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Comparative study of fast pyrolysis, hydropyrolysis and catalytic hydropyrolysis of poplar sawdust and rice husk in a modified Py-GC/MS microreactor system: Insights into product distribution, quantum description and reaction mechanism

Author

Listed:
  • He, Yifeng
  • Zhao, Yingnan
  • Chai, Meiyun
  • Zhou, Zhongyue
  • Sarker, Manobendro
  • Li, Chong
  • Liu, Ronghou
  • Cai, Junmeng
  • Liu, Xinghua

Abstract

Fast pyrolysis, hydropyrolysis and catalytic hydropyrolysis are three important methods to produce bio-oil from biomass and are of great interest to researchers. In this research, the comprehensive study of pyrolysis, hydropyrolysis and catalytic hydropyrolysis of poplar sawdust and rice husk was investigated in a modified laboratory Py-GC/MS microreactor system. Rh/ZrO2 (0.5 wt %) was prepared and applied in the catalytic hydropyrolysis process. An evaluation system including estimating method of product selectivity, the calculation method of O/C and H/C ratio, deoxygenation extent (DE) and hydrogen-loss extent (HLE), was established to fully measure the deoxygenation effect. The Rh/ZrO2-assisted catalytic hydropyrolysis showed a good deoxygenation effect as O/C ratios (0.10 for poplar sawdust, 0.11 for rice husk, respectively) are comparable to that of the reported upgraded bio-oil by hydrodeoxygenation (HDO). The highest hydrocarbon selectivity of 49.14% and DE of 87.6% were obtained in catalytic hydropyrolysis of poplar sawdust. For rice husk, the hydropyrolysis process gained a similar DE (82.7%) to that of the catalytic HyPy (83.7%), because rice husk with high ash content (19.4 wt %) contains a large number of mineral elements that are likely to form a self-catalysis effect. The reaction mechanism was further inferred according to product distribution and quantum calculation of oxygen-containing products, suggesting that Rh/ZrO2-assisted hydropyrolysis was accomplished by multistage reactions, involving initial pyrolysis of raw biomass and further deoxygenation of the pyrolysis intermediates. Moreover, this work can also provide a proven methodology and theoretical supports for future studies on catalytic hydropyrolysis of biomass.

Suggested Citation

  • He, Yifeng & Zhao, Yingnan & Chai, Meiyun & Zhou, Zhongyue & Sarker, Manobendro & Li, Chong & Liu, Ronghou & Cai, Junmeng & Liu, Xinghua, 2020. "Comparative study of fast pyrolysis, hydropyrolysis and catalytic hydropyrolysis of poplar sawdust and rice husk in a modified Py-GC/MS microreactor system: Insights into product distribution, quantum," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    • Handle: RePEc:eee:rensus:v:119:y:2020:i:c:s1364032119308123
    DOI: 10.1016/j.rser.2019.109604
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    2. Nishu, & Li, Chong & Chai, Meiyun & Rahman, Md. Maksudur & Li, Yingkai & Sarker, Manobendro & Liu, Ronghou, 2021. "Performance of alkali and Ni-modified ZSM-5 during catalytic pyrolysis of extracted hemicellulose from rice straw for the production of aromatic hydrocarbons," Renewable Energy, Elsevier, vol. 175(C), pages 936-951.
    3. Kan, Tao & Strezov, Vladimir & Evans, Tim & He, Jing & Kumar, Ravinder & Lu, Qiang, 2020. "Catalytic pyrolysis of lignocellulosic biomass: A review of variations in process factors and system structure," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    4. Wang, Jia & Jiang, Jianchun & Li, Dongxian & Meng, Xianzhi & Zhan, Guowu & Wang, Yunpu & Zhang, Aihua & Sun, Yunjuan & Ruan, Roger & Ragauskas, Arthur J., 2022. "Creating values from wastes: Producing biofuels from waste cooking oil via a tandem vapor-phase hydrotreating process," Applied Energy, Elsevier, vol. 323(C).
    5. He, Yifeng & Liu, Ronghou & Yellezuome, Dominic & Peng, Wanxi & Tabatabaei, Meisam, 2022. "Upgrading of biomass-derived bio-oil via catalytic hydrogenation with Rh and Pd catalysts," Renewable Energy, Elsevier, vol. 184(C), pages 487-497.
    6. Dudziec, Paweł & Stachowicz, Paweł & Stolarski, Mariusz J., 2023. "Diversity of properties of sawmill residues used as feedstock for energy generation," Renewable Energy, Elsevier, vol. 202(C), pages 822-833.

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