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Review on CO2 hydrate formation/dissociation and its cold energy application

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  • Sun, Qibei
  • Kang, Yong Tae

Abstract

Carbon dioxide hydrate has been paid growing attention due to its application potentials like being used as a secondary refrigerant and sequestration in the deep ocean. Therefore, there has been a lot of research on various gas hydrates, including methane hydrate, ethane hydrate, methane–CO2 mixture hydrate and so on. However, there is no review especially on the CO2 hydrate and its cooling application. In this paper, the review provides the comprehensive understanding of the CO2 hydrate with focus on the formation and dissociation models, including the kinetic and thermodynamic ones, as well as its applications. It is proposed that more experimental and modeling work should be carried out on CO2 hydrate dissociation, and the kinetic models should be developed by considering the effect of additives. It is also proposed that the cooling application of CO2 hydrate will become popular in the very near future and therefore, the experimental data at low pressure are needed. Finding the effective additives which can reduce the equilibrium conditions and increase the kinetic formation/dissociation rate is recommended.

Suggested Citation

  • Sun, Qibei & Kang, Yong Tae, 2016. "Review on CO2 hydrate formation/dissociation and its cold energy application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 478-494.
    • Handle: RePEc:eee:rensus:v:62:y:2016:i:c:p:478-494
    DOI: 10.1016/j.rser.2016.04.062
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    References listed on IDEAS

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    Cited by:

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    3. Luiz F. Rodrigues & Alessandro Ramos & Gabriel de Araujo & Edson Silveira & Marcelo Ketzer & Rogerio Lourega, 2019. "High-Pressure and Automatized System for Study of Natural Gas Hydrates," Energies, MDPI, vol. 12(16), pages 1-14, August.
    4. Choi, Sung & Park, Jungjoon & Kang, Yong Tae, 2019. "Experimental investigation on CO2 hydrate formation/dissociation for cold thermal energy harvest and transportation applications," Applied Energy, Elsevier, vol. 242(C), pages 1358-1368.
    5. Liu, Fa-Ping & Li, Ai-Rong & Qing, Sheng-Lan & Luo, Ze-Dong & Ma, Yu-Ling, 2022. "Formation kinetics, mechanism of CO2 hydrate and its applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    6. Nguyen, Ngoc N. & La, Vinh T. & Huynh, Chinh D. & Nguyen, Anh V., 2022. "Technical and economic perspectives of hydrate-based carbon dioxide capture," Applied Energy, Elsevier, vol. 307(C).
    7. Zhao, Jiafei & Song, Yongchen & Lim, Xin-Le & Lam, Wei-Haur, 2017. "Opportunities and challenges of gas hydrate policies with consideration of environmental impacts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 875-885.

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