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Investigation on methane recovery from low-concentration coal mine gas by tetra-n-butyl ammonium chloride semiclathrate hydrate formation

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  • Zhong, Dong-Liang
  • Wang, Wen-Chun
  • Zou, Zhen-Lin
  • Lu, Yi-Yu
  • Yan, Jin
  • Ding, Kun

Abstract

This work presents an investigation of using tetra-n-butyl ammonium chloride (TBAC) semiclathrate hydrate to separate CH4 from a low-concentration coal mine gas containing 30mol% CH4, 60mol% N2, and 10mol% O2. Phase equilibrium data of TBAC semiclathrate hydrate formed in the presence of low-concentration coal mine gas with TBAC concentration ranging from 0.49mol% to 3.3mol% were measured and reported. A high pressure micro-differential scanning calorimeter (HP µ-DSC) was employed to characterize the phase behaviors of TBAC semiclathrate hydrate formed in the presence of coal mine gas with TBAC concentration fixed at 3.3mol% (the stoichiometric concentration of TBAC semiclathrate). It was found that pure TBAC semiclathrate hydrate coexists with the TBAC-coal mine gas mixed hydrate in the pressure range of (1.4–6.2MPa). In addition, kinetic experiments were performed to elucidate the effects of TBAC concentration, subcooling, and sodium dodecyl sulfate (SDS) concentration on CH4 separation efficiency and an optimum experimental condition for semiclathrate-based CH4 recovery was screened. The highest CH4 recovery and separation factor were obtained at the conditions of 0.49mol% TBAC, △T=8K, and 900ppm SDS. It was found that CH4 recovery obtained at 0.49mol% TBAC is comparable with that obtained at 0.29mol% TBAB, whereas CH4 concentration of the gas mixture released from the TBAC hydrate (49.6mol%) is increased substantially comparing to that obtained at 0.29mol% TBAB (42.5mol%).

Suggested Citation

  • Zhong, Dong-Liang & Wang, Wen-Chun & Zou, Zhen-Lin & Lu, Yi-Yu & Yan, Jin & Ding, Kun, 2018. "Investigation on methane recovery from low-concentration coal mine gas by tetra-n-butyl ammonium chloride semiclathrate hydrate formation," Applied Energy, Elsevier, vol. 227(C), pages 686-693.
    • Handle: RePEc:eee:appene:v:227:y:2018:i:c:p:686-693
    DOI: 10.1016/j.apenergy.2017.08.069
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    References listed on IDEAS

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    1. Kim, Soyoung & Baek, Il-Hyun & You, Jong-Kyun & Seo, Yongwon, 2015. "Guest gas enclathration in tetra-n-butyl ammonium chloride (TBAC) semiclathrates: Potential application to natural gas storage and CO2 capture," Applied Energy, Elsevier, vol. 140(C), pages 107-112.
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    7. Babu, Ponnivalavan & Kumar, Rajnish & Linga, Praveen, 2013. "Pre-combustion capture of carbon dioxide in a fixed bed reactor using the clathrate hydrate process," Energy, Elsevier, vol. 50(C), pages 364-373.
    8. Li, Zheng & Zhong, Dong-Liang & Lu, Yi-Yu & Yan, Jin & Zou, Zhen-Lin, 2017. "Preferential enclathration of CO2 into tetra-n-butyl phosphonium bromide semiclathrate hydrate in moderate operating conditions: Application for CO2 capture from shale gas," Applied Energy, Elsevier, vol. 199(C), pages 370-381.
    9. Babu, Ponnivalavan & Ho, Chie Yin & Kumar, Rajnish & Linga, Praveen, 2014. "Enhanced kinetics for the clathrate process in a fixed bed reactor in the presence of liquid promoters for pre-combustion carbon dioxide capture," Energy, Elsevier, vol. 70(C), pages 664-673.
    10. Zhong, Dong-Liang & Ding, Kun & Lu, Yi-Yu & Yan, Jin & Zhao, Wei-Long, 2016. "Methane recovery from coal mine gas using hydrate formation in water-in-oil emulsions," Applied Energy, Elsevier, vol. 162(C), pages 1619-1626.
    11. Xu, Chun-Gang & Zhang, Shao-Hong & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2013. "CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide) solution and Raman spectroscopic analysis," Energy, Elsevier, vol. 59(C), pages 719-725.
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    5. Mu, Liang & Zhou, Ziqi & Zhao, Huixing & Zhu, Xiaohai & Cui, Qingyan, 2024. "High-efficiency recovery of methane from coal bed gas via hydrate formation in emulsions," Energy, Elsevier, vol. 290(C).
    6. Xie, Yan & Zhu, Yu-Jie & Cheng, Li-Wei & Zheng, Tao & Zhong, Jin-Rong & Xiao, Peng & Sun, Chang-Yu & Chen, Guang-Jin & Feng, Jing-Chun, 2023. "The coexistence of multiple hydrates triggered by varied H2 molecule occupancy during CO2/H2 hydrate dissociation," Energy, Elsevier, vol. 262(PA).
    7. Wang, Bin & Liu, Shuyang & Wang, Pengfei, 2022. "Microwave-assisted high-efficient gas production of depressurization-induced methane hydrate exploitation," Energy, Elsevier, vol. 247(C).
    8. Wang, Bin & Dong, Hongsheng & Fan, Zhen & Liu, Shuyang & Lv, Xin & Li, Qingping & Zhao, Jiafei, 2020. "Numerical analysis of microwave stimulation for enhancing energy recovery from depressurized methane hydrate sediments," Applied Energy, Elsevier, vol. 262(C).
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    10. Yan, Jin & Lu, Yi-Yu & Zhong, Dong-Liang & Zou, Zhen-Lin & Li, Jian-Bo, 2019. "Enhanced methane recovery from low-concentration coalbed methane by gas hydrate formation in graphite nanofluids," Energy, Elsevier, vol. 180(C), pages 728-736.

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