IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v227y2018icp686-693.html
   My bibliography  Save this article

Investigation on methane recovery from low-concentration coal mine gas by tetra-n-butyl ammonium chloride semiclathrate hydrate formation

Author

Listed:
  • Zhong, Dong-Liang
  • Wang, Wen-Chun
  • Zou, Zhen-Lin
  • Lu, Yi-Yu
  • Yan, Jin
  • Ding, Kun

Abstract

This work presents an investigation of using tetra-n-butyl ammonium chloride (TBAC) semiclathrate hydrate to separate CH4 from a low-concentration coal mine gas containing 30mol% CH4, 60mol% N2, and 10mol% O2. Phase equilibrium data of TBAC semiclathrate hydrate formed in the presence of low-concentration coal mine gas with TBAC concentration ranging from 0.49mol% to 3.3mol% were measured and reported. A high pressure micro-differential scanning calorimeter (HP µ-DSC) was employed to characterize the phase behaviors of TBAC semiclathrate hydrate formed in the presence of coal mine gas with TBAC concentration fixed at 3.3mol% (the stoichiometric concentration of TBAC semiclathrate). It was found that pure TBAC semiclathrate hydrate coexists with the TBAC-coal mine gas mixed hydrate in the pressure range of (1.4–6.2MPa). In addition, kinetic experiments were performed to elucidate the effects of TBAC concentration, subcooling, and sodium dodecyl sulfate (SDS) concentration on CH4 separation efficiency and an optimum experimental condition for semiclathrate-based CH4 recovery was screened. The highest CH4 recovery and separation factor were obtained at the conditions of 0.49mol% TBAC, △T=8K, and 900ppm SDS. It was found that CH4 recovery obtained at 0.49mol% TBAC is comparable with that obtained at 0.29mol% TBAB, whereas CH4 concentration of the gas mixture released from the TBAC hydrate (49.6mol%) is increased substantially comparing to that obtained at 0.29mol% TBAB (42.5mol%).

Suggested Citation

  • Zhong, Dong-Liang & Wang, Wen-Chun & Zou, Zhen-Lin & Lu, Yi-Yu & Yan, Jin & Ding, Kun, 2018. "Investigation on methane recovery from low-concentration coal mine gas by tetra-n-butyl ammonium chloride semiclathrate hydrate formation," Applied Energy, Elsevier, vol. 227(C), pages 686-693.
    • Handle: RePEc:eee:appene:v:227:y:2018:i:c:p:686-693
    DOI: 10.1016/j.apenergy.2017.08.069
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261917310875
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2017.08.069?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kim, Soyoung & Baek, Il-Hyun & You, Jong-Kyun & Seo, Yongwon, 2015. "Guest gas enclathration in tetra-n-butyl ammonium chloride (TBAC) semiclathrates: Potential application to natural gas storage and CO2 capture," Applied Energy, Elsevier, vol. 140(C), pages 107-112.
    2. Zhong, Dong-Liang & Li, Zheng & Lu, Yi-Yu & Wang, Jia-Le & Yan, Jin, 2015. "Evaluation of CO2 removal from a CO2+CH4 gas mixture using gas hydrate formation in liquid water and THF solutions," Applied Energy, Elsevier, vol. 158(C), pages 133-141.
    3. Yang, Mingjun & Jing, Wen & Zhao, Jiafei & Ling, Zheng & Song, Yongchen, 2016. "Promotion of hydrate-based CO2 capture from flue gas by additive mixtures (THF (tetrahydrofuran) + TBAB (tetra-n-butyl ammonium bromide))," Energy, Elsevier, vol. 106(C), pages 546-553.
    4. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    5. Babu, Ponnivalavan & Kumar, Rajnish & Linga, Praveen, 2013. "Pre-combustion capture of carbon dioxide in a fixed bed reactor using the clathrate hydrate process," Energy, Elsevier, vol. 50(C), pages 364-373.
    6. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2010. "Tetra-n-butyl ammonium bromide semi-clathrate hydrate process for post-combustion capture of carbon dioxide in the presence of dodecyl trimethyl ammonium chloride," Energy, Elsevier, vol. 35(9), pages 3902-3908.
    7. Li, Zheng & Zhong, Dong-Liang & Lu, Yi-Yu & Yan, Jin & Zou, Zhen-Lin, 2017. "Preferential enclathration of CO2 into tetra-n-butyl phosphonium bromide semiclathrate hydrate in moderate operating conditions: Application for CO2 capture from shale gas," Applied Energy, Elsevier, vol. 199(C), pages 370-381.
    8. Babu, Ponnivalavan & Ho, Chie Yin & Kumar, Rajnish & Linga, Praveen, 2014. "Enhanced kinetics for the clathrate process in a fixed bed reactor in the presence of liquid promoters for pre-combustion carbon dioxide capture," Energy, Elsevier, vol. 70(C), pages 664-673.
    9. Zhong, Dong-Liang & Ding, Kun & Lu, Yi-Yu & Yan, Jin & Zhao, Wei-Long, 2016. "Methane recovery from coal mine gas using hydrate formation in water-in-oil emulsions," Applied Energy, Elsevier, vol. 162(C), pages 1619-1626.
    10. Xu, Chun-Gang & Zhang, Shao-Hong & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2013. "CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide) solution and Raman spectroscopic analysis," Energy, Elsevier, vol. 59(C), pages 719-725.
    11. Huang, Yuping & Zheng, Qipeng P. & Fan, Neng & Aminian, Kashy, 2014. "Optimal scheduling for enhanced coal bed methane production through CO2 injection," Applied Energy, Elsevier, vol. 113(C), pages 1475-1483.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Li, Ze-Yu & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen & Xu, Chun-Gang & Yan, Ran, 2019. "The plateau effects and crystal transition study in Tetrahydrofuran (THF)/CO2/H2 hydrate formation processes," Applied Energy, Elsevier, vol. 238(C), pages 195-201.
    2. Zhang, Qiang & Zheng, Junjie & Zhang, Baoyong & Linga, Praveen, 2021. "Coal mine gas separation of methane via clathrate hydrate process aided by tetrahydrofuran and amino acids," Applied Energy, Elsevier, vol. 287(C).
    3. Xie, Yan & Zhu, Yu-Jie & Cheng, Li-Wei & Zheng, Tao & Zhong, Jin-Rong & Xiao, Peng & Sun, Chang-Yu & Chen, Guang-Jin & Feng, Jing-Chun, 2023. "The coexistence of multiple hydrates triggered by varied H2 molecule occupancy during CO2/H2 hydrate dissociation," Energy, Elsevier, vol. 262(PA).
    4. Wang, Bin & Liu, Shuyang & Wang, Pengfei, 2022. "Microwave-assisted high-efficient gas production of depressurization-induced methane hydrate exploitation," Energy, Elsevier, vol. 247(C).
    5. Wang, Bin & Dong, Hongsheng & Fan, Zhen & Liu, Shuyang & Lv, Xin & Li, Qingping & Zhao, Jiafei, 2020. "Numerical analysis of microwave stimulation for enhancing energy recovery from depressurized methane hydrate sediments," Applied Energy, Elsevier, vol. 262(C).
    6. Choi, Wonjung & Lee, Yohan & Mok, Junghoon & Seo, Yongwon, 2020. "Influence of feed gas composition on structural transformation and guest exchange behaviors in sH hydrate – Flue gas replacement for energy recovery and CO2 sequestration," Energy, Elsevier, vol. 207(C).
    7. Zang, Xiaoya & Wan, Lihua & He, Yong & Liang, Deqing, 2020. "CO2 removal from synthesized ternary gas mixtures used hydrate formation with sodium dodecyl sulfate(SDS) as additive," Energy, Elsevier, vol. 190(C).
    8. Xu, Chun-Gang & Xie, Wen-Jun & Chen, Guo-Shu & Yan, Xiao-Xue & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2020. "Study on the influencing factors of gas consumption in hydrate-based CO2 separation in the presence of CP by Raman analysis," Energy, Elsevier, vol. 198(C).
    9. Mu, Liang & Zhou, Ziqi & Zhao, Huixing & Zhu, Xiaohai & Cui, Qingyan, 2024. "High-efficiency recovery of methane from coal bed gas via hydrate formation in emulsions," Energy, Elsevier, vol. 290(C).
    10. Yan, Jin & Lu, Yi-Yu & Zhong, Dong-Liang & Zou, Zhen-Lin & Li, Jian-Bo, 2019. "Enhanced methane recovery from low-concentration coalbed methane by gas hydrate formation in graphite nanofluids," Energy, Elsevier, vol. 180(C), pages 728-736.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Liu, Jun & Ding, Jia-Xiang & Liang, De-Qing, 2018. "Experimental study on hydrate-based gas separation of mixed CH4/CO2 using unstable ice in a silica gel bed," Energy, Elsevier, vol. 157(C), pages 54-64.
    2. Wang, Yiwei & Deng, Ye & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Zhang, Guangqing & Yue, Gang & Yang, Lanying, 2018. "Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation," Energy, Elsevier, vol. 150(C), pages 377-395.
    3. Yang, Mingjun & Jing, Wen & Zhao, Jiafei & Ling, Zheng & Song, Yongchen, 2016. "Promotion of hydrate-based CO2 capture from flue gas by additive mixtures (THF (tetrahydrofuran) + TBAB (tetra-n-butyl ammonium bromide))," Energy, Elsevier, vol. 106(C), pages 546-553.
    4. Wang, Yiwei & Du, Mei & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Chen, Bo & Chen, Guangjin & Sun, Changyu & Yang, Lanying, 2017. "Experiments and simulations for continuous recovery of methane from coal seam gas (CSG) utilizing hydrate formation," Energy, Elsevier, vol. 129(C), pages 28-41.
    5. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    6. Cai, Jing & Xu, Chun-Gang & Lin, Fu-Hua & Yu, Hai-Zhu & Li, Xiao-Sen, 2016. "A novel method for evaluating effects of promoters on hydrate formation," Energy, Elsevier, vol. 102(C), pages 567-575.
    7. Kim, Soyoung & Choi, Sung-Deuk & Seo, Yongwon, 2017. "CO2 capture from flue gas using clathrate formation in the presence of thermodynamic promoters," Energy, Elsevier, vol. 118(C), pages 950-956.
    8. Yan, Jin & Lu, Yi-Yu & Zhong, Dong-Liang & Zou, Zhen-Lin & Li, Jian-Bo, 2019. "Enhanced methane recovery from low-concentration coalbed methane by gas hydrate formation in graphite nanofluids," Energy, Elsevier, vol. 180(C), pages 728-736.
    9. Babu, Ponnivalavan & Ong, Hong Wen Nelson & Linga, Praveen, 2016. "A systematic kinetic study to evaluate the effect of tetrahydrofuran on the clathrate process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 94(C), pages 431-442.
    10. Zheng, Junjie & Bhatnagar, Krittika & Khurana, Maninder & Zhang, Peng & Zhang, Bao-Yong & Linga, Praveen, 2018. "Semiclathrate based CO2 capture from fuel gas mixture at ambient temperature: Effect of concentrations of tetra-n-butylammonium fluoride (TBAF) and kinetic additives," Applied Energy, Elsevier, vol. 217(C), pages 377-389.
    11. Zheng, Junjie & Zhang, Peng & Linga, Praveen, 2017. "Semiclathrate hydrate process for pre-combustion capture of CO2 at near ambient temperatures," Applied Energy, Elsevier, vol. 194(C), pages 267-278.
    12. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    13. Li, Zheng & Zhong, Dong-Liang & Lu, Yi-Yu & Yan, Jin & Zou, Zhen-Lin, 2017. "Preferential enclathration of CO2 into tetra-n-butyl phosphonium bromide semiclathrate hydrate in moderate operating conditions: Application for CO2 capture from shale gas," Applied Energy, Elsevier, vol. 199(C), pages 370-381.
    14. Wang, Pengfei & Chen, Yiqi & Teng, Ying & An, Senyou & Li, Yun & Han, Meng & Yuan, Bao & Shen, Suling & Chen, Bin & Han, Songbai & Zhu, Jinlong & Zhu, Jianbo & Zhao, Yusheng & Xie, Heping, 2024. "A comprehensive review of hydrogen purification using a hydrate-based method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 194(C).
    15. Theo, Wai Lip & Lim, Jeng Shiun & Hashim, Haslenda & Mustaffa, Azizul Azri & Ho, Wai Shin, 2016. "Review of pre-combustion capture and ionic liquid in carbon capture and storage," Applied Energy, Elsevier, vol. 183(C), pages 1633-1663.
    16. Xu, Chun-Gang & Xie, Wen-Jun & Chen, Guo-Shu & Yan, Xiao-Xue & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2020. "Study on the influencing factors of gas consumption in hydrate-based CO2 separation in the presence of CP by Raman analysis," Energy, Elsevier, vol. 198(C).
    17. Veluswamy, Hari Prakash & Kumar, Asheesh & Premasinghe, Kulesha & Linga, Praveen, 2017. "Effect of guest gas on the mixed tetrahydrofuran hydrate kinetics in a quiescent system," Applied Energy, Elsevier, vol. 207(C), pages 573-583.
    18. Adeel ur Rehman & Bhajan Lal, 2022. "RETRACTED: Gas Hydrate-Based CO 2 Capture: A Journey from Batch to Continuous," Energies, MDPI, vol. 15(21), pages 1-27, November.
    19. Yi, Jie & Zhong, Dong-Liang & Yan, Jin & Lu, Yi-Yu, 2019. "Impacts of the surfactant sulfonated lignin on hydrate based CO2 capture from a CO2/CH4 gas mixture," Energy, Elsevier, vol. 171(C), pages 61-68.
    20. Zhong, Dong-Liang & Wang, Jia-Le & Lu, Yi-Yu & Li, Zheng & Yan, Jin, 2016. "Precombustion CO2 capture using a hybrid process of adsorption and gas hydrate formation," Energy, Elsevier, vol. 102(C), pages 621-629.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:227:y:2018:i:c:p:686-693. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.