IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v63y2013icp252-259.html
   My bibliography  Save this article

HBGS (hydrate based gas separation) process for carbon dioxide capture employing an unstirred reactor with cyclopentane

Author

Listed:
  • Ho, Leong Chuan
  • Babu, Ponnivalavan
  • Kumar, Rajnish
  • Linga, Praveen

Abstract

The effect of CP (cyclopentane) as a promoter/additive, in the HBGS (hydrate based gas separation) process for pre-combustion gas mixture was investigated by employing an unstirred reactor configuration. Gas uptake measurements were performed at two different temperatures (275.7 K and 285.7 K) and at an experimental pressure of 6.0 MPa to determine the kinetics of hydrate formation. Experiments were conducted with three different volumes (7.5, 15 and 22 ml) of CP and based on induction time and the rate of hydrate growth, 15 ml of CP was determined to be the optimal volume for carbon dioxide capture at 6.0 MPa and 275.7 K. In addition, the effect of a kinetic promoter, SDS (sodium dodecyl sulfate), was investigated. Surprisingly, no improvement in kinetic performance was observed at 6.0 MPa and 275.7 K in the presence of SDS and CP. From the study, it was found that at the optimal 15 ml CP (CP layer thickness of 1.8 mm), the average composition of carbon dioxide in the hydrate phase was 90.36 mol% with a separation factor of 17.82. Furthermore, the unstirred reactor also yielded better kinetic performance over the stirred tank reactor with the unstirred reactor having a 2.28 times higher average gas uptake.

Suggested Citation

  • Ho, Leong Chuan & Babu, Ponnivalavan & Kumar, Rajnish & Linga, Praveen, 2013. "HBGS (hydrate based gas separation) process for carbon dioxide capture employing an unstirred reactor with cyclopentane," Energy, Elsevier, vol. 63(C), pages 252-259.
    • Handle: RePEc:eee:energy:v:63:y:2013:i:c:p:252-259
    DOI: 10.1016/j.energy.2013.10.031
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544213008827
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2013.10.031?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Lee, Hyun Ju & Lee, Ju Dong & Linga, Praveen & Englezos, Peter & Kim, Young Seok & Lee, Man Sig & Kim, Yang Do, 2010. "Gas hydrate formation process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 35(6), pages 2729-2733.
    2. Mondal, Monoj Kumar & Balsora, Hemant Kumar & Varshney, Prachi, 2012. "Progress and trends in CO2 capture/separation technologies: A review," Energy, Elsevier, vol. 46(1), pages 431-441.
    3. Huen Lee & Jong-won Lee & Do Youn Kim & Jeasung Park & Yu-Taek Seo & Huang Zeng & Igor L. Moudrakovski & Christopher I. Ratcliffe & John A. Ripmeester, 2005. "Tuning clathrate hydrates for hydrogen storage," Nature, Nature, vol. 434(7034), pages 743-746, April.
    4. Xu, Chun-Gang & Li, Xiao-Sen & Lv, Qiu-Nan & Chen, Zhao-Yang & Cai, Jing, 2012. "Hydrate-based CO2 (carbon dioxide) capture from IGCC (integrated gasification combined cycle) synthesis gas using bubble method with a set of visual equipment," Energy, Elsevier, vol. 44(1), pages 358-366.
    5. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2011. "Hydrate-based pre-combustion carbon dioxide capture process in the system with tetra-n-butyl ammonium bromide solution in the presence of cyclopentane," Energy, Elsevier, vol. 36(3), pages 1394-1403.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    2. Theo, Wai Lip & Lim, Jeng Shiun & Hashim, Haslenda & Mustaffa, Azizul Azri & Ho, Wai Shin, 2016. "Review of pre-combustion capture and ionic liquid in carbon capture and storage," Applied Energy, Elsevier, vol. 183(C), pages 1633-1663.
    3. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    4. Babu, Ponnivalavan & Ong, Hong Wen Nelson & Linga, Praveen, 2016. "A systematic kinetic study to evaluate the effect of tetrahydrofuran on the clathrate process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 94(C), pages 431-442.
    5. Cai, Jing & Zhang, Yu & Xu, Chun-Gang & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen, 2018. "Raman spectroscopic studies on carbon dioxide separation from fuel gas via clathrate hydrate in the presence of tetrahydrofuran," Applied Energy, Elsevier, vol. 214(C), pages 92-102.
    6. Xu, Chun-Gang & Zhang, Shao-Hong & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2013. "CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide) solution and Raman spectroscopic analysis," Energy, Elsevier, vol. 59(C), pages 719-725.
    7. Ma, Z.W. & Zhang, P. & Bao, H.S. & Deng, S., 2016. "Review of fundamental properties of CO2 hydrates and CO2 capture and separation using hydration method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1273-1302.
    8. Xu, Chun-Gang & Xie, Wen-Jun & Chen, Guo-Shu & Yan, Xiao-Xue & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2020. "Study on the influencing factors of gas consumption in hydrate-based CO2 separation in the presence of CP by Raman analysis," Energy, Elsevier, vol. 198(C).
    9. Chen, Siyuan & Wang, Yanhong & Lang, Xuemei & Fan, Shuanshi & Li, Gang, 2023. "Rapid and high hydrogen storage in epoxycyclopentane hydrate at moderate pressure," Energy, Elsevier, vol. 268(C).
    10. Yuan, Qing & Sun, Chang-Yu & Yang, Xin & Ma, Ping-Chuan & Ma, Zheng-Wei & Liu, Bei & Ma, Qing-Lan & Yang, Lan-Ying & Chen, Guang-Jin, 2012. "Recovery of methane from hydrate reservoir with gaseous carbon dioxide using a three-dimensional middle-size reactor," Energy, Elsevier, vol. 40(1), pages 47-58.
    11. Chen, Zhaoyang & Fang, Jie & Xu, Chungang & Xia, Zhiming & Yan, Kefeng & Li, Xiaosen, 2020. "Carbon dioxide hydrate separation from Integrated Gasification Combined Cycle (IGCC) syngas by a novel hydrate heat-mass coupling method," Energy, Elsevier, vol. 199(C).
    12. Zhao, Jiafei & Yu, Tao & Song, Yongchen & Liu, Di & Liu, Weiguo & Liu, Yu & Yang, Mingjun & Ruan, Xuke & Li, Yanghui, 2013. "Numerical simulation of gas production from hydrate deposits using a single vertical well by depressurization in the Qilian Mountain permafrost, Qinghai-Tibet Plateau, China," Energy, Elsevier, vol. 52(C), pages 308-319.
    13. Nguyen, Ngoc N. & La, Vinh T. & Huynh, Chinh D. & Nguyen, Anh V., 2022. "Technical and economic perspectives of hydrate-based carbon dioxide capture," Applied Energy, Elsevier, vol. 307(C).
    14. Ding, Ya-Long & Xu, Chun-Gang & Yu, Yi-Song & Li, Xiao-Sen, 2017. "Methane recovery from natural gas hydrate with simulated IGCC syngas," Energy, Elsevier, vol. 120(C), pages 192-198.
    15. Shi, Lingli & Ding, Jiaxiang & Liang, Deqing, 2019. "Enhanced CH4 storage in hydrates with the presence of sucrose stearate," Energy, Elsevier, vol. 180(C), pages 978-988.
    16. Veluswamy, Hari Prakash & Kumar, Rajnish & Linga, Praveen, 2014. "Hydrogen storage in clathrate hydrates: Current state of the art and future directions," Applied Energy, Elsevier, vol. 122(C), pages 112-132.
    17. Li, Ze-Yu & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen & Xu, Chun-Gang & Yan, Ran, 2019. "The plateau effects and crystal transition study in Tetrahydrofuran (THF)/CO2/H2 hydrate formation processes," Applied Energy, Elsevier, vol. 238(C), pages 195-201.
    18. Zheng, Junjie & Bhatnagar, Krittika & Khurana, Maninder & Zhang, Peng & Zhang, Bao-Yong & Linga, Praveen, 2018. "Semiclathrate based CO2 capture from fuel gas mixture at ambient temperature: Effect of concentrations of tetra-n-butylammonium fluoride (TBAF) and kinetic additives," Applied Energy, Elsevier, vol. 217(C), pages 377-389.
    19. Babu, Ponnivalavan & Ho, Chie Yin & Kumar, Rajnish & Linga, Praveen, 2014. "Enhanced kinetics for the clathrate process in a fixed bed reactor in the presence of liquid promoters for pre-combustion carbon dioxide capture," Energy, Elsevier, vol. 70(C), pages 664-673.
    20. Zheng, Junjie & Zhang, Peng & Linga, Praveen, 2017. "Semiclathrate hydrate process for pre-combustion capture of CO2 at near ambient temperatures," Applied Energy, Elsevier, vol. 194(C), pages 267-278.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:63:y:2013:i:c:p:252-259. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.