, Chennai 603 203, India)

  • Sivasankaran Harish

    (International Institute for Carbon-Neutral Energy Research, Kyushu University, Nishi-ku, Fukuoka 819-0395, Japan)

Abstract

In this work, we experimentally investigated the solidification behavior of functionalized graphene-based phase change nanocomposites inside a sphere. The influence of graphene nanoplatelets on thermal transport and rheological characteristics of the such nanocomposites were also discussed. We adopted the covalent functionalization method to prepare highly stable phase change nanocomposites using commercially available phase change material (PCM) OM08 as the host matrix and graphene nanoplatelets (GnPs) with 0.1, 0.3, and 0.5 volume percentage as the nano inclusions. We report a maximum thermal conductivity enhancement of ~102 and ~46% with 0.5 vol% in the solid and liquid states, respectively. Rheological measurements show that the pure PCM shows Newtonian behavior, whereas the inclusion of GnPs leads to the transition to non-Newtonian behavior, especially at lower shear rates. Viscosity of the nanocomposite increases with an increase in the volume fraction of GnP. For 0.5 vol% of GnPs, maximum increase in viscosity was found to be ~37% at a shear rate of 1000 s −1 . Time required for complete solidification decreases with the loading of GnPs. Maximum reduction in solidification time with 0.5 vol% of GnPs was ~40% for bath temperature of −10°C.

Suggested Citation

  • Rajendran Prabakaran & Shaji Sidney & Dhasan Mohan Lal & C. Selvam & Sivasankaran Harish, 2019. "Solidification of Graphene-Assisted Phase Change Nanocomposites inside a Sphere for Cold Storage Applications," Energies, MDPI, vol. 12(18), pages 1-16, September.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:18:p:3473-:d:265518
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    References listed on IDEAS

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    Cited by:

    1. Jesus Fernando Hinojosa & Saul Fernando Moreno & Victor Manuel Maytorena, 2023. "Low-Temperature Applications of Phase Change Materials for Energy Storage: A Descriptive Review," Energies, MDPI, vol. 16(7), pages 1-39, March.
    2. Sivashankar, M. & Selvam, C. & Manikandan, S. & Harish, Sivasankaran, 2020. "Performance improvement in concentrated photovoltaics using nano-enhanced phase change material with graphene nanoplatelets," Energy, Elsevier, vol. 208(C).
    3. Muhammad Saqib & Rafal Andrzejczyk, 2023. "A review of phase change materials and heat enhancement methodologies," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 12(3), May.
    4. Liu, Honglei & Li, Baotong & Zhang, Lukuan & Li, Xin, 2020. "Optimizing heat-absorption efficiency of phase change materials by mimicking leaf vein morphology," Applied Energy, Elsevier, vol. 269(C).
    5. Robert Sekret & Przemysław Starzec, 2021. "Developing a Cold Accumulator with a Capsule Bed Containing Water as a Phase-Change Material," Energies, MDPI, vol. 14(9), pages 1-18, May.
    6. Kassianne Tofani & Saeed Tiari, 2021. "Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review," Energies, MDPI, vol. 14(13), pages 1-34, June.
    7. Ewelina Radomska & Lukasz Mika & Karol Sztekler, 2020. "The Impact of Additives on the Main Properties of Phase Change Materials," Energies, MDPI, vol. 13(12), pages 1-34, June.
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    9. Marcin Kremieniewski, 2020. "Influence of Graphene Oxide on Rheological Parameters of Cement Slurries," Energies, MDPI, vol. 13(20), pages 1-15, October.

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