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A novel one-pot synthesis of tetragonal sulfated zirconia catalyst with high activity for biodiesel production from the transesterification of soybean oil

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  • Shi, Guoliang
  • Yu, Feng
  • Wang, Yan
  • Pan, Dahai
  • Wang, Huigang
  • Li, Ruifeng

Abstract

A sulfated zirconia catalyst has been prepared by a novel one-pot vapor-controlled synthesis route using ammonium persulphate as sulfate agent. A possible formation mechanism of the catalyst is proposed. The effect of calcination temperature and S/Zr molar ratio on the structural, textural and catalytic properties of the prepared catalyst were investigated in detail using X-ray diffraction (XRD), N2 adsorption–desorption, ammonia temperature programmed desorption (NH3-TPD), Fourier transform infrared spectroscopy (FTIR) and a scanning electron microscope (SEM) which was equipped with an energy dispersive spectroscope (EDS). The results indicated that the samples calcined at 500 °C possessed zirconia of pure tetragonal structure, more content of sulfur and better distribution of acid sites on the surface of zirconia compared with the samples calcined at 600 °C at fixed S/Zr molar ratio. Moreover, they showed excellent catalytic activity with 100% yields of biodiesel for the transesterification of soybean oil with methanol.

Suggested Citation

  • Shi, Guoliang & Yu, Feng & Wang, Yan & Pan, Dahai & Wang, Huigang & Li, Ruifeng, 2016. "A novel one-pot synthesis of tetragonal sulfated zirconia catalyst with high activity for biodiesel production from the transesterification of soybean oil," Renewable Energy, Elsevier, vol. 92(C), pages 22-29.
    • Handle: RePEc:eee:renene:v:92:y:2016:i:c:p:22-29
    DOI: 10.1016/j.renene.2016.01.094
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    References listed on IDEAS

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    1. Patel, Anjali & Brahmkhatri, Varsha & Singh, Namita, 2013. "Biodiesel production by esterification of free fatty acid over sulfated zirconia," Renewable Energy, Elsevier, vol. 51(C), pages 227-233.
    2. Bozbas, Kahraman, 2008. "Biodiesel as an alternative motor fuel: Production and policies in the European Union," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(2), pages 542-552, February.
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    1. Kumar, Praveen & Matoh, Lev & Srivastava, Vimal Chandra & Štangar, Urška Lavrenčič, 2020. "Synthesis of zinc/ferrocyanide nano-composite catalysts having a high activity for transesterification reaction," Renewable Energy, Elsevier, vol. 148(C), pages 946-952.
    2. Nayak, Sheetal N. & Bhasin, Chandra Prakash & Nayak, Milap G., 2019. "A review on microwave-assisted transesterification processes using various catalytic and non-catalytic systems," Renewable Energy, Elsevier, vol. 143(C), pages 1366-1387.
    3. Das, Bikashbindu & Mohanty, Kaustubha, 2019. "A review on advances in sustainable energy production through various catalytic processes by using catalysts derived from waste red mud," Renewable Energy, Elsevier, vol. 143(C), pages 1791-1811.

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