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Pyrolysis of Cedrus deodara saw mill shavings in hydrogen and nitrogen atmosphere for the production of bio-oil

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  • Krishna, Bhavya B.
  • Biswas, Bijoy
  • Ohri, Priyanka
  • Kumar, Jitendra
  • Singh, Rawel
  • Bhaskar, Thallada

Abstract

Pyrolysis of deodar has been carried out at 350 and 400 °C at 0.1, 1, 2 and 3 MPa hydrogen pressure. Pyrolysis under nitrogen atmosphere has been carried out at 300, 350, 400 and 450 °C. The favourable process conditions under hydrogen environment were found to be 400 °C and 2 MPa pressure and in case of nitrogen environment was found to be 350 °C. The products have been characterised using GC–MS, 1H NMR, FT-IR and SEM. It has been observed that the bio-oil is rich in phenolic compounds under nitrogen and hydrogen atmospheres. Selectivity towards certain compounds such as catechol, vanillin and its derivatives etc. are high under hydrogen atmosphere. Deodar has undergone decomposition significantly which is evident by the absence of most functionality in bio-char and loss of crystallinity. The products formed under hydrogen and nitrogen environments are different from each other owing to the differences in reaction mechanism.

Suggested Citation

  • Krishna, Bhavya B. & Biswas, Bijoy & Ohri, Priyanka & Kumar, Jitendra & Singh, Rawel & Bhaskar, Thallada, 2016. "Pyrolysis of Cedrus deodara saw mill shavings in hydrogen and nitrogen atmosphere for the production of bio-oil," Renewable Energy, Elsevier, vol. 98(C), pages 238-244.
    • Handle: RePEc:eee:renene:v:98:y:2016:i:c:p:238-244
    DOI: 10.1016/j.renene.2016.02.056
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    1. Xu, Feng & Yu, Jianming & Tesso, Tesfaye & Dowell, Floyd & Wang, Donghai, 2013. "Qualitative and quantitative analysis of lignocellulosic biomass using infrared techniques: A mini-review," Applied Energy, Elsevier, vol. 104(C), pages 801-809.
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    3. Zhu, Haodong & Yi, Baojun & Hu, Hongyun & Fan, Qizhou & Wang, Hao & Yao, Hong, 2021. "The effects of char and potassium on the fast pyrolysis behaviors of biomass in an infrared-heating condition," Energy, Elsevier, vol. 214(C).
    4. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    5. Biswas, Bijoy & Singh, Rawel & Kumar, Jitendra & Singh, Raghuvir & Gupta, Piyush & Krishna, Bhavya B. & Bhaskar, Thallada, 2018. "Pyrolysis behavior of rice straw under carbon dioxide for production of bio-oil," Renewable Energy, Elsevier, vol. 129(PB), pages 686-694.
    6. Bhoi, P.R. & Ouedraogo, A.S. & Soloiu, V. & Quirino, R., 2020. "Recent advances on catalysts for improving hydrocarbon compounds in bio-oil of biomass catalytic pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    7. Amer, Mohammad W. & Aljariri Alhesan, Jameel S. & Ibrahim, Sawsan & Qussay, Ghadeer & Marshall, Marc & Al-Ayed, Omar S., 2021. "Potential use of corn leaf waste for biofuel production in Jordan (physio-chemical study)," Energy, Elsevier, vol. 214(C).
    8. Yue, Xiaokang & Zhang, Shuai & Shang, Ningzhao & Gao, Shutao & Wang, Zhi & Wang, Chun, 2020. "Porous organic polymer supported PdAg bimetallic catalyst for the hydrodeoxygenation of lignin-derived species," Renewable Energy, Elsevier, vol. 149(C), pages 600-608.

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