IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v140y2015icp107-112.html
   My bibliography  Save this article

Guest gas enclathration in tetra-n-butyl ammonium chloride (TBAC) semiclathrates: Potential application to natural gas storage and CO2 capture

Author

Listed:
  • Kim, Soyoung
  • Baek, Il-Hyun
  • You, Jong-Kyun
  • Seo, Yongwon

Abstract

The enclathration of guest gases such as CH4 and CO2 in tetra-n-butyl ammonium chloride (TBAC) semiclathrates and their potential application to natural gas storage and CO2 capture were examined with a primary focus on stability condition measurements and cage filling characteristics. The phase behaviors clearly demonstrated that the double CH4 (or CO2)+TBAC semiclathrates yielded a significantly enhanced thermodynamic stability. In particular, the highest stabilization occurred at 3.3mol%, the stoichiometric concentration of TBAC·29.7H2O. The cage-dependent 13C NMR chemical shift identified CH4 molecules enclathrated in the small 512 cages of the double TBAC semiclathrates. CO2 inclusion in the double TBAC semiclathrate was also confirmed using Raman spectroscopy. In addition, the dissociation enthalpy and the dissociation temperature of the TBAC semiclathrate under atmospheric pressure were measured to be 204.8±1.7J/g and 288.0K, respectively, by a differential scanning calorimeter. The experimental results demonstrate that TBAC semiclathrates can potentially be used for gas storage and CO2 capture due to their high thermodynamic stability and favorable enclathration characteristics of guest gases.

Suggested Citation

  • Kim, Soyoung & Baek, Il-Hyun & You, Jong-Kyun & Seo, Yongwon, 2015. "Guest gas enclathration in tetra-n-butyl ammonium chloride (TBAC) semiclathrates: Potential application to natural gas storage and CO2 capture," Applied Energy, Elsevier, vol. 140(C), pages 107-112.
    • Handle: RePEc:eee:appene:v:140:y:2015:i:c:p:107-112
    DOI: 10.1016/j.apenergy.2014.11.076
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261914012458
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2014.11.076?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2010. "Tetra-n-butyl ammonium bromide semi-clathrate hydrate process for post-combustion capture of carbon dioxide in the presence of dodecyl trimethyl ammonium chloride," Energy, Elsevier, vol. 35(9), pages 3902-3908.
    2. Kondo, Wataru & Ohtsuka, Kaoru & Ohmura, Ryo & Takeya, Satoshi & Mori, Yasuhiko H., 2014. "Clathrate-hydrate formation from a hydrocarbon gas mixture: Compositional evolution of formed hydrate during an isobaric semi-batch hydrate-forming operation," Applied Energy, Elsevier, vol. 113(C), pages 864-871.
    3. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2011. "Hydrate-based pre-combustion carbon dioxide capture process in the system with tetra-n-butyl ammonium bromide solution in the presence of cyclopentane," Energy, Elsevier, vol. 36(3), pages 1394-1403.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Xiaolin & Dennis, Mike, 2016. "Characterisation of thermal properties and charging performance of semi-clathrate hydrates for cold storage applications," Applied Energy, Elsevier, vol. 167(C), pages 59-69.
    2. Li, Zheng & Zhong, Dong-Liang & Lu, Yi-Yu & Yan, Jin & Zou, Zhen-Lin, 2017. "Preferential enclathration of CO2 into tetra-n-butyl phosphonium bromide semiclathrate hydrate in moderate operating conditions: Application for CO2 capture from shale gas," Applied Energy, Elsevier, vol. 199(C), pages 370-381.
    3. Koyama, Ryo & Chen, Li-Jen & Alavi, Saman & Ohmura, Ryo, 2020. "Improving thermal efficiency of hydrate-based heat engine generating renewable energy from low-grade heat sources using a crystal engineering approach," Energy, Elsevier, vol. 198(C).
    4. Zhong, Dong-Liang & Wang, Wen-Chun & Zou, Zhen-Lin & Lu, Yi-Yu & Yan, Jin & Ding, Kun, 2018. "Investigation on methane recovery from low-concentration coal mine gas by tetra-n-butyl ammonium chloride semiclathrate hydrate formation," Applied Energy, Elsevier, vol. 227(C), pages 686-693.
    5. Yang, Mingjun & Jing, Wen & Zhao, Jiafei & Ling, Zheng & Song, Yongchen, 2016. "Promotion of hydrate-based CO2 capture from flue gas by additive mixtures (THF (tetrahydrofuran) + TBAB (tetra-n-butyl ammonium bromide))," Energy, Elsevier, vol. 106(C), pages 546-553.
    6. Kim, Soyoung & Choi, Sung-Deuk & Seo, Yongwon, 2017. "CO2 capture from flue gas using clathrate formation in the presence of thermodynamic promoters," Energy, Elsevier, vol. 118(C), pages 950-956.
    7. Lee, Yohan & Lee, Dongyoung & Lee, Jong-Won & Seo, Yongwon, 2016. "Enclathration of CO2 as a co-guest of structure H hydrates and its implications for CO2 capture and sequestration," Applied Energy, Elsevier, vol. 163(C), pages 51-59.
    8. Theo, Wai Lip & Lim, Jeng Shiun & Hashim, Haslenda & Mustaffa, Azizul Azri & Ho, Wai Shin, 2016. "Review of pre-combustion capture and ionic liquid in carbon capture and storage," Applied Energy, Elsevier, vol. 183(C), pages 1633-1663.
    9. Zheng, Junjie & Bhatnagar, Krittika & Khurana, Maninder & Zhang, Peng & Zhang, Bao-Yong & Linga, Praveen, 2018. "Semiclathrate based CO2 capture from fuel gas mixture at ambient temperature: Effect of concentrations of tetra-n-butylammonium fluoride (TBAF) and kinetic additives," Applied Energy, Elsevier, vol. 217(C), pages 377-389.
    10. Kim, Soyoung & Seo, Yongwon, 2015. "Semiclathrate-based CO2 capture from flue gas mixtures: An experimental approach with thermodynamic and Raman spectroscopic analyses," Applied Energy, Elsevier, vol. 154(C), pages 987-994.
    11. Zheng, Junjie & Zhang, Peng & Linga, Praveen, 2017. "Semiclathrate hydrate process for pre-combustion capture of CO2 at near ambient temperatures," Applied Energy, Elsevier, vol. 194(C), pages 267-278.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yi, Jie & Zhong, Dong-Liang & Yan, Jin & Lu, Yi-Yu, 2019. "Impacts of the surfactant sulfonated lignin on hydrate based CO2 capture from a CO2/CH4 gas mixture," Energy, Elsevier, vol. 171(C), pages 61-68.
    2. Yang, Mingjun & Song, Yongchen & Jiang, Lanlan & Liu, Weiguo & Dou, Binlin & Jing, Wen, 2014. "Effects of operating mode and pressure on hydrate-based desalination and CO2 capture in porous media," Applied Energy, Elsevier, vol. 135(C), pages 504-511.
    3. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    4. Yuan, Qing & Sun, Chang-Yu & Yang, Xin & Ma, Ping-Chuan & Ma, Zheng-Wei & Liu, Bei & Ma, Qing-Lan & Yang, Lan-Ying & Chen, Guang-Jin, 2012. "Recovery of methane from hydrate reservoir with gaseous carbon dioxide using a three-dimensional middle-size reactor," Energy, Elsevier, vol. 40(1), pages 47-58.
    5. Veluswamy, Hari Prakash & Kumar, Asheesh & Premasinghe, Kulesha & Linga, Praveen, 2017. "Effect of guest gas on the mixed tetrahydrofuran hydrate kinetics in a quiescent system," Applied Energy, Elsevier, vol. 207(C), pages 573-583.
    6. Yan, Jin & Lu, Yi-Yu & Zhong, Dong-Liang & Zou, Zhen-Lin & Li, Jian-Bo, 2019. "Enhanced methane recovery from low-concentration coalbed methane by gas hydrate formation in graphite nanofluids," Energy, Elsevier, vol. 180(C), pages 728-736.
    7. Ding, Ya-Long & Xu, Chun-Gang & Yu, Yi-Song & Li, Xiao-Sen, 2017. "Methane recovery from natural gas hydrate with simulated IGCC syngas," Energy, Elsevier, vol. 120(C), pages 192-198.
    8. Babu, Ponnivalavan & Ong, Hong Wen Nelson & Linga, Praveen, 2016. "A systematic kinetic study to evaluate the effect of tetrahydrofuran on the clathrate process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 94(C), pages 431-442.
    9. Chun-Gang Xu & Min Wang & Gang Xu & Xiao-Sen Li & Wei Zhang & Jing Cai & Zhao-Yang Chen, 2021. "The Relationship between Thermal Characteristics and Microstructure/Composition of Carbon Dioxide Hydrate in the Presence of Cyclopentane," Energies, MDPI, vol. 14(4), pages 1-17, February.
    10. Babu, Ponnivalavan & Ho, Chie Yin & Kumar, Rajnish & Linga, Praveen, 2014. "Enhanced kinetics for the clathrate process in a fixed bed reactor in the presence of liquid promoters for pre-combustion carbon dioxide capture," Energy, Elsevier, vol. 70(C), pages 664-673.
    11. Wang, Xiaolin & Dennis, Mike, 2016. "Characterisation of thermal properties and charging performance of semi-clathrate hydrates for cold storage applications," Applied Energy, Elsevier, vol. 167(C), pages 59-69.
    12. Sun, Qibei & Kang, Yong Tae, 2016. "Review on CO2 hydrate formation/dissociation and its cold energy application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 478-494.
    13. Xu, Chun-Gang & Zhang, Shao-Hong & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2013. "CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide) solution and Raman spectroscopic analysis," Energy, Elsevier, vol. 59(C), pages 719-725.
    14. Yu, Yi-Song & Xu, Chun-Gang & Li, Xiao-Sen, 2018. "Crystal morphology-based kinetic study of carbon dioxide-hydrogen-tetra-n-butyl ammonium bromide hydrates formation in a static system," Energy, Elsevier, vol. 143(C), pages 546-553.
    15. Lee, Yohan & Lee, Dongyoung & Lee, Jong-Won & Seo, Yongwon, 2016. "Enclathration of CO2 as a co-guest of structure H hydrates and its implications for CO2 capture and sequestration," Applied Energy, Elsevier, vol. 163(C), pages 51-59.
    16. Yang, Mingjun & Jing, Wen & Zhao, Jiafei & Ling, Zheng & Song, Yongchen, 2016. "Promotion of hydrate-based CO2 capture from flue gas by additive mixtures (THF (tetrahydrofuran) + TBAB (tetra-n-butyl ammonium bromide))," Energy, Elsevier, vol. 106(C), pages 546-553.
    17. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    18. Xu, Chun-Gang & Li, Xiao-Sen & Lv, Qiu-Nan & Chen, Zhao-Yang & Cai, Jing, 2012. "Hydrate-based CO2 (carbon dioxide) capture from IGCC (integrated gasification combined cycle) synthesis gas using bubble method with a set of visual equipment," Energy, Elsevier, vol. 44(1), pages 358-366.
    19. Veluswamy, Hari Prakash & Kumar, Asheesh & Seo, Yutaek & Lee, Ju Dong & Linga, Praveen, 2018. "A review of solidified natural gas (SNG) technology for gas storage via clathrate hydrates," Applied Energy, Elsevier, vol. 216(C), pages 262-285.
    20. Wang, Lanyun & Zhang, Yajuan & Xie, Huilong & Lu, Xiaoran & Wen, Xinglin & Liu, Zhen & Zhou, Huajian & Liu, Zejian & Xu, Yongliang, 2022. "Effect of voltage and initial temperature on thermodynamics and kinetics of CO2 hydrate formation in an electrostatic spraying reactor," Energy, Elsevier, vol. 239(PD).

    More about this item

    Keywords

    Semiclathrate; TBAC; Gas storage; CO2 capture; Guest gas;
    All these keywords.

    JEL classification:

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:140:y:2015:i:c:p:107-112. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.