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Thermal property prediction and measurement of organic phase change materials in the liquid phase near the melting point

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  • O’Connor, William E.
  • Warzoha, Ronald
  • Weigand, Rebecca
  • Fleischer, Amy S.
  • Wemhoff, Aaron P.

Abstract

Organic phase change materials (PCMs) are a popular choice for many thermal energy storage applications including solar energy, building envelope thermal barriers, and passive cooling of portable electronics. Since the extent of phase change during a heating or cooling process is dependent upon rapid thermal penetration into the PCM, accurate knowledge of the thermal diffusivity of the PCM in both solid and liquid phases is crucial. This study addresses the existing gaps in information for liquid-phase PCM properties by examining an approach that determines the best path to prediction (BPP) for the thermal diffusivity of both alkanes and unsaturated acids. Knowledge of the BPP will enable researchers to explore the influence of PCM molecular structure on bulk thermophysical properties, thereby allowing the fabrication of optimized PCMs.

Suggested Citation

  • O’Connor, William E. & Warzoha, Ronald & Weigand, Rebecca & Fleischer, Amy S. & Wemhoff, Aaron P., 2014. "Thermal property prediction and measurement of organic phase change materials in the liquid phase near the melting point," Applied Energy, Elsevier, vol. 132(C), pages 496-506.
    • Handle: RePEc:eee:appene:v:132:y:2014:i:c:p:496-506
    DOI: 10.1016/j.apenergy.2014.07.045
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    2. Vélez, C. & Khayet, M. & Ortiz de Zárate, J.M., 2015. "Temperature-dependent thermal properties of solid/liquid phase change even-numbered n-alkanes: n-Hexadecane, n-octadecane and n-eicosane," Applied Energy, Elsevier, vol. 143(C), pages 383-394.
    3. Xu, Bin & Gan, Wen-tao & Wang, Yang-liang & Chen, Xing-ni & Fei, Yue & Pei, Gang, 2023. "Thermal performance of a novel Trombe wall integrated with direct absorption solar collector based on phase change slurry in winter," Renewable Energy, Elsevier, vol. 213(C), pages 246-258.
    4. He, Y. & Tao, Y.B. & Zhao, C.Y. & Yu, X.K., 2022. "Structure parameter analysis and optimization of photovoltaic-phase change material-thermoelectric coupling system under space conditions," Renewable Energy, Elsevier, vol. 200(C), pages 320-333.
    5. Kahwaji, Samer & Johnson, Michel B. & Kheirabadi, Ali C. & Groulx, Dominic & White, Mary Anne, 2016. "Stable, low-cost phase change material for building applications: The eutectic mixture of decanoic acid and tetradecanoic acid," Applied Energy, Elsevier, vol. 168(C), pages 457-464.
    6. Cao, Qiang & Sun, Zheng & Li, Zimu & Luan, Mingkai & Tang, Xiao & Li, Peng & Jiang, Zhenhua & Wei, Li, 2019. "Reduction of real gas losses with a DC flow in the regenerator of the refrigeration cycle," Applied Energy, Elsevier, vol. 235(C), pages 139-146.

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