IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v11y2018i2p399-d130950.html
   My bibliography  Save this article

Anti-Agglomerator of Tetra-n-Butyl Ammonium Bromide Hydrate and Its Effect on Hydrate-Based CO 2 Capture

Author

Listed:
  • Rong Li

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    Key Laboratory of Gas Hydrate, CAS and Guangzhou Center for Gas Hydrate Research, CAS, Guangzhou 510640, China
    Nano Sciences and Technology Institute, University of Science and Technology of China, Suzhou 215123, China)

  • Xiao-Sen Li

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    Key Laboratory of Gas Hydrate, CAS and Guangzhou Center for Gas Hydrate Research, CAS, Guangzhou 510640, China
    Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China)

  • Zhao-Yang Chen

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    Key Laboratory of Gas Hydrate, CAS and Guangzhou Center for Gas Hydrate Research, CAS, Guangzhou 510640, China
    Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China)

  • Yu Zhang

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    Key Laboratory of Gas Hydrate, CAS and Guangzhou Center for Gas Hydrate Research, CAS, Guangzhou 510640, China
    Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China)

  • Chun-Gang Xu

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    Key Laboratory of Gas Hydrate, CAS and Guangzhou Center for Gas Hydrate Research, CAS, Guangzhou 510640, China
    Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China)

  • Zhi-Ming Xia

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    Key Laboratory of Gas Hydrate, CAS and Guangzhou Center for Gas Hydrate Research, CAS, Guangzhou 510640, China
    Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China)

Abstract

Tetra-n-butyl ammonium bromide (TBAB) was widely used in the research fields of cold storage and CO 2 hydrate separation due to its high phase change latent heat and thermodynamic promotion for hydrate formation. Agglomeration always occurred in the process of TBAB hydrate generation, which led to the blockage in the pipeline and the separation apparatus. In this work, we screened out a kind of anti-agglomerant that can effectively solve the problem of TBAB hydrate agglomeration. The anti-agglomerant (AA) is composed of 90% cocamidopropyl dimethylamine and 10% glycerol, which can keep TBAB hydrate of 19.3–29.0 wt. % in a stable state of slurry over 72 h. The microscopic observation of the morphology of the TBAB hydrate particles showed that the addition of AA can greatly reduce the size of the TBAB hydrate particles. CO 2 gas separation experiments found that the addition of AA led to great improvement on gas storage capacity, CO 2 split fraction and separation factor, due to the increasing of contact area between gas phase and hydrate particles. The CO 2 split fraction and separation factor with AA addition reached up to 70.3% and 42.8%, respectively.

Suggested Citation

  • Rong Li & Xiao-Sen Li & Zhao-Yang Chen & Yu Zhang & Chun-Gang Xu & Zhi-Ming Xia, 2018. "Anti-Agglomerator of Tetra-n-Butyl Ammonium Bromide Hydrate and Its Effect on Hydrate-Based CO 2 Capture," Energies, MDPI, vol. 11(2), pages 1-12, February.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:2:p:399-:d:130950
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/11/2/399/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/11/2/399/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Hendriks, C.A. & Blok, K. & Turkenburg, W.C., 1991. "Technology and cost of recovering and storing carbon dioxide from an integrated-gasifier, combined-cycle plant," Energy, Elsevier, vol. 16(11), pages 1277-1293.
    2. Xu, Chun-Gang & Zhang, Shao-Hong & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2013. "CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide) solution and Raman spectroscopic analysis," Energy, Elsevier, vol. 59(C), pages 719-725.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhao, Xin & Fang, Qingchao & Qiu, Zhengsong & Mi, Shiyou & Wang, Zhiyuan & Geng, Qi & Zhang, Yubin, 2022. "Experimental investigation on hydrate anti-agglomerant for oil-free systems in the production pipe of marine natural gas hydrates," Energy, Elsevier, vol. 242(C).
    2. Shuo Yan & Wenjie Dai & Shuli Wang & Yongchao Rao & Shidong Zhou, 2018. "Graphene Oxide: An Effective Promoter for CO 2 Hydrate Formation," Energies, MDPI, vol. 11(7), pages 1-13, July.
    3. Kim, Hyunho & Zheng, Junjie & Yin, Zhenyuan & Babu, Ponnivalavan & Kumar, Sreekala & Tee, Jackson & Linga, Praveen, 2023. "Semi-clathrate hydrate slurry as a cold energy storage and transport medium: Rheological study, energy analysis and enhancement by amino acid," Energy, Elsevier, vol. 264(C).
    4. Liu, Fa-Ping & Li, Ai-Rong & Qing, Sheng-Lan & Luo, Ze-Dong & Ma, Yu-Ling, 2022. "Formation kinetics, mechanism of CO2 hydrate and its applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zheng, Junjie & Bhatnagar, Krittika & Khurana, Maninder & Zhang, Peng & Zhang, Bao-Yong & Linga, Praveen, 2018. "Semiclathrate based CO2 capture from fuel gas mixture at ambient temperature: Effect of concentrations of tetra-n-butylammonium fluoride (TBAF) and kinetic additives," Applied Energy, Elsevier, vol. 217(C), pages 377-389.
    2. Haraden, John, 1992. "The status of hot dry rock as an energy source," Energy, Elsevier, vol. 17(8), pages 777-786.
    3. Cai, Jing & Xu, Chun-Gang & Lin, Fu-Hua & Yu, Hai-Zhu & Li, Xiao-Sen, 2016. "A novel method for evaluating effects of promoters on hydrate formation," Energy, Elsevier, vol. 102(C), pages 567-575.
    4. Cai, Jing & Xu, Chun-Gang & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen, 2017. "Hydrate-based methane separation from coal mine methane gas mixture by bubbling using the scale-up equipment," Applied Energy, Elsevier, vol. 204(C), pages 1526-1534.
    5. Vlachou, Andriana & Vassos, Spyros & Andrikopoulos, Andreas, 1996. "Energy and environment: Reducing CO2 emissions from the electric power industry," Journal of Policy Modeling, Elsevier, vol. 18(4), pages 343-376, August.
    6. Ding, Ya-Long & Xu, Chun-Gang & Yu, Yi-Song & Li, Xiao-Sen, 2017. "Methane recovery from natural gas hydrate with simulated IGCC syngas," Energy, Elsevier, vol. 120(C), pages 192-198.
    7. Nakićenović, Nebojša & John, Aviott, 1991. "CO2 reduction and removal: Measures for the next century," Energy, Elsevier, vol. 16(11), pages 1347-1377.
    8. Foroutan, Shima & Mohsenzade, Hanie & Dashti, Ali & Roosta, Hadi, 2021. "New insights into the evaluation of kinetic hydrate inhibitors and energy consumption in rocking and stirred cells," Energy, Elsevier, vol. 218(C).
    9. Li, Ze-Yu & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen & Xu, Chun-Gang & Yan, Ran, 2019. "The plateau effects and crystal transition study in Tetrahydrofuran (THF)/CO2/H2 hydrate formation processes," Applied Energy, Elsevier, vol. 238(C), pages 195-201.
    10. Zhong, Dong-Liang & Wang, Jia-Le & Lu, Yi-Yu & Li, Zheng & Yan, Jin, 2016. "Precombustion CO2 capture using a hybrid process of adsorption and gas hydrate formation," Energy, Elsevier, vol. 102(C), pages 621-629.
    11. Wang, Yan & Zhong, Dong-Liang & Li, Zheng & Li, Jian-Bo, 2020. "Application of tetra-n-butyl ammonium bromide semi-clathrate hydrate for CO2 capture from unconventional natural gases," Energy, Elsevier, vol. 197(C).
    12. Kheshgi, Haroon S. & Prince, Roger C., 2005. "Sequestration of fermentation CO2 from ethanol production," Energy, Elsevier, vol. 30(10), pages 1865-1871.
    13. Zhao, Qi & Chen, Zhao-Yang & Li, Xiao-Sen & Xia, Zhi-Ming, 2023. "Experimental study of CO2 hydrate formation under an electrostatic field," Energy, Elsevier, vol. 272(C).
    14. Liu, Jun & Ding, Jia-Xiang & Liang, De-Qing, 2018. "Experimental study on hydrate-based gas separation of mixed CH4/CO2 using unstable ice in a silica gel bed," Energy, Elsevier, vol. 157(C), pages 54-64.
    15. Babu, Ponnivalavan & Ho, Chie Yin & Kumar, Rajnish & Linga, Praveen, 2014. "Enhanced kinetics for the clathrate process in a fixed bed reactor in the presence of liquid promoters for pre-combustion carbon dioxide capture," Energy, Elsevier, vol. 70(C), pages 664-673.
    16. Wang, Fei & Fu, Shanfei & Guo, Gang & Jia, Zhen-Zhen & Luo, Sheng-Jun & Guo, Rong-Bo, 2016. "Experimental study on hydrate-based CO2 removal from CH4/CO2 mixture," Energy, Elsevier, vol. 104(C), pages 76-84.
    17. Xie, Yan & Zhu, Yu-Jie & Cheng, Li-Wei & Zheng, Tao & Zhong, Jin-Rong & Xiao, Peng & Sun, Chang-Yu & Chen, Guang-Jin & Feng, Jing-Chun, 2023. "The coexistence of multiple hydrates triggered by varied H2 molecule occupancy during CO2/H2 hydrate dissociation," Energy, Elsevier, vol. 262(PA).
    18. Liu, Yinan & Deng, Shuai & Zhao, Ruikai & He, Junnan & Zhao, Li, 2017. "Energy-saving pathway exploration of CCS integrated with solar energy: A review of innovative concepts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 652-669.
    19. Zheng, Junjie & Zhang, Peng & Linga, Praveen, 2017. "Semiclathrate hydrate process for pre-combustion capture of CO2 at near ambient temperatures," Applied Energy, Elsevier, vol. 194(C), pages 267-278.
    20. Xia, Zhi-Ming & Li, Xiao-Sen & Chen, Zhao-Yang & Li, Gang & Yan, Ke-Feng & Xu, Chun-Gang & Lv, Qiu-Nan & Cai, Jing, 2016. "Hydrate-based CO2 capture and CH4 purification from simulated biogas with synergic additives based on gas solvent," Applied Energy, Elsevier, vol. 162(C), pages 1153-1159.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:11:y:2018:i:2:p:399-:d:130950. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.