IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v11y2018i12p3514-d191185.html
   My bibliography  Save this article

Effect of Accelerated High Temperature on Oxidation and Polymerization of Biodiesel from Vegetable Oils

Author

Listed:
  • Jae-Kon Kim

    (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority, Cheongju 28115, Korea
    Co-first authors.)

  • Cheol-Hwan Jeon

    (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority, Cheongju 28115, Korea
    Co-first authors.)

  • Hyung Won Lee

    (School of Environmental Engineering, University of Seoul, Seoul 02504, Korea)

  • Young-Kwon Park

    (School of Environmental Engineering, University of Seoul, Seoul 02504, Korea)

  • Kyong-il Min

    (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority, Cheongju 28115, Korea)

  • In-ha Hwang

    (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority, Cheongju 28115, Korea)

  • Young-Min Kim

    (Department of Environmental Sciences and Biotechnology, Hallym University, Chuncheon 24252, Korea)

Abstract

Oxidation of biodiesel (BD) obtained from the decomposition of biomass can damage the fuel injection and engine parts during its use as a fuel. The excess heating of vegetable oils can also cause polymerization of the biodiesel. The extent of BD oxidation depends on its fatty acid composition. In this study, an accelerated oxidation test of BDs at 95 °C was investigated according to ASTM D 2274 by applying a long-term storage test for 16 weeks. The density, viscosity, and total acid number (TAN) of BDs increased because of the accelerated oxidation. Furthermore, the contents of unsaturated fatty acid methyl esters (FAMEs), C18:2 ME, and C18:3 ME in BDs decreased due to the accelerated oxidation. The 1 H-nuclear magnetic resonance spectrum of BDs that were obtained from the accelerated high temperature oxidation at 180 °C for 72 h differed from that of fresh BDs. The mass spectrum obtained from the analysis of the model FAME, linoleic acid (C18:2) methyl ester, which was oxidized at high temperature, indicated the formation of dimers and epoxy dimers of linoleic acid (C18:2) methyl ester by a Diels-Alder reaction.

Suggested Citation

  • Jae-Kon Kim & Cheol-Hwan Jeon & Hyung Won Lee & Young-Kwon Park & Kyong-il Min & In-ha Hwang & Young-Min Kim, 2018. "Effect of Accelerated High Temperature on Oxidation and Polymerization of Biodiesel from Vegetable Oils," Energies, MDPI, vol. 11(12), pages 1-11, December.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:12:p:3514-:d:191185
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/11/12/3514/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/11/12/3514/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Ali, Obed M. & Mamat, Rizalman & Abdullah, Nik R. & Abdullah, Abdul Adam, 2016. "Analysis of blended fuel properties and engine performance with palm biodiesel–diesel blended fuel," Renewable Energy, Elsevier, vol. 86(C), pages 59-67.
    2. Jain, Siddharth & Sharma, M.P., 2010. "Stability of biodiesel and its blends: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 667-678, February.
    3. Antonio Molino & Vincenzo Larocca & Simeone Chianese & Dino Musmarra, 2018. "Biofuels Production by Biomass Gasification: A Review," Energies, MDPI, vol. 11(4), pages 1-31, March.
    4. Nwafor, O.M.I, 2003. "The effect of elevated fuel inlet temperature on performance of diesel engine running on neat vegetable oil at constant speed conditions," Renewable Energy, Elsevier, vol. 28(2), pages 171-181.
    5. Yaakob, Zahira & Mohammad, Masita & Alherbawi, Mohammad & Alam, Zahangir & Sopian, Kamaruzaman, 2013. "Overview of the production of biodiesel from Waste cooking oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 184-193.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Andra Lovasz & Nicu Cornel Sabau & Ioana Borza & Radu Brejea, 2023. "Production and Quality of Biodiesel under the Influence of a Rapeseed Fertilization System," Energies, MDPI, vol. 16(9), pages 1-27, April.
    2. Jakub Čedík & Martin Pexa & Michal Holúbek & Jaroslav Mrázek & Hardikk Valera & Avinash Kumar Agarwal, 2021. "Operational Parameters of a Diesel Engine Running on Diesel–Rapeseed Oil–Methanol–Iso-Butanol Blends," Energies, MDPI, vol. 14(19), pages 1-24, September.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mahmudul, H.M. & Hagos, F.Y. & Mamat, R. & Adam, A. Abdul & Ishak, W.F.W. & Alenezi, R., 2017. "Production, characterization and performance of biodiesel as an alternative fuel in diesel engines – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 497-509.
    2. Rizwanul Fattah, I.M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Masum, B.M. & Imtenan, S. & Ashraful, A.M., 2014. "Effect of antioxidants on oxidation stability of biodiesel derived from vegetable and animal based feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 356-370.
    3. Md Mofijur Rahman & Mohammad Rasul & Nur Md Sayeed Hassan, 2017. "Study on the Tribological Characteristics of Australian Native First Generation and Second Generation Biodiesel Fuel," Energies, MDPI, vol. 10(1), pages 1-16, January.
    4. Yaakob, Zahira & Narayanan, Binitha N. & Padikkaparambil, Silija & Unni K., Surya & Akbar P., Mohammed, 2014. "A review on the oxidation stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 136-153.
    5. Sierra-Cantor, Jonathan Fabián & Guerrero-Fajardo, Carlos Alberto, 2017. "Methods for improving the cold flow properties of biodiesel with high saturated fatty acids content: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 774-790.
    6. Chakraborty, Rajat & Gupta, Abhishek.K. & Chowdhury, Ratul, 2014. "Conversion of slaughterhouse and poultry farm animal fats and wastes to biodiesel: Parametric sensitivity and fuel quality assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 120-134.
    7. Octávio Alves & Luís Calado & Roberta M. Panizio & Catarina Nobre & Eliseu Monteiro & Paulo Brito & Margarida Gonçalves, 2022. "Gasification of Solid Recovered Fuels with Variable Fractions of Polymeric Materials," Energies, MDPI, vol. 15(21), pages 1-19, November.
    8. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    9. Gheorghe Lazaroiu & Lucian Mihaescu & Gabriel Negreanu & Constantin Pana & Ionel Pisa & Alexandru Cernat & Dana-Alexandra Ciupageanu, 2018. "Experimental Investigations of Innovative Biomass Energy Harnessing Solutions," Energies, MDPI, vol. 11(12), pages 1-18, December.
    10. Singh, Paramvir & Varun, & Chauhan, S.R., 2016. "Carbonyl and aromatic hydrocarbon emissions from diesel engine exhaust using different feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 269-291.
    11. Andrea Di Giuliano & Stefania Lucantonio & Katia Gallucci, 2021. "Devolatilization of Residual Biomasses for Chemical Looping Gasification in Fluidized Beds Made Up of Oxygen-Carriers," Energies, MDPI, vol. 14(2), pages 1-16, January.
    12. Altarazi, Yazan S.M. & Abu Talib, Abd Rahim & Gires, Ezanee & Yu, Jianglong & Lucas, John & Yusaf, Talal, 2021. "Performance and exhaust emissions rate of small-scale turbojet engine running on dual biodiesel blends using Gasturb," Energy, Elsevier, vol. 232(C).
    13. Zhang, Hanfei & Wang, Ligang & Pérez-Fortes, Mar & Van herle, Jan & Maréchal, François & Desideri, Umberto, 2020. "Techno-economic optimization of biomass-to-methanol with solid-oxide electrolyzer," Applied Energy, Elsevier, vol. 258(C).
    14. Kim, Jun Young & Kim, Dongjae & Li, Zezhong John & Dariva, Claudio & Cao, Yankai & Ellis, Naoko, 2023. "Predicting and optimizing syngas production from fluidized bed biomass gasifiers: A machine learning approach," Energy, Elsevier, vol. 263(PC).
    15. Senthil Kumar, M. & Kerihuel, A. & Bellettre, J. & Tazerout, M., 2005. "Experimental investigations on the use of preheated animal fat as fuel in a compression ignition engine," Renewable Energy, Elsevier, vol. 30(9), pages 1443-1456.
    16. Manju Dhakad Tanwar & Felipe Andrade Torres & Ali Mubarak Alqahtani & Pankaj Kumar Tanwar & Yashas Bhand & Omid Doustdar, 2023. "Promising Bioalcohols for Low-Emission Vehicles," Energies, MDPI, vol. 16(2), pages 1-22, January.
    17. Dwivedi, Gaurav & Jain, Siddharth & Sharma, M.P., 2011. "Impact analysis of biodiesel on engine performance—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4633-4641.
    18. Dwivedi, Gaurav & Sharma, M.P., 2014. "Impact of cold flow properties of biodiesel on engine performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 650-656.
    19. Siddharth Jain, 2023. "An Assessment of the Operation and Emission Characteristics of a Diesel Engine Powered by a New Biofuel Prepared Using In Situ Transesterification of a Dry Spirogyra Algae–Jatropha Powder Mixture," Energies, MDPI, vol. 16(3), pages 1-16, February.
    20. Fabián Vargas & Armando Pérez & Rene Delgado & Emilio Hernández & José Alejandro Suástegui, 2019. "Performance Analysis of a Compression Ignition Engine Using Mixture Biodiesel Palm and Diesel," Sustainability, MDPI, vol. 11(18), pages 1-26, September.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:11:y:2018:i:12:p:3514-:d:191185. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.