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A systematic kinetic study to evaluate the effect of tetrahydrofuran on the clathrate process for pre-combustion capture of carbon dioxide

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  • Babu, Ponnivalavan
  • Ong, Hong Wen Nelson
  • Linga, Praveen

Abstract

THF (Tetrahydrofuran) is the most commonly employed promoter for the gas hydrate formation pertaining to applications like carbon dioxide capture and energy storage (for natural gas and hydrogen). In this work, THF was investigated as a promoter for pre-combustion capture of carbon dioxide (CO2) from fuel gas mixture (CO2/H2) in a systematic manner. 0.5, 1.0, 3.0 and 5.56 mol% THF solution were employed with different driving force conditions to study the effect of pressure, temperature and composition of gases in hydrate. The kinetic performance of the CO2/H2/THF gas hydrate system was evaluated by reviewing the IT (induction time), normalized gas uptake, normalized rate of hydrate formation and the hydrate phase composition. The optimum operating conditions and optimum THF concentration in this study was found to be 6.0 MPa, 282.2 K, and 5.56 mol% THF respectively. 5.56 mol% THF solution yielded an average gas uptake of 13.9 mmol of gas/mol of water for hydrate growth and an average normalized rate of hydrate formation of 1679.8 mmol s−1 m−3.

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  • Babu, Ponnivalavan & Ong, Hong Wen Nelson & Linga, Praveen, 2016. "A systematic kinetic study to evaluate the effect of tetrahydrofuran on the clathrate process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 94(C), pages 431-442.
    • Handle: RePEc:eee:energy:v:94:y:2016:i:c:p:431-442
    DOI: 10.1016/j.energy.2015.11.009
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    5. Xia, Zhi-ming & Li, Xiao-sen & Chen, Zhao-yang & Li, Gang & Cai, Jing & Wang, Yi & Yan, Ke-feng & Xu, Chun-gang, 2017. "Hydrate-based acidic gases capture for clean methane with new synergic additives," Applied Energy, Elsevier, vol. 207(C), pages 584-593.
    6. Kim, Soyoung & Choi, Sung-Deuk & Seo, Yongwon, 2017. "CO2 capture from flue gas using clathrate formation in the presence of thermodynamic promoters," Energy, Elsevier, vol. 118(C), pages 950-956.
    7. Najmus S. Sifat & Yousef Haseli, 2019. "A Critical Review of CO 2 Capture Technologies and Prospects for Clean Power Generation," Energies, MDPI, vol. 12(21), pages 1-33, October.
    8. Theo, Wai Lip & Lim, Jeng Shiun & Hashim, Haslenda & Mustaffa, Azizul Azri & Ho, Wai Shin, 2016. "Review of pre-combustion capture and ionic liquid in carbon capture and storage," Applied Energy, Elsevier, vol. 183(C), pages 1633-1663.
    9. Zheng, Junjie & Bhatnagar, Krittika & Khurana, Maninder & Zhang, Peng & Zhang, Bao-Yong & Linga, Praveen, 2018. "Semiclathrate based CO2 capture from fuel gas mixture at ambient temperature: Effect of concentrations of tetra-n-butylammonium fluoride (TBAF) and kinetic additives," Applied Energy, Elsevier, vol. 217(C), pages 377-389.
    10. Foroutan, Shima & Mohsenzade, Hanie & Dashti, Ali & Roosta, Hadi, 2021. "New insights into the evaluation of kinetic hydrate inhibitors and energy consumption in rocking and stirred cells," Energy, Elsevier, vol. 218(C).
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