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Graphene Oxide: An Effective Promoter for CO 2 Hydrate Formation

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  • Shuo Yan

    (Jiangsu key laboratory of oil-gas storage and transportation technology, Changzhou 213016, China
    Changzhou University, School of Petroleum Engineering, Changzhou 213016, China)

  • Wenjie Dai

    (Jiangsu key laboratory of oil-gas storage and transportation technology, Changzhou 213016, China
    Changzhou University, School of Petroleum Engineering, Changzhou 213016, China)

  • Shuli Wang

    (Jiangsu key laboratory of oil-gas storage and transportation technology, Changzhou 213016, China
    Changzhou University, School of Petroleum Engineering, Changzhou 213016, China)

  • Yongchao Rao

    (Jiangsu key laboratory of oil-gas storage and transportation technology, Changzhou 213016, China
    Changzhou University, School of Petroleum Engineering, Changzhou 213016, China)

  • Shidong Zhou

    (Jiangsu key laboratory of oil-gas storage and transportation technology, Changzhou 213016, China
    Changzhou University, School of Petroleum Engineering, Changzhou 213016, China)

Abstract

The main difficulties in applying technologies based on hydrate formation are the slow hydrate formation rate, low storage capacity, severe formation conditions and environmentally devastating promoters. Nano-sized graphene oxide has special microstructure features such as its functional groups and a large specific surface area, which can lead to high heat and mass transfer efficiency, large gas dissolution, fast nucleation and formation rate. In this work, CO 2 hydrate formation with and without graphene oxide nanoparticles was investigated. Herein, the promoting mechanism and effects of graphene oxide concentrations in different initial pressures ranging from 3 to 5 MPa at 279 K on CO 2 hydrate formation process were studied experimentally. The experimental results showed that graphene oxide can shorten the induction time by 53–74.3% and increase the gas consumption up to 5.1–15.9% under different system pressures. Based on the results, the optimum concentration was ascertained as 50 ppm under which condition, the induction time and the reaction time were the shortest while the pressure drop and the gas consumption reached the maximum.

Suggested Citation

  • Shuo Yan & Wenjie Dai & Shuli Wang & Yongchao Rao & Shidong Zhou, 2018. "Graphene Oxide: An Effective Promoter for CO 2 Hydrate Formation," Energies, MDPI, vol. 11(7), pages 1-13, July.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:7:p:1756-:d:156159
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    References listed on IDEAS

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    Cited by:

    1. Yu Liu & Xiangrui Liao & Changrui Shi & Zheng Ling & Lanlan Jiang, 2020. "Promoting and Inhibitory Effects of Hydrophilic/Hydrophobic Modified Aluminum Oxide Nanoparticles on Carbon Dioxide Hydrate Formation," Energies, MDPI, vol. 13(20), pages 1-14, October.
    2. Deng, Zhixia & Fan, Shuanshi & Wang, Yanhong & Lang, Xuemei & Li, Gang & Liu, Faping & Li, Mengyang, 2023. "High storage capacity and high formation rate of carbon dioxide hydrates via super-hydrophobic fluorinated graphenes," Energy, Elsevier, vol. 264(C).
    3. Cheng, Zucheng & Li, Shaohua & Liu, Yu & Zhang, Yi & Ling, Zheng & Yang, Mingjun & Jiang, Lanlan & Song, Yongchen, 2022. "Post-combustion CO2 capture and separation in flue gas based on hydrate technology：A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    4. Wang, Fang & Mu, Jinchi & Lin, Wenjing & Cao, Yuehan & Wang, Yuhan & Leng, Shuai & Guo, Lihong & Zhou, Ying, 2024. "Post-combustion CO2 capture via the hydrate formation at the gas-liquid-solid interface induced by the non-surfactant graphene oxide," Energy, Elsevier, vol. 290(C).
    5. Aminnaji, Morteza & Qureshi, M Fahed & Dashti, Hossein & Hase, Alfred & Mosalanejad, Abdolali & Jahanbakhsh, Amir & Babaei, Masoud & Amiri, Amirpiran & Maroto-Valer, Mercedes, 2024. "CO2 Gas hydrate for carbon capture and storage applications – Part 1," Energy, Elsevier, vol. 300(C).
    6. Kasala, Erasto E. & Wang, Jinjie & Hussain, Wakeel & Majid, Asia & Nyakilla, Edwin E., 2025. "Enhancing CO2 hydrate formation and long-term stability in subseafloor saline sediments through integrated thermal and pressure management for effective CO2 sequestration," Applied Energy, Elsevier, vol. 377(PD).

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