IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v120y2017icp362-373.html
   My bibliography  Save this article

Characteristics of CO2 hydrate formation/dissociation in H2O + THF aqueous solution and estimation of CO2 emission reduction by district cooling application

Author

Listed:
  • Kim, Shol
  • Lee, Seong Hyuk
  • Kang, Yong Tae

Abstract

CO2 conversion by gas hydrate is considered one of most practical technologies in the fields of Carbon Capture, Utilization and Storage (CCUS). In this study, the effects of hydrate formation pressure and concentration of tetrahydrofuran (THF) on the CO2 + THF hydrate formation and dissociation performance are investigated, and the reduction of CO2 emission by applying the CO2 + THF hydrate for district cooling system is also evaluated. The CO2 capture ratio tends to increase with increasing the hydrate formation pressure and THF concentration. It is found that the CO2 regeneration rate increases with decreasing the formation pressure and the increasing rate decreases with time. It is concluded that the optimum conditions for the CO2 + THF hydrate formation and dissociation are 1.5 MPa, THF 1.5 mol% to use hydrate slurry as the working fluid for district cooling application. Also, the dissociation enthalpy of CO2 + THF hydrate was measured by using the high pressure micro-differential scanning calorimeter. The cycle simulation of hydrate cooling system is conducted, and the COP is estimated as 11.55. Finally, it is estimated that 20,684 tons of CO2 emission could be reduced per year if the CO2 + THF hydrate technology is applied to the district cooling system of 51,600 RT.

Suggested Citation

  • Kim, Shol & Lee, Seong Hyuk & Kang, Yong Tae, 2017. "Characteristics of CO2 hydrate formation/dissociation in H2O + THF aqueous solution and estimation of CO2 emission reduction by district cooling application," Energy, Elsevier, vol. 120(C), pages 362-373.
    • Handle: RePEc:eee:energy:v:120:y:2017:i:c:p:362-373
    DOI: 10.1016/j.energy.2016.11.086
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544216317169
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2016.11.086?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Song, Yongchen & Cheng, Chuanxiao & Zhao, Jiafei & Zhu, Zihao & Liu, Weiguo & Yang, Mingjun & Xue, Kaihua, 2015. "Evaluation of gas production from methane hydrates using depressurization, thermal stimulation and combined methods," Applied Energy, Elsevier, vol. 145(C), pages 265-277.
    2. Wang, Xiaolin & Dennis, Mike & Hou, Liangzhuo, 2014. "Clathrate hydrate technology for cold storage in air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 34-51.
    3. Choi, Jae Woo & Chung, Jin Tack & Kang, Yong Tae, 2014. "CO2 hydrate formation at atmospheric pressure using high efficiency absorbent and surfactants," Energy, Elsevier, vol. 78(C), pages 869-876.
    4. Ma, Z.W. & Zhang, P. & Bao, H.S. & Deng, S., 2016. "Review of fundamental properties of CO2 hydrates and CO2 capture and separation using hydration method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1273-1302.
    5. Chong, Zheng Rong & Yang, She Hern Bryan & Babu, Ponnivalavan & Linga, Praveen & Li, Xiao-Sen, 2016. "Review of natural gas hydrates as an energy resource: Prospects and challenges," Applied Energy, Elsevier, vol. 162(C), pages 1633-1652.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Jie Wang & Airong Li & Faping Liu & Zedong Luo, 2021. "Experimental study on in situ dissociation kinetics of CO2 hydrate in pure water and water/sediments systems," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(2), pages 331-341, April.
    2. Emiliano Borri & Nan Hua & Adriano Sciacovelli & Dawei Wu & Yulong Ding & Yongliang Li & Vincenza Brancato & Yannan Zhang & Andrea Frazzica & Wenguang Li & Zhibin Yu & Yanio E. Milian & Svetlana Ushak, 2022. "Phase Change Slurries for Cooling and Storage: An Overview of Research Trends and Gaps," Energies, MDPI, vol. 15(19), pages 1-17, September.
    3. Qin, Jiyou & Chinen, Daigo & Obara, Shin'ya, 2022. "Storage and discharge efficiency of small-temperature-difference CO2 hydrate batteries with cyclopentane accelerators," Applied Energy, Elsevier, vol. 308(C).
    4. Zang, Xiaoya & Wang, Jing & He, Yong & Zhou, Xuebing & Liang, Deqing, 2022. "Formation kinetics and microscopic characteristics of synthesized ternary gas mixture hydrates in TBAB aqueous solutions," Energy, Elsevier, vol. 245(C).
    5. Choi, Sung & Park, Jungjoon & Kang, Yong Tae, 2019. "Experimental investigation on CO2 hydrate formation/dissociation for cold thermal energy harvest and transportation applications," Applied Energy, Elsevier, vol. 242(C), pages 1358-1368.
    6. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    7. Wang, Yiwei & Deng, Ye & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Zhang, Guangqing & Yue, Gang & Yang, Lanying, 2018. "Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation," Energy, Elsevier, vol. 150(C), pages 377-395.
    8. Zhang, Yue & Deng, Shuai & Zhao, Li & Nie, Xianhua & Xu, Weicong & He, Junnan, 2020. "Exploring a potential application of hydrate separation for composition adjustable combined cooling and power system," Applied Energy, Elsevier, vol. 268(C).
    9. Lai, Xi & Zhao, Li & Nie, Xianhua & Zhang, Yue & Zhang, Qi, 2023. "Hydrate-based composition separation of R32/R1234yf mixed working fluids applied in composition-adjustable organic Rankine cycle," Energy, Elsevier, vol. 284(C).
    10. Veluswamy, Hari Prakash & Kumar, Asheesh & Premasinghe, Kulesha & Linga, Praveen, 2017. "Effect of guest gas on the mixed tetrahydrofuran hydrate kinetics in a quiescent system," Applied Energy, Elsevier, vol. 207(C), pages 573-583.
    11. Li, Xiangxuan & Cui, Wei & Ma, Ting & Ma, Zhao & Liu, Jun & Wang, Qiuwang, 2023. "Lattice Boltzmann simulation of coupled depressurization and thermal decomposition of carbon dioxide hydrate for cold thermal energy storage," Energy, Elsevier, vol. 278(PB).
    12. Li, Shuangjun & Deng, Shuai & Zhao, Li & Zhao, Ruikai & Yuan, Xiangzhou, 2021. "Thermodynamic carbon pump 2.0: Elucidating energy efficiency through the thermodynamic cycle," Energy, Elsevier, vol. 215(PB).
    13. Foroutan, Shima & Mohsenzade, Hanie & Dashti, Ali & Roosta, Hadi, 2021. "New insights into the evaluation of kinetic hydrate inhibitors and energy consumption in rocking and stirred cells," Energy, Elsevier, vol. 218(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    2. Park, Joon Ho & Park, Jungjoon & Lee, Jae Won & Kang, Yong Tae, 2023. "Progress in CO2 hydrate formation and feasibility analysis for cold thermal energy harvesting application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 187(C).
    3. Bi, Yuehong & Chen, Jie & Miao, Zhen, 2016. "Thermodynamic optimization for dissociation process of gas hydrates," Energy, Elsevier, vol. 106(C), pages 270-276.
    4. Cheng, Zucheng & Li, Shaohua & Liu, Yu & Zhang, Yi & Ling, Zheng & Yang, Mingjun & Jiang, Lanlan & Song, Yongchen, 2022. "Post-combustion CO2 capture and separation in flue gas based on hydrate technology：A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    5. Choi, Sung & Park, Jungjoon & Kang, Yong Tae, 2019. "Experimental investigation on CO2 hydrate formation/dissociation for cold thermal energy harvest and transportation applications," Applied Energy, Elsevier, vol. 242(C), pages 1358-1368.
    6. Cai, Jing & Lv, Tao & Zhang, Yu & von Solms, Nicolas & Xu, Chun-Gang & Chen, Zhao-Yang & Li, Xiao-Sen, 2020. "Studies on temperature characteristics and initial formation interface during cyclopentane-methane hydrate formation in large-scale equipment with bubbling," Applied Energy, Elsevier, vol. 258(C).
    7. Veluswamy, Hari Prakash & Kumar, Asheesh & Seo, Yutaek & Lee, Ju Dong & Linga, Praveen, 2018. "A review of solidified natural gas (SNG) technology for gas storage via clathrate hydrates," Applied Energy, Elsevier, vol. 216(C), pages 262-285.
    8. Cheng, Chuanxiao & Wang, Fan & Tian, Yongjia & Wu, Xuehong & Zheng, Jili & Zhang, Jun & Li, Longwei & Yang, Penglin & Zhao, Jiafei, 2020. "Review and prospects of hydrate cold storage technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 117(C).
    9. Zhao, Jiafei & Song, Yongchen & Lim, Xin-Le & Lam, Wei-Haur, 2017. "Opportunities and challenges of gas hydrate policies with consideration of environmental impacts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 875-885.
    10. Zhang, Fengyuan & Wang, Xiaolin & Lou, Xia & Lipiński, Wojciech, 2021. "The effect of sodium dodecyl sulfate and dodecyltrimethylammonium chloride on the kinetics of CO2 hydrate formation in the presence of tetra-n-butyl ammonium bromide for carbon capture applications," Energy, Elsevier, vol. 227(C).
    11. Wang, Yi & Feng, Jing-Chun & Li, Xiao-Sen & Zhang, Yu, 2018. "Influence of well pattern on gas recovery from methane hydrate reservoir by large scale experimental investigation," Energy, Elsevier, vol. 152(C), pages 34-45.
    12. Lee, Joonseop & Lee, Dongyoung & Seo, Yongwon, 2021. "Experimental investigation of the exact role of large-molecule guest substances (LMGSs) in determining phase equilibria and structures of natural gas hydrates," Energy, Elsevier, vol. 215(PB).
    13. Yin, Zhenyuan & Huang, Li & Linga, Praveen, 2019. "Effect of wellbore design on the production behaviour of methane hydrate-bearing sediments induced by depressurization," Applied Energy, Elsevier, vol. 254(C).
    14. Liu, Zheng & Zheng, Junjie & Wang, Zhiyuan & Gao, Yonghai & Sun, Baojiang & Liao, Youqiang & Linga, Praveen, 2023. "Effect of clay on methane hydrate formation and dissociation in sediment: Implications for energy recovery from clayey-sandy hydrate reservoirs," Applied Energy, Elsevier, vol. 341(C).
    15. Zheng, Ruyi & Li, Shuxia & Li, Qingping & Li, Xiaoli, 2018. "Study on the relations between controlling mechanisms and dissociation front of gas hydrate reservoirs," Applied Energy, Elsevier, vol. 215(C), pages 405-415.
    16. Chong, Zheng Rong & Moh, Jia Wei Regine & Yin, Zhenyuan & Zhao, Jianzhong & Linga, Praveen, 2018. "Effect of vertical wellbore incorporation on energy recovery from aqueous rich hydrate sediments," Applied Energy, Elsevier, vol. 229(C), pages 637-647.
    17. Yang, Mingjun & Dong, Shuang & Zhao, Jie & Zheng, Jia-nan & Liu, Zheyuan & Song, Yongchen, 2021. "Ice behaviors and heat transfer characteristics during the isothermal production process of methane hydrate reservoirs by depressurization," Energy, Elsevier, vol. 232(C).
    18. Zhong, Xiuping & Pan, Dongbin & Zhu, Ying & Wang, Yafei & Zhai, Lianghao & Li, Xitong & Tu, Guigang & Chen, Chen, 2021. "Fracture network stimulation effect on hydrate development by depressurization combined with thermal stimulation using injection-production well patterns," Energy, Elsevier, vol. 228(C).
    19. Mok, Junghoon & Choi, Wonjung & Seo, Yongwon, 2021. "The dual-functional roles of N2 gas for the exploitation of natural gas hydrates: An inhibitor for dissociation and an external guest for replacement," Energy, Elsevier, vol. 232(C).
    20. Yu, Tao & Guan, Guoqing & Abudula, Abuliti & Wang, Dayong & Song, Yongchen, 2021. "Numerical evaluation of free gas accumulation behavior in a reservoir during methane hydrate production using a multiple-well system," Energy, Elsevier, vol. 218(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:120:y:2017:i:c:p:362-373. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.